N,N,N-tris(3,4-dimethylphenyl)amine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N-tris(3,4-dimethylphenyl)amine
• 英文别名: Tris(3,4-dimethylphenyl)amine；N,N-bis(3,4-dimethylphenyl)-3,4-dimethylaniline
• 化学式: C₂₄H₂₇N
• 分子量: 329.485
• InChiKey: DJTPVVSMKXCQDF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  25
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4-硝基邻二甲苯 在 bis(acetylacetonato)palladium(II) 、 2-(二环己基膦)3,6-二甲氧基-2′,4′,6′-三异丙基-1,1′-联苯 、 caesium carbonate 、 联硼酸频那醇酯 作用下， 以 甲苯 为溶剂， 以63 %的产率得到N,N,N-tris(3,4-dimethylphenyl)amine
  参考文献：
  名称：

  硝基芳烃作为亲电子试剂和芳胺替代物在 Buchwald-Hartwig 型 C-N 键构建偶联中的双重作用

  摘要：

  构建 C(sp 2 )–N 键最广泛使用的方法之一是过渡金属催化的芳基卤化物/硼酸与胺的交叉偶联，称为乌尔曼缩合、Buchwald-Hartwig 胺化和 Chan –拉姆联轴器。然而，芳基卤化物/硼酸通常需要多步制备，同时产生大量腐蚀性和有毒废物，使得该反应不太有吸引力。在此，我们提出了一种前所未有的方法，通过Buchwald-Hartwig 型反应形成 C(sp 2 )–N，使用合成上游硝基芳烃作为唯一起始原料，从而消除了对芳基卤化物和预先形成的芳基胺的需要。从硝基芳烃一步获得了多种对称的二芳基胺和三芳基胺，更重要的是，还通过一锅/两步法高选择性地合成了各种不对称的二芳基胺和三芳基胺。此外，放大实验的成功、药物中间体的后期功能化以及空穴传输材料TCTA的快速制备展示了该方案在合成化学中的实用性和实用性。机理研究表明，这种转化可能通过硝基芳烃还原原位生成的芳胺中间体进行，随后与另一种硝基芳烃发生脱硝

  DOI：

  10.1039/d3sc06618e

文献信息

• Triarylamine compound, process for producing the same and electrophotographic photoreceptor using the same
  申请人：FUJI XEROX CO., LTD.

  公开号：EP0617005A2

  公开（公告）日：1994-09-28

  A triarylamine compound useful as a charge transport material of an electrophotographic photoreceptor, which represented by formula (I) wherein Ar1 and Ar2 each represents a phenyl group or a condensed ring group.

  一种可用作电致发光感光元件电荷传输材料的三芳基胺化合物，由式（I）表示 其中 Ar1 和 Ar2 各代表一个苯基或一个缩合环基。
• Ligand-Accelerated Catalysis of the Ullmann Condensation:  Application to Hole Conducting Triarylamines
  作者：H. Bruce Goodbrand、Nan-Xing Hu

  DOI：10.1021/jo981804o

  日期：1999.1.1
• IMAGING MEMBER
  申请人：Tong Yuhua

  公开号：US20090325094A1

  公开（公告）日：2009-12-31

  Provided is an imaging member such as photoreceptor comprising a substrate, a charge generation layer, a first charge transport layer, a second charge transport layer, and an optional overcoat layer. The first charge transport layer is formed from a first CTL formulation comprising an aromatic monoamine and a first polymeric film forming binder material. The second charge transport layer is formed from a second CTL formulation comprising aromatic diamine and a second polymeric film forming binder material. The imaging member has gained improved properties such as removal of anti-curl layer, desirable structural flatness, electrical properties, mechanical robustness, flexibility, longevity, and copy image qualities over extended use, among others.
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：HODOGAYA CHEMICAL CO., LTD.

  公开号：US20170179398A1

  公开（公告）日：2017-06-22

  The organic EL device of the present invention has an anode, a hole transport layer, a luminous layer, an electron transport layer, and a cathode in this order, and the hole transport layer contains an arylamine compound represented by the following general formula (1): where Ar 1 to Ar 4 each represent a monovalent aromatic hydrocarbon group or a monovalent aromatic heterocyclic group.
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：HODOGAYA CHEMICAL CO., LTD.

  公开号：US20180026198A1

  公开（公告）日：2018-01-25

  The organic EL device of the present invention has an anode, a hole transport layer, a luminous layer, an electron transport layer, and a cathode in the order of description. The hole transport layer includes an arylamine compound represented by the following general formula (1): in the formula, Ar 1 to Ar 4 each represent a monovalent aromatic hydrocarbon group or a monovalent aromatic heterocyclic group, and the luminous layer includes an N-aromatic substituted nitrogen-containing heterocyclic compound.