chlorodimethyl(1,5,6,7-tetrahydro-3-phenyl-s-indacen-1-yl)silane

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: chlorodimethyl(1,5,6,7-tetrahydro-3-phenyl-s-indacen-1-yl)silane
• 英文别名: chloro-dimethyl-(3-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane
• 化学式: C₂₀H₂₁ClSi
• 分子量: 324.925
• InChiKey: CNCFAAJXQIPVSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.69
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  chlorodimethyl(1,5,6,7-tetrahydro-3-phenyl-s-indacen-1-yl)silane 、 叔丁胺 在 三乙胺 作用下， 以 正己烷 为溶剂， 以88.7%的产率得到N-(1,1-dimethylethyl)-1,1-dimethyl-1-(1,5,6,7-tetrahydro-3-phenyl-s-indacen-1-yl)silanamine
  参考文献：
  名称：

  Fused ring substituted indenyl metal complexes and polymerization process

  摘要：

  揭示了由融合环吲哚衍生物配体构成的第四族金属受限几何配合物，其催化衍生物，制备这些配合物的过程以及它们作为烯烃聚合催化剂组分的用途。

  公开号：

  US05965756A1
• 作为产物：
  描述：

  1,2,3,5-Tetrahydro-7-phenyl-s-indacene 、 dilithium 、 二氯二甲基硅烷 在 正己烷 作用下， 以 四氢呋喃 为溶剂， 反应 16.0h， 以resulted in the isolation of the desired product as a yellow oil (15.1492 g, 91.1% yield)的产率得到chlorodimethyl(1,5,6,7-tetrahydro-3-phenyl-s-indacen-1-yl)silane
  参考文献：
  名称：

  Compositions of interpolymers of alpha-olefin monomers with one or more vinyl or vinylidene aromatic monomers and/or one or more hindered aliphatic or cycloaliphatic vinyl or vinylidene monomers blended with a conductive additive

  摘要：

  一种聚合材料混合物，包括(A)至少一种基于组分A、B和C的组合重量的约1至约99.99重量百分比的至少一种基本随机交联聚合物；其中，所述交联聚合物：(1) 包含约0.5至约65摩尔百分比的聚合物单元，其来源于：(a) 至少一种乙烯基或乙烯基苯单体，或(b) 至少一种受阻的脂肪族或环状脂肪族乙烯基或乙烯基苯单体，或(c) 至少一种乙烯基或乙烯基苯单体和至少一种受阻的脂肪族或环状脂肪族乙烯基或乙烯基苯单体的组合；(2) 包含约35至约99.5摩尔百分比的聚合物单元，其来源于至少一种具有2至20个碳原子的脂肪族α-烯烃；(3) 具有大于约1,000的分子量(Mn)；(4) 具有约0.01至约1,000的熔融指数(I2)；(5) 具有约1.5至约20的分子量分布(Mw/Mn)；以及(B)基于组分A、B和C的组合重量的约99至约0.01重量百分比的一个或多个导电添加剂和/或一个或多个具有高磁导率的添加剂；以及(C)基于组分A、B和C的组合重量的约0至约98.99重量百分比的一个或多个A以外的聚合物。

  公开号：

  US20020132905A1

文献信息

• Functionalized ethylene/vinyl or vinylidene aromatic interpolymers
  申请人：——

  公开号：US20020037988A1

  公开（公告）日：2002-03-28

  Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.

  本发明揭示了基本随机功能化互穿聚合物和制造它们的方法。这些新型互穿聚合物包括由乙烯和乙烯芳香单体制备而成的互穿聚合物，例如乙烯-苯乙烯互穿聚合物，然后使用各种亲电和亲核试剂进行功能化。
• Acoustical insulation foams
  申请人：——

  公开号：US20030162852A1

  公开（公告）日：2003-08-28

  An acoustical insulation foam having, either with or without elastification, an Asker C hardness of less than about 65, a density of about 5 to about 150 kg/m3, a cell size of about 0.05 to about 15 mm, an open cell content of 0 to about 100 volume percent, a thickness of about 1 to about 200 mm, and a width of about 100 to about 3000 mm; comprising; (A) one or more alkenyl aromatic polymers, (B) one or more substantially random interpolymers and (C) optionally, one or more nucleating agents and (D) optionally, one or more other additives; and (E) one or more blowing agents.

