N,N-dibenzyl-N-(2,2-diphenylvinyl)amine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-dibenzyl-N-(2,2-diphenylvinyl)amine
• 英文别名: N,N-dibenzyl-2,2-diphenylethenamine
• 化学式: C₂₈H₂₅N
• 分子量: 375.513
• InChiKey: WRSZBSUYEDLWHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  29
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  联苯乙醛 、 二苄胺 以 氯仿 为溶剂， 反应 4.0h， 以71%的产率得到N,N-dibenzyl-N-(2,2-diphenylvinyl)amine
  参考文献：
  名称：

  Highly Chemoselective Formation of Aldehyde Enamines under Very Mild Reaction Conditions

  摘要：

  Although ketone enamines are widely used in organic synthesis, aldehyde enamines are rarely employed due to the limitations of their preparation using known methods (need for acid or base, excess of amine, and/or elevated temperature). We have successfully developed rapid and particularly mild condensation conditions (1 h, 0 degrees C, 1.2 equiv of amine) leading to di- and trisubstituted enamines with excellent conversion (84-100%). Remarkably high chemoselectivity was observed with complete discrimination between aldehyde and ketone, among other functional groups positively tested.

  DOI：

  10.1021/jo0611061

文献信息

• Electrophotographic photoreceptor containing enamine compound, image formation apparatus provided with the same, enamine compound and method for producing the same
  申请人：Obata Takatsugu

  公开号：US20080286671A1

  公开（公告）日：2008-11-20

  An electrophotographic photoreceptor comprising laminating a monolayer type photosensitive layer containing a charge generation material and a charge transport material or a laminate type photosensitive layer obtained by laminating a charge generation layer containing a charge generation material and a charge transport layer containing a charge transport material in this order, on a conductive support, wherein the charge transport layer of the monolayer type photosensitive layer or laminate type photosensitive layer contains an enamine compound represented by the following formula (1).
• US7977020B2
  申请人：——

  公开号：US7977020B2

  公开（公告）日：2011-07-12