N1,N3,N5-tricyclohexylbenzene-1,3,5-tricarboxamide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N1,N3,N5-tricyclohexylbenzene-1,3,5-tricarboxamide
• 英文别名: N,N',N''-tricyclohexyl-1,3,5-benzamide；trimesic acid tris(cyclohexylamide)；1,3,5-Benzenetricarboxylic acid tris(cyclohexylamide)；1-N,3-N,5-N-tricyclohexylbenzene-1,3,5-tricarboxamide
• 化学式: C₂₇H₃₉N₃O₃
• 分子量: 453.625
• InChiKey: LNYGCDOWFJXOSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  87.3
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  均苯三甲酸 、 环己胺 在 三光气 、 N,N-二甲基甲酰胺 作用下， 以 乙酸乙酯 为溶剂， 反应 15.5h， 以94.8%的产率得到N1,N3,N5-tricyclohexylbenzene-1,3,5-tricarboxamide
  参考文献：
  名称：

  用均苯三甲酸生产N, Nˊ,Nˊˊ-三环己 基-1,3,5-苯酰胺的工艺

  摘要：

  本发明公开了一种用均苯三甲酸生产N,Nˊ,Nˊˊ?三环己基?1,3,5?苯酰胺的工艺，先用均苯三甲酸和三光气在引发剂存在下、乙酸乙酯介质中合成均苯三甲酰氯，之后不需处理连同产物及溶剂滴加入含有环己胺和乙酸乙酯介质的反应釜中，滴加过程中严格控温以使体系温度低于40℃，滴加完毕后升温至78℃，反应6?10小时，停止加热，降温至60℃以下，抽滤，碾碎所得滤饼得粗产品，沸水洗涤粗产品，抽滤，再用NaOH溶液洗涤所得滤饼，抽滤，再用清水洗涤滤饼，抽滤，干燥，既得白色粉末N,Nˊ,Nˊˊ?三环己基?1,3,5?苯酰胺。本发明生产工艺方法原料易得、工艺操作简单、所得产品纯度高、颜色好、易于工业化。

  公开号：

  CN104230739B

文献信息

• USE OF PHOSPHOROUS-CONTAINING ORGANIC OXYIMIDES AS FLAME RETARDANTS AND/OR AS STABILIZERS FOR PLASTICS, FLAME-RETARDANT AND/OR STABILIZED PLASTIC COMPOSITIONS, METHOD FOR THE PRODUCTION THEREOF, MOULDED PART, PAINT AND COATINGS
  申请人：FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.

  公开号：US20170260366A1

  公开（公告）日：2017-09-14

  The present invention relates to the use of phosphorous-containing organic oxyimides according to the general formula (I) as flame retardant for plastic materials, as radical generators in plastic materials and/or stabilisers for plastics. In addition, the present invention relates to a flame-retardant plastic material moulding compound in which the previously described phosphorous-containing organic oxyimides are integrated, and also to a method for the production of the previously mentioned plastic material composition. Furthermore, the present invention relates to a moulded article, a paint or a coating from the previously mentioned flame-retardant plastic material composition.

  本发明涉及根据一般式(I)的含磷有机氧亚胺化合物作为塑料材料的阻燃剂，作为塑料材料中的自由基发生剂和/或塑料的稳定剂。此外，本发明涉及一种阻燃塑料材料成型复合物，其中集成了前述的含磷有机氧亚胺化合物，并且涉及一种用于制备前述塑料材料组合物的方法。此外，本发明涉及一种从前述阻燃塑料材料组合物制成的成型制品、涂料或涂层。
• POLYESTER RESIN COMPOSITION CONTAINING AMINO-TRIAZINE DERIVATIVE
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20160194477A1

  公开（公告）日：2016-07-07

  A polyester resin composition containing 100 parts by mass of a polyester resin and 0.01 to 10 parts by mass of a 2-amino-1,3,5-triazine derivative of Formula [1]: a polyester resin molded body obtained by the composition, and a crystal nucleating agent including the triazine derivative. A polyester resin composition containing a crystal nucleating agent that makes it possible to produce, with high productivity, a polyester resin molded product that promotes polyester resin crystallization and maintains high transparency after crystallization and is applicable for a wide variety of uses can be provided.

