2-chloro-4,5,6-trifluoro-1,3-phenylenediamine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-chloro-4,5,6-trifluoro-1,3-phenylenediamine
• 英文别名: 2-chloro-4,5,6-trifluorobenzene-1,3-diamine
• 化学式: C₆H₄ClF₃N₂
• 分子量: 196.559
• InChiKey: HPLRZQXLEBHCQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  氯五氟苯 在 ammonium hydroxide 作用下， 反应 48.0h， 以56%的产率得到4-氯-2,5,6-三氟苯-1,3-二胺
  参考文献：
  名称：

  摘要：

  Ammonolysis of chloropentafluorobenzene both in the presence and in the absence of copper(I) salt results mainly in replacement of the para- and ortho-fluorine atoms with respect to chlorine rather than replacement of the chlorine atom. Ammonolysis of 4-chloro-2,3,5,6-tetrafluoroaniline and 2-chloro-3,4,5,6-tetrafluoroaniline in the absence of copper(I) salt yields exclusively the corresponding fluorine substitution products, whereas in the presence of copper(I) salt the chlorine atom is replaced. Successive ammonolysis of chloropentafluorobenzene in the presence of copper catalyst along these two paths was put into the basis of a new method for preparation of 2,3,5,6-tetrafluoro-1,4-phenylenediamine.

  DOI：

  10.1023/a:1012492726911

文献信息

• Gas separation membrane, gas separation module, gas separation device, and gas separation method
  申请人：FUJIFILM Corporation

  公开号：US10040035B2

  公开（公告）日：2018-08-07

  Provided are a gas separation membrane which includes a gas separation layer formed to include a polyimide compound and in which the polyimide compound includes a repeating unit represented by the following Formula (I), a gas separation module, a gas separation device, and a gas separation method using the same. In Formula (I), R represents a group having a specific structure. R3 represents a specific substituent group. A1 to A3 represent a hydrogen atom or a specific substituent group, but all of A1 to A3 do not represent a hydrogen atom at the same time. In this case, at least one of R3, A1, A2, and A3 represents a specific polar group.

  本发明提供了一种气体分离膜，该膜包括由聚酰亚胺化合物形成的气体分离层，其中聚酰亚胺化合物包括由下式（I）表示的重复单元；还提供了一种气体分离组件、一种气体分离装置和一种使用该膜的气体分离方法。 式（I）中，R 代表具有特定结构的基团。R3 代表特定的取代基。A1 至 A3 代表氢原子或特定取代基，但所有 A1 至 A3 不同时代表氢原子。 在这种情况下，R3、A1、A2 和 A3 中至少有一个代表特定的极性基团。
• Gas separation composite membrane, gas separation module, gas separation device, gas separation method, and method of producing gas separation composite membrane
  申请人：FUJIFILM Corporation

  公开号：US10226743B2

  公开（公告）日：2019-03-12

  Provided are a gas separation composite membrane including a gas separation layer which is formed to include a polyimide compound on the upper side of a gas permeating support, in which the solubility of the polyimide compound in dimethylacetamide at 20° C. is 20 mg/100 g or less, and the thickness of the gas separation layer is 0.1 μm or greater and less than 5.0 μm, a method of producing the same, a gas separation module using the gas separation composite membrane, a gas separation device, and a gas separation method.

  本发明提供了一种气体分离复合膜，包括气体分离层，该气体分离层是在气体渗透支架的上侧形成的，其中包括聚酰亚胺化合物，聚酰亚胺化合物在 20° C 时在二甲基乙酰胺中的溶解度为 20 mg/100 g 或以下，气体分离层的厚度为 0.1 μm 或以上且小于 5.0 μm；本发明还提供了一种生产方法、一种使用该气体分离复合膜的气体分离组件、一种气体分离装置和一种气体分离方法。
• Gas separation membrane, gas separation module, gas separation device, gas separation method, and polyimide compound
  申请人：FUJIFILM Corporation

  公开号：US10537859B2

  公开（公告）日：2020-01-21

  A gas separation membrane includes a gas separation layer containing a polyimide compound having a repeating unit represented by Formula (I), in Formula (I), RI represents a hydrogen atom, an alkyl group, or a halogen atom, Xa represents a sulfamoyl group, an alkoxysulfonyl group, a carboxy group, a hydroxy group, an acyloxy group, or a halogen atom, and R represents a mother nucleus having a specific structure.

  气体分离膜包括气体分离层，该层含有聚酰亚胺化合物，其重复单元由式（I）表示、 在式（I）中，RI 代表氢原子、烷基或卤素原子，Xa 代表氨基磺酰基、烷氧基磺酰基、羧基、羟基、酰氧基或卤素原子，R 代表具有特定结构的母核。
• Method for producing gas separation composite membrane, liquid composition, gas separation composite membrane, gas separation module, gas separation apparatus, and gas separation method
  申请人：FUJIFILM Corporation

  公开号：US10654005B2

  公开（公告）日：2020-05-19

  The method for producing a gas separation composite membrane includes applying a mixed liquid containing compounds (a) and (b) below onto a porous support to form a coating film and curing the coating film to form a crosslinked polysiloxane compound layer: (a) a particular crosslinkable polysiloxane compound having a structural unit (a1), a structural unit (a2), and a structural unit (a3) or (a4), and (b) a particular crosslinkable polysiloxane compound having a structural unit (b1), a structural unit (b2), and a structural unit (b3) or (b4), where R1a to R1f and R2a to R2f represent a particular group and * represents a particular linking site.

  生产气体分离复合膜的方法包括将含有以下化合物（a）和（b）的混合液体涂抹在多孔支架上以形成涂膜，并固化涂膜以形成交联聚硅氧烷化合物层： (a) 具有结构单元(a1)、结构单元(a2)和结构单元(a3)或(a4)的特定可交联聚硅氧烷化合物，和 (b) 具有结构单元(b1)、结构单元(b2)和结构单元(b3)或(b4)的特定可交联聚硅氧烷化合物、 其中 R1a 至 R1f 和 R2a 至 R2f 代表一个特定的组，* 代表一个特定的连接点。
• GAS SEPARATION COMPOSITE MEMBRANE AND METHOD OF PRODUCING THE SAME, AND GAS SEPARATING MODULE, GAS SEPARATION APPARATUS AND GAS SEPARATION METHOD USING THE SAME
  申请人：FUJIFILM Corporation

  公开号：US20140130667A1

  公开（公告）日：2014-05-15

  A gas separation composite membrane, containing a gas-permeable supporting layer and a gas separating layer containing a crosslinked polyimide resin over the gas-permeable supporting layer, in which the crosslinked polyimide resin is formed by a polyimide compound being crosslinked by a radically crosslinkable functional group thereof, and a ratio [η] of a crosslinked site to an imide group of the polyimide compound (the number of crosslinked sites/the number of imide groups) in the crosslinked polyimide resin is 0.0001 or more and 0.45 or less; a method of producing the same; and a gas separating module, a gas separation apparatus and a gas separation method using the same.