2,10-dimethyl-6λ⁵-[1,2,3]benzooxadiphosphole[2,3-b][1,2,3]benzooxadiphosphol-6-one

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 2,10-dimethyl-6λ⁵-[1,2,3]benzooxadiphosphole[2,3-b][1,2,3]benzooxadiphosphol-6-one
• 英文别名: 2,10-Dimethyl-[1,2,3]benzoxadiphospholo[2,3-b][1,2,3]benzoxadiphosphole 6-oxide
• 化学式: C₁₄H₁₂O₃P₂
• 分子量: 290.195
• InChiKey: IJAPODIUEFNRHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  magnesium,1-methoxy-4-methylbenzene-6-ide,bromide 在 三氯化铝 、 三氯化磷 作用下， 以 四氢呋喃 为溶剂， 反应 8.5h， 生成 2,10-dimethyl-6λ⁵-[1,2,3]benzooxadiphosphole[2,3-b][1,2,3]benzooxadiphosphol-6-one
  参考文献：
  名称：

  A New Performance of the Reaction of PCl3/AlCl3 with Anisoles − One-Pot and Multi-Step Syntheses of a New Fused-Ring System [1,2,3]Benzoxadiphospholo[2,3-b][1,2,3]benzoxadiphosphole

  摘要：

  Anisoles 4 react with AlCl3 and PCl3 to yield the new fused bicyclic system derivatives 5 and 6 as major products in a one-pot procedure. An alternative multi-step synthesis of this system is also reported in which bis(o-methoxyaryl)phosphane oxides 11 are treated with AlCl3 and PCl3; the diarylphosphane oxides 11 are obtained by a new simple method.

  DOI：

  10.1002/1099-0690(200106)2001:12<2229::aid-ejoc2229>3.0.co;2-t

文献信息

• A New Performance of the Reaction of PCl3/AlCl3 with Anisoles − One-Pot and Multi-Step Syntheses of a New Fused-Ring System [1,2,3]Benzoxadiphospholo[2,3-b][1,2,3]benzoxadiphosphole
  作者：Graziano Baccolini、Michele Bazzocchi、Carla Boga

  DOI：10.1002/1099-0690(200106)2001:12<2229::aid-ejoc2229>3.0.co;2-t

  日期：2001.6

  Anisoles 4 react with AlCl3 and PCl3 to yield the new fused bicyclic system derivatives 5 and 6 as major products in a one-pot procedure. An alternative multi-step synthesis of this system is also reported in which bis(o-methoxyaryl)phosphane oxides 11 are treated with AlCl3 and PCl3; the diarylphosphane oxides 11 are obtained by a new simple method.