  一种聚酯树脂组合物，包含100质量部的聚酯树脂和0.01至10质量部的公式[1]中2-氨基-1,3,5-三嗪衍生物；通过该组合物获得的聚酯树脂成型体，以及包括三嗪衍生物的晶核剂。可以提供一种聚酯树脂组合物，包含能够高效生产聚酯树脂成型产品的晶核剂，促进聚酯树脂结晶并在结晶后保持高透明度，适用于各种用途。
• COMPOSITION AND FIRE-RETARDANT RESIN COMPOSITION
  申请人：ADEKA CORPORATION

  公开号：US20210171833A1

  公开（公告）日：2021-06-10

  A heat-resistant composition useful as a flame retardant, a flame retardant composition containing the same, and a flame-retardant resin composition are provided. The composition contains 20 to 50 parts by mass of a specific melamine salt as component (A), 50 to 80 parts by mass of a specific piperazine salt as component (B), and 1 to 50 parts by mass of a phosphoric ester compound having a specific structure as component (C), wherein the sum of the components (A) and (B) is 100 parts by mass.

  提供一种作为阻燃剂有用的耐热组合物，包含该组合物的阻燃剂组合物以及阻燃树脂组合物。该组合物包含20至50质量份的特定三聚氰胺盐作为组分（A），50至80质量份的特定哌嗪盐作为组分（B），以及1至50质量份具有特定结构的磷酸酯化合物作为组分（C），其中组分（A）和（B）的总和为100质量份。
• A POLYLACTIC ACID STEREOCOMPLEX COMPOSITION, ITS MOLDED PRODUCT, A PROCESS FOR ITS MANUFACTURE AND ITS APPLICATION
  申请人：INSTITUTE OF CHEMISTRY ACADEMY OF SCIENCES

  公开号：US20160272811A1

  公开（公告）日：2016-09-22

  The instant invention discloses a polylactic acid stereocomplex composition containing pure stereocomplex crystals and a process for its manufacture. The composition according to this invention comprising (a) 30-70 wt % poly (L-lactic acid) (PLLA). (b) 70-30 wt % poly (D-lactic acid) (PDLA) and (c) 0.01-10 wt % nucleating agent, which can be obtained by solution and melt blending. Stereocomplex crystals are preferentially formed according to the invention, and the homocrystals (a crystal form) for the PLLA or PDLA homopolymer can't be observed. The melting temperature of the composition according to the invention is at least 200° C., which is about 30-50° C. higher than the PLLA or PDLA homopolymer.

  本发明揭示了一种聚乳酸立体互穴复合物组合物以及其制造方法。该发明的组合物包括(a) 30-70重量％的聚(L-乳酸)(PLLA)。(b) 70-30重量％的聚(D-乳酸)(PDLA)和(c) 0.01-10重量％的成核剂，可以通过溶液和熔融混合获得。根据本发明，立体互穴复合物晶体首选形成，PLL或PDLA单体的同晶体（一种晶体形式）不能被观察到。根据本发明，该组合物的熔点温度至少为200℃，比PLL或PDLA单体高约30-50℃。
• POLYOLEFIN RESIN COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2319882A1

  公开（公告）日：2011-05-11

  The present invention provides a polyolefin-based resin composition containing a crystal nucleating agent having a specific structure, which polyolefin-based resin composition has a superior transparency and whose crystallization is facilitated. The polyolefin-based resin composition is characterized by comprising, with respect to 100 parts by mass of a polyolefin-based resin, 0.01 to 1 parts by mass of at least one crystal nucleating agent selected from the group consisting of crystal nucleating agents each having a structure represented by one of the following Formulae (1) to (6):

  本发明提供了一种含有具有特定结构的成核剂的聚烯烃基树脂组合物，该聚烯烃基树脂组合物具有优越的透明度，并有利于其结晶。 该聚烯烃基树脂组合物的特征是，相对于 100 质量份的聚烯烃基树脂，含有 0.01 至 1 质量份的至少一种成核剂，该成核剂选自具有下式（1）至（6）之一结构的成核剂：