4-(4'-acryloyloxy)biphenyl acid

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(4'-acryloyloxy)biphenyl acid
• 英文别名: 4-(4-Prop-2-enoyloxyphenyl)benzoic acid
• 化学式: C₁₆H₁₂O₄
• 分子量: 268.269
• InChiKey: TUPSBXQQVJNJPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-(4'-acryloyloxy)biphenyl acid 、 (R)-1,1'-Bi-2-naphthol 在 4-二甲氨基吡啶 、 N,N'-二异丙基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 5.0h， 以35 g的产率得到
  参考文献：
  名称：

  JP5962945

  摘要：

  公开号：

文献信息

• ALKALOID MONOMERS, LIQUID CRYSTAL COMPOSITIONS AND POLYMER NETWORKS DERIVED THEREFROM
  申请人：Goldfinger Marc B.

  公开号：US20110193019A1

  公开（公告）日：2011-08-11

  Disclosed is the chemical synthesis of chiral alkaloid monomers, liquid crystal compositions comprising the chiral alkaloid monomers, and polymerization of the liquid crystal compositions to provide polymer networks with useful cholesteric optical properties and stability.

  公开了手性生物碱单体的化学合成、包含手性生物碱单体的液晶组合物，以及液晶组合物的聚合，以提供具有有用的胆甾光学性能和稳定性的聚合物网络。
• PHOTO-CROSSLINKABLE LIQUID CRYSTAL MONOMERS WITH OPTICAL ACTIVITY
  申请人：CHEN Yu-hsien

  公开号：US20120289731A1

  公开（公告）日：2012-11-15

  The present invention relates to photo-crosslinkable liquid crystal monomers with optical activity. The liquid crystal monomers contains one chiral center with an acrylate group or terminal diacrylate groups, and terminal dibenzene rings are introduced in order to extend its hard segment for the purpose of getting a wider liquid crystalline phase. By introducing the liquid crystal monomers, the room temperature nematic liquid crystal or the cholesteric liquid crystal may have a better mutual solubility and a wider, steadier structure of liquid crystal. The liquid crystal monomers have the following formula structure:

  本发明涉及具有光学活性的光交联液晶单体。液晶单体包含一个手性中心，带有丙烯酸酯基团或末端二丙烯酸酯基团，并引入末端二苯环，以延伸其硬段，以获得更广的液晶相。通过引入液晶单体，室温向列型液晶或胆甾型液晶可能具有更好的相互溶解性和更广泛、更稳定的液晶结构。液晶单体具有以下结构式：
• Blockcopolymer solid electrolyte, ion-conductive membrane and process for producing the blockcopolymer
  申请人：Nippon Soda Co., Ltd.

  公开号：EP2341510B1

  公开（公告）日：2012-10-31
• Composition for polymer solid electrolyte, polmer solid electrolyte, polymer, polymer solid electrolyte battery, ionconductive membrane, copolymer and process for producing the copolymer
  申请人：Muramoto Hiroo

  公开号：US20070040145A1

  公开（公告）日：2007-02-22

  The present invention provides a polymer solid electrolyte excellent in thermal properties, physical properties and ion conductivity and being close to practical level; especially, a totally solid electrolyte and a composition for producing the same. A composition for polymer solid electrolyte includes a copolymer having repeating units represented by Formula (I): (wherein each of R 1 to R 3 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R 4a and R 4b independently represents a hydrogen atom or a methyl group; R 5 represents a hydrogen atom, a hydrocarbon group, an acyl group or a silyl group; and m is an integer of 1 to 100), and repeating units represented by Formula (II): (wherein each of R 6 and R 8 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R 9 represents an organic group having at lease one functional group selected from the group consisting of hydroxyl group, carboxyl group, epoxy group, acid anhydride group and amino group); and an electrolyte salt.
• Polymer, Crosslinked Polymer, Composition for Solid Polymer Electrolyte, Solid Polymer Electrolyte, and Adhesive Composition
  申请人：Niitani Takeshi

  公开号：US20080166636A1

  公开（公告）日：2008-07-10

  A polymer including a block chain A which is formed from a random copolymer containing a repeating unit (I) represented by the formula (I) wherein R 1 to R 3 each independently represents hydrogen or C 1-10 hydrocarbon and R 1 and R 3 may bond to form a ring; R 4a and R 4b each independently represents hydrogen or methyl; R 5 represents hydrogen, hydrocarbon, acyl, or silyl; and m represents any integer of 1 to 100 and when m is 2 or more and each R 4a may be the same or different from one another and each R 4b may be the same or different from one another; and a repeating unit (II) represented by the formula (II) wherein R 6 and R 8 each independently represents hydrogen or C 1-10 hydrocarbon and R 6 and R 8 may bond to form a ring; R 7 represents hydrogen, C 1-10 hydrocarbon, hydroxyl, hydrocarbonoxy, carboxyl, acid anhydride, amino, ester, or an organic group having at least one functional group selected from the group consisting of hydroxyl, carboxyl, epoxy, acid anhydride, and amino; and R 9 represents an organic group having at least one functional group selected from the group consisting of hydroxyl, carboxyl, epoxy, acid anhydride, and amino; and a block chain B having a repeating unit (III) represented by the formula (III) wherein R 10 to R 12 each independently represents hydrogen or C 1-10 hydrocarbon and R 13 represents aryl or heteroaryl; and wherein an arrangement order thereof is B, A, B.