Z-2-cyclopentylthio-1,1,1,4,4,4-hexafluorobut-2-ene

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: Z-2-cyclopentylthio-1,1,1,4,4,4-hexafluorobut-2-ene
• 英文别名: Cyclopentyl[(Z)-1-(trifluoromethyl)-3,3,3-trifluoro-1-propenyl] sulfide；[(Z)-1,1,1,4,4,4-hexafluorobut-2-en-2-yl]sulfanylcyclopentane
• 化学式: C₉H₁₀F₆S
• 分子量: 264.235
• InChiKey: KAOGIKJUZHNJLV-ALCCZGGFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  (Z)-1,1,1,2,4,4,4-heptafluoro-but-2-ene 、 环戊硫醇 在 potassium carbonate 作用下， 以 乙腈 为溶剂， 以70%的产率得到Z-2-cyclopentylthio-1,1,1,4,4,4-hexafluorobut-2-ene
  参考文献：
  名称：

  Cycloadditions and nucleophilic attack on Z-2H-heptafluorobut-2-ene

  摘要：

  Chemistry of Z-2H-Heptafluorobut-2-ene 1 is surveyed; cycloaddition reactions occur with a variety of benzenoid compounds, in some cases leading directly to aromatics. Addition to cyclopentadiene, followed by eliminations of hydrogen fluoride and ethyne, lead to isomeric bistrifluoromethylcyclopentadienes. Nucleophilic reactions occur readily with oxygen, nitrogen and sulphur nucleophiles and aniline provides a quinoline synthesis. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(98)00201-4

文献信息

• Cycloadditions and nucleophilic attack on Z-2H-heptafluorobut-2-ene
  作者：Richard D. Chambers、Andrew R. Edwards

  DOI：10.1016/s0040-4020(98)00201-4

  日期：1998.5

  Chemistry of Z-2H-Heptafluorobut-2-ene 1 is surveyed; cycloaddition reactions occur with a variety of benzenoid compounds, in some cases leading directly to aromatics. Addition to cyclopentadiene, followed by eliminations of hydrogen fluoride and ethyne, lead to isomeric bistrifluoromethylcyclopentadienes. Nucleophilic reactions occur readily with oxygen, nitrogen and sulphur nucleophiles and aniline provides a quinoline synthesis. (C) 1998 Elsevier Science Ltd. All rights reserved.