  一种具有声学隔离功能的泡沫材料，具有Asker C硬度小于约65，密度约为5至150千克/立方米，孔径约为0.05至15毫米，开孔率为0至约100体积百分比，厚度约为1至200毫米，宽度约为100至3000毫米；包括：（A）一种或多种烯基芳香聚合物，（B）一种或多种基本随机互聚物，（C）可选地，一种或多种成核剂和（D）可选地，一种或多种其他添加剂；和（E）一种或多种发泡剂。
• Fused ring substituted indenyl metal complexes and polymerization
  申请人：The Dow Chemical Company

  公开号：US06034022A1

  公开（公告）日：2000-03-07

  Group 4 metal constrained geometry complexes comprising a fused ring indenyl derivative ligand, catalytic derivatives thereof, processes for preparing the same and their use as components of olefin polymerization catalysts are disclosed.

  本发明公开了一种包括融合环吲哚基衍生物配体的第四族金属受限几何配合物，其催化衍生物，制备它们的方法以及它们作为烯烃聚合催化剂组分的使用。
• Compositions having improved ignition resistance
  申请人：The Dow Chemical Company

  公开号：US06262161B1

  公开（公告）日：2001-07-17

  The present invention relates to compositions having enhanced ignition resistance, comprising: (A) from about 5 to about 90 percent by weight of at least one substantially random interpolymer; (B) from about 10 to about 94.9 percent by weight of at least one filler selected from ammonium polyphosphate, magnesium hydroxide, calcium hydroxide, and aluminum trihydrate; and (C) at least one component selected from; (1) about 5 to about 50 percent by weight of at least one filler; or (2) about 0.5 to about 20 percent by weight of at least one metal borate, and, optionally, about 0.5 to about 10 percent by weight of at least one processing aid; or (3) about 0.1 to about 15 percent by weight of at least one initiator or at least one coupling agent; or (4) about 0.1 to about 20 percent by weight of at least one hindered amine stabilizer.

  本发明涉及具有增强点火抗性的组合物，包括：(A)约5至约90重量％的至少一种基本随机的互聚物；(B)约10至约94.9重量％的至少一种填料，所述填料选自聚磷酸铵、氢氧化镁、氢氧化钙和三水合铝；以及(C)至少一种组分，所述组分选自：(1)约5至约50重量％的至少一种填料；或(2)约0.5至约20重量％的至少一种金属硼酸盐，以及可选地约0.5至约10重量％的至少一种加工助剂；或(3)约0.1至约15重量％的至少一种引发剂或至少一种偶联剂；或(4)约0.1至约20重量％的至少一种受阻胺稳定剂。
• Soft and flexible foams made from blends of alkenyl aromatic polymers
  申请人：The Dow Chemical Company

  公开号：US06133333A1

  公开（公告）日：2000-10-17

  A soft foam having an Asker C hardness of less than about 65, comprising; (A) from about 30 to about 70 percent by weight (based on the combined weight of Components A and B) of one or more alkenyl aromatic polymers and wherein at least one of said alkenyl aromatic polymers has a molecular weight (M.sub.w) of from about 100,000 to about 500,000; and (B) from about 30 to about 70 percent by weight (based on the combined weight of Components A and B) of one or more substantially random interpolymers; and (C) optionally, one or more nucleating agents; and (D) optionally, one or more other additives; and (E) one or more blowing agents present in a total amount of from about 0.4 to about 5.0 gram-moles per kilogram (based on the combined weight of Components A and B).

  硬度小于约65 Asker C的软泡沫，包括：（A）约30至约70重量％（基于组分A和B的总重量）的一种或多种烯基芳香聚合物，其中至少一种所述烯基芳香聚合物的分子量（M.sub.w）约为100,000至约500,000；和（B）约30至约70重量％（基于组分A和B的总重量）的一种或多种基本随机互聚物；以及（C）可选的一种或多种成核剂；和（D）可选的一种或多种其他添加剂；以及（E）一种或多种发泡剂，其总量约为每千克组分A和B的组合重量约0.4至约5.0克摩尔。