N,N'-didodecyl-2,4-pyridinedicarboxamide

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N,N'-didodecyl-2,4-pyridinedicarboxamide
• 英文别名: 2-N,4-N-didodecylpyridine-2,4-dicarboxamide
• 化学式: C₃₁H₅₅N₃O₂
• 分子量: 501.797
• InChiKey: KBAGCRGFFRYSLO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  36
• 可旋转键数：
  24
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  71.1
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2,4-吡啶二羧酸 在 氯化亚砜 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 生成 N,N'-didodecyl-2,4-pyridinedicarboxamide
  参考文献：
  名称：

  Self-Assembly of a Pyridyl Derivative and its Silver Complex: Formation of a Liquid Crystalline Phase and Organogels

  摘要：

  Self-assembling behavior of N,N-didodecyl-3,5-pyridinedicarboxamide and its silver complex has been studied. They act as gelators in solution and gelate a variety of organic solvents. Though the silver complex exhibits lower gelation abilities for halogenated and aromatic solvents, long-term stability is achieved for ethanol and acetone gels. Moreover, the silver complex exhibits a smectic A phase on cooling while a single component of N,N'-didodecyl-3,5-pyridinedicarboxamide exhibits no mesomorphic behavior. The XRD pattern for the complex shows that the layer spacing of the SA phase is 37 angstrom.

  DOI：

  10.1080/154214091009914

文献信息

• Self-Assembly of a Pyridyl Derivative and its Silver Complex: Formation of a Liquid Crystalline Phase and Organogels
  作者：Kazuhiro Yabuuchi†、Takashi Kato

  DOI：10.1080/154214091009914

  日期：2005.11.1

  Self-assembling behavior of N,N-didodecyl-3,5-pyridinedicarboxamide and its silver complex has been studied. They act as gelators in solution and gelate a variety of organic solvents. Though the silver complex exhibits lower gelation abilities for halogenated and aromatic solvents, long-term stability is achieved for ethanol and acetone gels. Moreover, the silver complex exhibits a smectic A phase on cooling while a single component of N,N'-didodecyl-3,5-pyridinedicarboxamide exhibits no mesomorphic behavior. The XRD pattern for the complex shows that the layer spacing of the SA phase is 37 angstrom.