膦,1H-茚-1-基二苯基- | 138784-88-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 中文名称: 膦,1H-茚-1-基二苯基-
• 英文名称: 1-diphenylphosphinoindene
• 英文别名: (1H-inden-1-yl)diphenylphosphine；Phosphine, 1H-inden-1-yldiphenyl-；1H-inden-1-yl(diphenyl)phosphane
• CAS: 138784-88-0
• 化学式: C₂₁H₁₇P
• 分子量: 300.34
• InChiKey: MYDCQLBEJDDLBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  膦,1H-茚-1-基二苯基- 、 正丁基锂 在 正己烷 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 16.42h， 以to give 4.45 g of off-white solid的产率得到(1-(diphenylphosphino)-1H-indenyl)lithium
  参考文献：
  名称：

  3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process

  摘要：

  本发明涉及杂原子取代的环戊二烯基含配体、包含这些配体的金属络合物、由催化剂组分制备的催化体系。金属络合物包含“a”杂原子-Cp键或环杂原子-Cp键在Cp的3位。在首选金属络合物中，配体是3-杂原子取代的茚基基团。烯烃聚合的催化体系可在高温下使用，具有高活性并产生高分子量聚合物。

  公开号：

  US06268444B1
• 作为产物：
  描述：

  inden-1-yl lithium 、 乙醚 、 二苯基氯化膦 在 氯化锂 、 正己烷 作用下， 以 四氢呋喃 为溶剂， 反应 16.25h， 以to give 16.43 g of off-white solid的产率得到膦,1H-茚-1-基二苯基-
  参考文献：
  名称：

  3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process

  摘要：

  本发明涉及杂原子取代的环戊二烯基含配体、包含这些配体的金属络合物、由催化剂组分制备的催化体系。金属络合物包含“a”杂原子-Cp键或环杂原子-Cp键在Cp的3位。在首选金属络合物中，配体是3-杂原子取代的茚基基团。烯烃聚合的催化体系可在高温下使用，具有高活性并产生高分子量聚合物。

  公开号：

  US06268444B1

文献信息

• New cyclopentadienyl, indenyl or fluorenyl substituted phosphine compounds and their use in catalytic reactions
  申请人：Evonik Degussa GmbH

  公开号：EP1894938A1

  公开（公告）日：2008-03-05

  The invention is directed to a phosphine compound represented by general formula (1) wherein R' and R" independently are selected from alkyl, cycloalkyl and 2-furyl radicals, or R' and R" are joined together to form with the phosphorous atom a carbon-phosphorous monocycle comprising at least 3 carbon atoms or a carbon-phosphorous bicycle; the alkyl radicals, cycloalkyl radicals, and carbon-phosphorous monocycle being unsubstituted or substituted by at least one radical selected from the group of alkyl, cycloalkyl, aryl, alkoxy, and aryloxy radicals; Cps is a partially substituted or completely substituted cyclopentadien-1-yl group, including substitutions resulting in a fused ring system, and wherein a substitution at the 1-position of the cyclopentadien-1-yl group is mandatory when the cyclopentadien-1-yl group is not part of a fused ring system or is part of an indenyl group. Also claimed is the use of these phosphines as ligands in catalytic reactions and the preparation of these phosphines.

  该发明涉及一种由通式（1）表示的膦化合物 其中 R'和R"独立地选自烷基、环烷基和2-呋喃基，或者R'和R"结合在一起与磷原子形成至少含有3个碳原子的碳-磷单环或碳-磷双环；所述烷基基团、环烷基基团和碳-磷单环未取代或取代，所述取代包括来自烷基、环烷基、芳基、烷氧基和芳氧基基团中至少一个基团的选择； Cps是部分取代或完全取代的环戊二烯-1-基团，包括导致融合环系统的取代，当环戊二烯-1-基团不是融合环系统的一部分或是茚基团的一部分时，环戊二烯-1-基团的1-位取代是强制的。还声明了这些膦化合物作为催化反应中的配体以及这些膦化合物的制备的用途。
• Synthesis, properties and structures of methyldiphenylphosphonium 1-indenylide, 1-C9H6PMePh2, and its chiral tricarbonylchromium(0) complex Cr(η5-1-C9H6PMePh2)(CO)3
  作者：John H. Brownie、Michael C. Baird

