(5-Pentafluorobenzoyloxyimino-5H-thiophen-2-ylidene)-(2-methylphenyl)-acetonitrile

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (5-Pentafluorobenzoyloxyimino-5H-thiophen-2-ylidene)-(2-methylphenyl)-acetonitrile
• 英文别名: [(Z)-[(5E)-5-[cyano-(2-methylphenyl)methylidene]thiophen-2-ylidene]amino] 2,3,4,5,6-pentafluorobenzoate
• 化学式: C₂₀H₉F₅N₂O₂S
• 分子量: 436.362
• InChiKey: DSQUZOOIGSNBFK-LYZNJHNGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  30
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  87.8
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  (5-Hydroxyimino-5H-thiophen-2-ylidene)-(2-methylphenyl)-acetonitrile 、 五氟苯甲酰氯 在 三乙胺 作用下， 以 四氢呋喃 、 水 为溶剂， 生成 (5-Pentafluorobenzoyloxyimino-5H-thiophen-2-ylidene)-(2-methylphenyl)-acetonitrile
  参考文献：
  名称：

  Oxime derivatives and the use thereof as latent acids

  摘要：

  式(I)或(II)的新羟肟衍生物，其中m为0或1；R1等为苯基、萘基、蒽基、菲基或杂环芳基；R′1例如为C2-C12烷基、苯基、萘基；R2为CN；R3为C2-C6卤代烷酰基、卤代苯甲酰基、磷酰基或有机硅基；R4、R5、R10和R11等为氢、C1-C6烷基、C1-C6烷氧基；R6等为氢、苯基、C1-C12烷基；R7和R8等为氢、C1-C12烷基；或者R7和R8与它们连接的氮原子一起形成5、6或7元环；R9例如为C1-C12烷基；A等为硫、氧、NR7a等；在光刻胶应用中作为潜在酸是有用的。

  公开号：

  US06485886B1

文献信息

• OXIME DERIVATIVES AND THE USE THEREOF AS LATENT ACIDS
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1124832A1

  公开（公告）日：2001-08-22
• US6485886B1
  申请人：——

  公开号：US6485886B1

  公开（公告）日：2002-11-26
• [EN] OXIME DERIVATIVES AND THE USE THEREOF AS LATENT ACIDS<br/>[FR] DERIVES D'OXIME ET LEUR UTILISATION EN TANT QU'ACIDES LATENTS
  申请人：CIBA SC HOLDING AG

  公开号：WO2000026219A1

  公开（公告）日：2000-05-11

  New oxime derivatives of formula (I) or (II), wherein m is 0 or 1; R1 inter alia is phenyl, naphthyl, anthracyl, phenanthryl or a heteroaryl radical; R'1 is for example C2-C12alkylene, phenylene, naphthylene; R2 is CN; R3 is C2-C6haloalkanoyl, halobenzoyl, a phosphoryl or an organosilyl group; R4, R5, R10 and R11 inter alia are hydrogen, C1-C6alkyl, C1-C6alkoxy; R6 inter alia is hydrogen, phenyl, C1-C12alkyl; R7 and R8 inter alia are hydrogen, C1-C12alkyl; or R7 and R8, together with the nitrogen atom to which they are bonded, form a 5-, 6- or 7-membered ring; R9 is for example C1-C12alkyl; and A inter alia is S, O, NR7a; are useful as latent acids, especially in photoresist applications.
• Oxime derivatives and the use thereof as latent acids
  申请人：Ciba Specialty Chemicals Corporation

  公开号：US06485886B1

  公开（公告）日：2002-11-26

  New oxime derivatives of formula (I) or. (II), wherein m is 0 or 1; R1 inter alia is phenyl, naphthyl, anthracyl, phenanthryl or a heteroaryl radical; R′1 is for example C2-C12alkylene, phenylene, naphthylene; R2 is CN; R3 is C2-C6haloalkanoyl, halobenzoyl, a phosphoryl or an organosilyl group; R4, R5, R10 and R11 inter alia are hydrogen, C1-C6alkyl, C1-C6alkoxy; R6 inter alia is hydrogen phenyl, C1-C12alkyl; R7 and R8 inter alia are hydrogen, C1-C12alkyl; or R7 and R8, together with the nitrogen atom to which they are bonded, form a 5-, 6 or 7-membered ring; R9 is for example C1-C12alkyl; and A inter alia is S, O, NR7a; are useful as latent acids, especially in photoresist applications.

  式(I)或(II)的新羟肟衍生物，其中m为0或1；R1等为苯基、萘基、蒽基、菲基或杂环芳基；R′1例如为C2-C12烷基、苯基、萘基；R2为CN；R3为C2-C6卤代烷酰基、卤代苯甲酰基、磷酰基或有机硅基；R4、R5、R10和R11等为氢、C1-C6烷基、C1-C6烷氧基；R6等为氢、苯基、C1-C12烷基；R7和R8等为氢、C1-C12烷基；或者R7和R8与它们连接的氮原子一起形成5、6或7元环；R9例如为C1-C12烷基；A等为硫、氧、NR7a等；在光刻胶应用中作为潜在酸是有用的。