(+/-)-benzoin; compound with benzil

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (+/-)-benzoin; compound with benzil
• 英文别名: (+/-)-Benzoin; Verbindung mit Benzil；1,2-Diphenylethane-1,2-dione;2-hydroxy-1,2-diphenylethanone
• 化学式: 2C₁₄H₁₀O₂*C₁₄H₁₂O₂
• 分子量: 632.712
• InChiKey: YMSACYRPLFCCON-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.36
• 重原子数：
  32
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  71.4
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (+/-)-benzoin; compound with benzil 生成 安息香精油 、 联苯甲酰
  参考文献：
  名称：

  Klinger, Chemische Berichte, 1886, vol. 19, p. 1865

  摘要：

  DOI：
• 作为产物：
  描述：

  cis-stilbenediol dibenzoate 在 乙醚 作用下， 生成 (+/-)-benzoin; compound with benzil
  参考文献：
  名称：

  Klinger, Chemische Berichte, 1886, vol. 19, p. 1865

  摘要：

  DOI：

文献信息

• Process for preparing positive-negative blended optical retardation film, positive-negative blended optical retardation film, and liquid crystal display element and liquid crystal display device using the same
  申请人：National Chiao Tung University

  公开号：US20040201797A1

  公开（公告）日：2004-10-14

  The invention provides a process for preparing a positive-negative-blended optical retardation film comprising coating a solution consisting of discotic and rod-like liquid crystal onto an alignment layer after unidirectionally rubbing treatment on a substrate, subsequently heating the coating to obtain a film consisting of discotic and rod-like liquid crystal with uniform arrangement, and then curing it through exposing under a UV-irradiation to obtain a positive-negative-blended optical retardation film with excellent viewing angle; and a positive-negative-blended optical retardation film. Further, the invention also provides a liquid crystal element and a liquid crystal device having said positive-negative-blended optical retardation film.

  本发明提供了一种正负混合型光缓膜的制备方法，包括在基底上单向摩擦处理后，将由盘状液晶和棒状液晶组成的溶液涂布在配向层上，随后加热涂布层，得到由均匀排列的盘状液晶和棒状液晶组成的薄膜，然后在紫外线照射下固化，得到视角极佳的正负混合型光缓膜；以及一种正负混合型光缓膜。此外，本发明还提供了一种液晶元件和液晶装置，该液晶元件和液晶装置具有所述正负混合型光缓膜。
• Ciamician; Silber, Chemische Berichte, 1901, vol. 34, p. 1540
  作者：Ciamician、Silber

  DOI：——

  日期：——
• Benrath, Journal fur praktische Chemie (Leipzig 1954), 1906, vol. <2> 73, p. 388
  作者：Benrath

  DOI：——

  日期：——
• Polycaprolactone polyol urethanes and processes for their production
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0021825B1

  公开（公告）日：1984-09-26
• CHEMICAL TAGGING INDICATORS AND METHOD TO LOCATE OVERHEATED SPOTS IN LIQUID-FILLED ELECTRICAL DEVICES
  申请人：Shkolnik Anatoly

  公开号：US20100319606A1

  公开（公告）日：2010-12-23

  A method for identifying overheated spots in liquid-filled electrical devices, comprising the steps of: a) determining the locations of potentially overheatable spots in said device and mapping said locations; b) positioning a tag consisting of one or more chemical indicators on potentially overheatable spots in said devices, wherein when said tags are exposed to a given high temperature, they are depolymerized into thermal degradation products which are diffused into the liquid; c) identifying the thermal degradation products by analytical methods; and d) locating the overheated places according to the identified thermal degradation products and the map of locations of said tags; wherein the tags comprise polymers and copolymers, which are substantially absent from the liquid of the device at normal working conditions.