  DOI：10.1016/j.jorganchem.2008.05.027

  日期：2008.8

  1-C9H6PMePh2 (1) and its chromium(0) complex, Cr(η5-1-C9H6PMePh2)(CO)3 (2) have been synthesized and characterized spectroscopically and crystallographically. The structures and properties of 1 and 2 are compared with those of the analogous C5H4PMePh2 and its chromium complex, Cr(η5-C5H4PMePh2)(CO)3. Compound 2, obtained as a racemic mixture, exhibits planar chirality resulting from coordination of the

  迄今未知茚衍生的叶立德，methyldiphenylphosphonium 1- indenylide，1-C 9 H ^ 6 PMePh 2（1）和它的铬（0）配合物，铬（η 5 -1-C 9 H ^ 6 PMePh 2）（CO）3（2）已经合成并且在光谱和晶体学上表征。的结构和性能的1和2与这些类似的C相比，5 ħ 4 PMePh 2和它的铬络合物，铬（η 5 -C 5 H ^ 4 PMePh2）（CO）3。作为外消旋混合物获得的化合物2由于前手性芳族配体的配位而显示出平面手性。
• Facile <i>meso</i> to <i>rac</i> Isomerization of the Bis-Planar Chiral Ferrocenyldiphosphine Bis(1-(diphenylphosphino)-η⁵-indenyl)iron(II)
  作者：Owen J. Curnow、Glen M. Fern

  DOI：10.1021/om020200e

  日期：2002.7.1

  The meso isomer of the ferrocenyldiphosphine bis(1-(diphenylphosphino)-η5-indenyl)iron(II) isomerizes to the rac isomer overnight in tetrahydrofuran at room temperature. The isomerization is accelerated by salts but does not occur in chloroform solvent.

  的内消旋的二茂铁双异构体（1-（二苯基膦基）-η 5 -茚基）合铁（II）异构化成外消旋在室温下过夜异构体在四氢呋喃中。盐可加速异构化，但在氯仿溶剂中不会发生。
• CYCLOPENTADIENYL, INDENYL OR FLUORENYL SUBSTITUTED PHOSPHINE COMPOUNDS AND THEIR USE IN CATALYTIC REACTIONS
  申请人：Plenio Herbert

  公开号：US20090253907A1

  公开（公告）日：2009-10-08

  A phosphine compound represented by general formula (1) wherein R′ and R″ independently are selected from alkyl, cycloalkyl and 2-furyl radicals, or R′ and R″ are joined together to form with the phosphorous atom a carbon-phosphorous monocycle including at least 3 carbon atoms or a carbon-phosphorous bicycle; the alkyl radicals, cycloalkyl radicals, and carbon-phosphorous monocycle being unsubstituted or substituted by at least one radical selected from the group of alkyl, cycloalkyl, aryl, alkoxy, and aryloxy radicals; Cp s is a partially substituted or completely substituted cyclopentadien-1-yl group, including substitutions resulting in a fused ring system, and wherein a substitution at the 1-position of the cyclopentadien-1-yl group is mandatory when the cyclopentadien-1-yl group is not part of a fused ring system or is part of an indenyl group. These phosphines can be used as ligands in catalytic reactions.

  一种磷化合物，其通式表示为（1），其中R'和R''独立地选择烷基，环烷基和2-呋喃基基团，或者R'和R''与磷原子结合形成至少包括3个碳原子的碳-磷单环或碳-磷双环；烷基基团，环烷基基团和碳-磷单环未经取代或被至少一种从烷基，环烷基，芳基，烷氧基和芳氧基基团组成的基团取代；Cps是部分取代或完全取代的环戊二烯-1-基基团，包括导致融合环系统的取代，当环戊二烯-1-基基团不是融合环系统的一部分或是一个茚基基团的一部分时，必须在环戊二烯-1-基基团的1位进行取代。这些磷化物可以用作催化反应中的配体。
• New Cyclopentadienyl, Indenyl or Fluorenyl Substituted Phosphine Compounds and their Use in Catalytic Reactions
  申请人：PLENIO Herbert

  公开号：US20120245348A1

  公开（公告）日：2012-09-27

  Disclosed herein are phosphine compounds represented by the general formula (4): and corresponding phosphonium salts represented by the general formula (4a): Also disclosed are processes for the preparation of these phosphines and phosphonium salts as well as their use as ligands in catalytic reactions.

  本文披露了由一般式（4）表示的膦化合物和由一般式（4a）表示的相应膦鎵鹽，同时还披露了制备这些膦化合物和膦鎵鹽的过程，以及它们作为催化反应中的配体的用途。