N,N'-dimethylene-1,2-phenylenediamine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-dimethylene-1,2-phenylenediamine
• 英文别名: N-[2-(methylideneamino)phenyl]methanimine
• 化学式: C₈H₈N₂
• 分子量: 132.165
• InChiKey: VRDHDJSMRNPQQX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-dimethylene-1,2-phenylenediamine 、 Diphenylphosphine oxide 在 silver nitrate 作用下， 以 乙腈 为溶剂， 反应 12.0h， 生成 diphenyl(quinoxalin-2-yl)phosphine oxide
  参考文献：
  名称：

  CN108586531

  摘要：

  公开号：
• 作为产物：
  描述：

  聚合甲醛 、 邻苯二胺 在 γ-maghemite-silica nanocomposite from 20 mg FeCl3/g silica activated 作用下， 以 neat (no solvent) 为溶剂， 生成 N,N'-dimethylene-1,2-phenylenediamine
  参考文献：
  名称：

  γ-Maghemite-silica nanocomposite: A green catalyst for diverse aromatic N-heterocycles

  摘要：

  gamma-Maghemite-silica nanocomposite has been applied as a green catalyst to synthesize variety of aromatic N-heterocycles under solvent free conditions. Characterization was done by modern analytical tools (UV, IR, AAS, DSC, EDXRF, powdered XRD, EPR, Mossbauer and TEM). Mild reaction conditions and recyclability have made the present protocol both environmentally and economically viable. (c) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.catcom.2013.06.026

文献信息

• Phenylenediamine and 4,4′-diaminodiphenyls in cyclothiomethylation with CH2O and H2S
  作者：G. R. Khabibullina、V. R. Akhmetova、R. V. Kunakova

  DOI：10.1134/s107036321404015x

  日期：2014.4

  Cyclothiomethylation of o-phenylenediamine with CH2O and H2S gives rise to 1,2,4,5-tetrahydrobenzo[d][1,3,6]thiadiazepine and 1,2,6,7-tetrahydrobenzo[f][1,3,5,8]dithiadiazonine, whereas m-phenylenediamine forms benzothiaza macroheterocycles of various structure, comprising 4-8 molecules of the starting diamine, formaldehyde, and hydrogen sulfide. 4,4'-Diaminodiphenyls give bis(1,3,5-dithiazinanes), along with oligomeric hetero(N,S,O)atomic compounds.
• US7327433B2
  申请人：——

  公开号：US7327433B2

  公开（公告）日：2008-02-05
• [EN] COMPOUND FOR ORGANIC ELECTRIC ELEMENT, ORGANIC ELECTRIC ELEMENT USING SAME, AND ELECTRONIC DEVICE COMPRISING SAME ORGANIC LIGHT ELEMENT<br/>[FR] COMPOSÉ POUR ÉLÉMENT ÉLECTRIQUE ORGANIQUE, ÉLÉMENT ÉLECTRIQUE ORGANIQUE L'UTILISANT ET DISPOSITIF ÉLECTRONIQUE COMPRENANT LEDIT ÉLÉMENT LUMINESCENT ORGANIQUE<br/>[KO] 유기전기 소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
  申请人：DUK SAN NEOLUX CO LTD

  公开号：WO2020209514A1

  公开（公告）日：2020-10-15

  본 발명은 화학식 1로 표시되는 화합물과, 제 1전극, 제 2전극 및 상기 제 1전극과 상기 제 2전극 사이의 유기물층을 포함하는 유기전기소자, 및 상기 유기전기소자를 포함하는 전자장치를 제공한다. 상기 유기물층에 화학식 1로 표시되는 화합물을 포함됨으로써, 유기전기소자의 구동전압을 낮출 수 있고 발광 효율 및 수명을 향상시킬 수 있다.
• γ-Maghemite-silica nanocomposite: A green catalyst for diverse aromatic N-heterocycles
  作者：Pranab Ghosh、Amitava Mandal、Raju Subba

  DOI：10.1016/j.catcom.2013.06.026

  日期：2013.11

  gamma-Maghemite-silica nanocomposite has been applied as a green catalyst to synthesize variety of aromatic N-heterocycles under solvent free conditions. Characterization was done by modern analytical tools (UV, IR, AAS, DSC, EDXRF, powdered XRD, EPR, Mossbauer and TEM). Mild reaction conditions and recyclability have made the present protocol both environmentally and economically viable. (c) 2013 Elsevier B.V. All rights reserved.
• CN108586531
  申请人：——

  公开号：——

  公开（公告）日：——