CROSSLINKED AROMATIC POLYMER, POLYMER ELECTROLYTE, CATALYST INK, POLYMER ELECTROLYTE MEMBRANE, MEMBRANE-ELECTRODE ASSEMBLY AND FUEL CELL
申请人:Sumitomo Chemical Company, Limited
公开号:EP2147943A1
公开(公告)日:2010-01-27
A crosslinked aromatic polymer which is produced by a process comprising a reaction step of reacting an aromatic monomer having an ion exchange group of the following general formula
(1) and a poly-functional aromatic monomer of the following general formula (2) in a solvent, thereby generating a gel swollen with the solvent:
wherein, in the formulae,
Ar1 represents a (2+n)-valent aromatic group,
Ar2 represents a (3+p)-valent aromatic group,
Q represents an ion exchange group,
X1 represents a functional group condensable with X1 or X2,
X2 represents a functional group condensable with X1 or X2,
n represents an integer of 1 or more,
p represents an integer of 0 or more, and in this connection a plurality of X1's and X2's may be the same as or different from each other, respectively.
一种交联芳香族聚合物,其生产工艺包括以下反应步骤:将具有离子交换基团的下 列通式的芳香族单体与下列通式的多官能芳香族单体在溶剂中反应
(1)的芳香族单体和下式(2)的多官能芳香族单体在溶剂中反应,从而生成被溶剂溶胀的凝胶:
式中
Ar1 代表(2+n)价芳香基团、
Ar2 代表(3+p)价芳香基团、
Q 代表离子交换基团、
X1 代表可与 X1 或 X2 缩合的官能团、
X2 代表可与 X1 或 X2 缩合的官能团、
n 代表 1 或 1 以上的整数、
p 代表 0 或 0 以上的整数,其中多个 X1 和 X2 可分别相同或不同。