四氢-1,3-二(羟基甲基)-4-甲氧基-5,5-二甲基-1H-嘧啶-2-酮 | 13747-12-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 中文名称: 四氢-1,3-二(羟基甲基)-4-甲氧基-5,5-二甲基-1H-嘧啶-2-酮
• 英文名称: Tetrahydro-1,3-bis(hydroxymethyl)-4-methoxy-5,5-dimethyl-1H-pyrimidin-2-one
• 英文别名: 1,3-bis(hydroxymethyl)-4-methoxy-5,5-dimethyl-1,3-diazinan-2-one
• CAS: 13747-12-1
• 化学式: C₉H₁₈N₂O₄
• 分子量: 218.25
• InChiKey: VGBDEALNUKLDKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  73.2
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• Cross-Linkable Monomers and Polymers and the Use Thereof
  申请人：Jakob Martin

  公开号：US20110190462A1

  公开（公告）日：2011-08-04

  The invention relates to novel cross-linkable monomers that may be polymerized with ethylenically unsaturated comonomers to form cross-linkable copolymers. Said copolymers may particularly be used in the form of aqueous dispersions as formaldehyde-free adhesives or as coatings with good water resistance. The cross-linkable monomer is a compound in acid or salt form comprising an anion of the formula (I) and one or more cations for producing electrical neutrality, where R 1 and R 2 represent, independently of one another, hydrogen alkyl, cycloalkyl, aryl, aralkyl, —COOR 5 , —COO − cat + or —CON(R 6 R 7 ), R 6 and R 7 represent, independently of one another, hydrogen, alkyl, or aryl, cat 4 represents a monovalent cation, and one of the groups R 1 or R 2 may also represent a group —X—R 4 —CR 5 (OH)SO 3 − ), wherein X, R 4 , and R 5 assume one of the meanings listed below, R 3 represents hydrogen, alkyl, or aryl, X is selected from the group of direct C—C bond, —O—, —CH 2 —O—, —CH 2 —NR 8 —, —COO— or —CONR 8 —, R 8 represents hydrogen, alkyl, or aryl, R 4 represents alkylene, polyoxyalkylene, cycloalkylene, or arylene, and R 5 represents hydrogen, alkyl, cycloalkyl, or aryl.

  本发明涉及新型交联单体，可以与乙烯基不饱和共聚单体聚合形成交联共聚物。所述共聚物可以作为无甲醛粘合剂的水性分散液或具有良好耐水性的涂料使用。所述交联单体是一种酸或盐形式的化合物，包括公式（I）的阴离子和一个或多个阳离子以产生电中性，其中R1和R2分别独立地表示氢，烷基，环烷基，芳基，芳基烷基，-COOR5，-COO-cat+或-CON（R6R7），R6和R7分别独立地表示氢，烷基或芳基，cat4表示一价阳离子，R1或R2中的一个也可以表示一个基团-X-R4-CR5（OH）SO3-，其中X，R4和R5分别取下面列出的含义之一，R3表示氢，烷基或芳基，X从直接C-C键，-O-，-CH2-O-，-CH2-NR8-，-COO-或-CONR8-的群中选择，R8表示氢，烷基或芳基，R4表示烷基，聚氧烷基，环烷基或芳基，R5表示氢，烷基，环烷基或芳基。
• POLYVINYL ESTER DISPERSIONS WITH LOW FILM FORMATION TEMPERATURE AND HIGH WATER RESISTANCE AND USE THEREOF
  申请人：Hardt Daniela

  公开号：US20090281218A1

  公开（公告）日：2009-11-12

  Polyvinyl ester dispersions with low film formation temperature and high water resistance and use thereof What are described are polyvinyl ester dispersions having a minimum film formation temperature of less than or equal to 10° C. These comprise a crosslinkable polyvinyl ester dispersion and an ester of aliphatic monocarboxylic acids and at least trihydric aliphatic alcohols and/or an ester of at least tribasic aliphatic carboxylic acids and monohydric aliphatic alcohols as film formation assistants. These polyvinyl ester dispersions can be used as adhesives with high water resistance.
• POLYVINYL ESTER DISPERSIONS AND THEIR USE
  申请人：JAKOB MARTIN

  公开号：US20090312481A1

  公开（公告）日：2009-12-17

  A description is given of aqueous polyvinyl ester dispersions comprising a) at least one vinyl ester copolymer derived from at least one vinyl ester of a monocarboxylic acid, at least one ethylenically unsaturated monomer containing N-alkylol groups and/or derivatives of N-alkylol groups, and, if desired, further comonomers, b) at least one protective colloid, c) at least one carboxylic acid and/or salt thereof, containing at least one further radical selected from the group consisting of hydroxyl, amino, carboxyl, carboxylic ester, and carboxylic amide radicals, and d) at least one water-soluble salt of a divalent metal ion. These dispersions are especially suitable for adhesively bonding porous or semiporous substrates, such as wood. Adhesive bonds of high strength and water resistance can be produced that do not exhibit discoloration. The dispersions can be used more particularly as veneer adhesives.
• Cross-Linkable Polymer Dispersions, Method for the Production Thereof and Use Thereof
  申请人：Balzarek Christoph

  公开号：US20100179272A1

  公开（公告）日：2010-07-15

  Compositions containing an aqueous dispersion of selected polymers and selected polyaldehydes as crosslinking agents are described. Adhesives having very high resistance to boiling water can be produced from these formulations.
• US3956243A
  申请人：——

  公开号：US3956243A

  公开（公告）日：1976-05-11