四氨合硝酸铂 | 20634-12-2

• 物质功能分类: 有机原料 - 有机金属类化合物 - 有机铪、汞、银、铂等
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 中文名称: 四氨合硝酸铂
• 中文别名: 硝酸四氨合铂(II)
• 英文名称: tetraammineplatinum(II) nitrate
• 英文别名: azane;platinum(2+);dinitrate
• CAS: 20634-12-2
• 化学式: H₁₂N₆O₆Pt
• 分子量: 387.212
• InChiKey: RBAKORNXYLGSJB-UHFFFAOYSA-N

物化性质

• 熔点：
  262 °C (dec.) (lit.)
• 密度：
  1.05
• 暴露限值：
  ACGIH: TWA 0.002 mg/m3NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
• 稳定性/保质期：

  如果遵照规格使用和储存，则不会分解。避免接触还原剂、易氧化材料以及有机材料。水溶液与碱金属、碱土金属及许多有机和无机的活性化学药品不相溶。此外，还应注意金属粉末的安全存放。

计算性质

• 辛醇/水分配系数(LogP)：
  0.17
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  130
• 氢给体数：
  4
• 氢受体数：
  10

安全信息

• 危险等级：
  5.1
• 危险品标志：
  O,Xi
• 安全说明：
  S15,S26,S27,S36/37/39
• 危险类别码：
  R5,R8,R36/37/38,R43
• WGK Germany：
  3
• 危险品运输编号：
  UN 1479 5.1/PG 2
• 包装等级：
  III
• 危险类别：
  5.1
• 危险标志：
  GHS03,GHS07
• 危险性描述：
  H272,H315,H317,H319,H335
• 危险性防范说明：
  P220,P261,P280,P305 + P351 + P338

SDS

Name:	Tetraammineplatinum(II) nitrate Material Safety Data Sheet
Synonym:
CAS:	20634-12-2

Section 1 - Chemical Product MSDS Name:Tetraammineplatinum(II) nitrate Material Safety Data Sheet
Synonym:

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
20634-12-2	Tetraammineplatinum(II) nitrate		243-929-9

Hazard Symbols: XI O
Risk Phrases: 36/37/38 43 5 8

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. Heating may cause an explosion.
Contact with combustible material may cause fire.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
May cause sensitization by skin contact.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

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Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 20634-12-2: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 262 deg C (dec.)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: H12N6O6Pt
Molecular Weight: 387.22

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, combustible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Reducing agents, phosphorus, sulfur, organic matter.
Hazardous Decomposition Products:
Nitrogen oxides, ammonia.
Hazardous Polymerization: Will not occur.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 20634-12-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetraammineplatinum(II) nitrate - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: III
IMO
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: III
RID/ADR
No information available.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 43 May cause sensitization by skin contact.
R 5 Heating may cause an explosion.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 20634-12-2: 2
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 20634-12-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 20634-12-2 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

化学性质：硝酸四氨合铂，又称硝酸四氨铂或四氨合硝酸铂，是一种白色晶体，属于铂的四氨类化合物家族。它极易溶于水，不溶于乙醇和丙酮，在酸性条件下不稳定，已经络合的氨会脱离出来生成氯化铵，并与四氯合铂基团反应生成马格努斯绿色盐。在工业上，有时用作铂催化剂的前驱体。

反应信息

• 作为反应物：
  描述：

  Zirconium oxide 、 1,4,6,9-Tetraoxa-5-stannaspiro[4.4]nonane-2,3,7,8-tetrone 、 草酸铵 、 硝酸钯(II)水合物 、 四氨合硝酸铂 在 Zirconium oxide 作用下， 以 水 为溶剂， 生成 Palladium Platinum Tin Zirconium Oxide
  参考文献：
  名称：

  Catalysts and processes for producing butanol

  摘要：

  在一种实施例中，本发明是关于一种催化剂组合物，用于将乙醇转化为较高的醇，例如丁醇。该催化剂组合物包括一种或多种金属和一种或多种载体。所述的一种或多种金属选自钴、镍、钯、铂、锌、铁、锡和铜组成的群组。所述的一种或多种载体选自Al2O3、ZrO2、MgO、TiO2、沸石、ZnO和其混合物，其中催化剂基本上不含碱金属和碱土金属。

  公开号：

  US08962897B2

文献信息

• Catalysts and Processes for Producing Butanol
  申请人：CELANESE INTERNATIONAL CORPORATION

  公开号：US20140171696A1

  公开（公告）日：2014-06-19

  In one embodiment, the invention is to a catalyst composition for converting ethanol to higher alcohols, such as butanol. The catalyst composition comprises one or more metals and one or more supports. The one or more metals selected from the group consisting of cobalt, nickel, palladium, platinum, zinc, iron, tin and copper. The one or more supports are selected from the group consisting of Al 2 O 3 , ZrO 2 , MgO, TiO 2 , zeolite, ZnO, and mixtures thereof, wherein the catalyst is substantially free of alkali metals and alkaline earth metals.

  在一个实施例中，本发明涉及一种催化剂组合物，用于将乙醇转化为更高级别的醇，如丁醇。该催化剂组合物包括一种或多种金属和一种或多种载体。所述一种或多种金属选自钴、镍、钯、铂、锌、铁、锡和铜的群组。所述一种或多种载体选自Al2O3、ZrO2、MgO、TiO2、沸石、ZnO和其混合物的群组，其中催化剂基本上不含有碱金属和碱土金属。