2,3-diphenyltetrahydro-2H-pyran

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 2,3-diphenyltetrahydro-2H-pyran
• 英文别名: 2,3-Diphenyloxane；2,3-diphenyloxane
• 化学式: C₁₇H₁₈O
• 分子量: 238.329
• InChiKey: ZIPFCDUEBVSXMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  5-苯基-4-戊炔-1-醇 在 palladium 10% on activated carbon 、 氢气 、 copper(II) bis(trifluoromethanesulfonate) 作用下， 以 乙酸乙酯 、 1,2-二氯乙烷 为溶剂， 20.0~60.0 ℃ 、1.0 MPa 条件下， 反应 12.0h， 生成 2,3-diphenyltetrahydro-2H-pyran
  参考文献：
  名称：

  铜催化的烷氧基炔烃与二芳基碘鎓盐的分子内芳基醚化反应，可通过裂解稳定的CO键进行。

  摘要：

  实现了一种新型的铜催化的烷氧基炔烃与二芳基碘鎓盐的分子内芳基醚化反应。反应平稳进行，通过裂解稳定的CO键，生成具有容易获得的线性起始原料的有价值的氧杂环。

  DOI：

  10.1039/c4cc08363f

文献信息

• [EN] HYDROCARBON SYNTHESIS METHODS, APPARATUS, AND SYSTEMS<br/>[FR] PROCÉDÉS, APPAREIL ET SYSTÈMES DE SYNTHÈSE D'HYDROCARBURES
  申请人：MCNEFF CLAYTON V

  公开号：WO2014008355A1

  公开（公告）日：2014-01-09

  Embodiments of the invention include apparatus and systems for hydrocarbon synthesis and methods regarding the same. In an embodiment, the invention includes a process for creating a hydrocarbon product stream comprising reacting a reaction mixture in the presence of a catalyst inside of a reaction vessel to form a product mixture, the reaction mixture comprising a carbon source and water. The temperature inside the reaction vessel can be between 450 degrees Celsius and 600 degrees Celsius and the pressure inside the reaction vessel can be above supercritical pressure for water. In an embodiment, the invention includes an extrusion reactor system for creating a hydrocarbon product stream. The temperature inside the extrusion reactor housing between 450 degrees Celsius and 600 degrees Celsius. Pressure inside the reaction vessel can be above supercritical pressure for water. Other embodiments are also included herein.

  本发明的实施例包括用于合成碳氢化合物的设备和系统以及相关方法。在一种实施例中，本发明包括一种用于创建碳氢化合物产品流的过程，其中在反应容器内，在催化剂的存在下，反应混合物以形成产物混合物，反应混合物包括碳源和水。反应容器内的温度可在450摄氏度至600摄氏度之间，反应容器内的压力可高于水的超临界压力。在一种实施例中，本发明包括一种挤出反应器系统，用于创建碳氢化合物产品流。挤出反应器壳体内的温度在450摄氏度至600摄氏度之间。反应容器内的压力可高于水的超临界压力。本发明还包括其他实施例。
• HYDROCARBON SYNTHESIS METHODS, APPARATUS, AND SYSTEMS
  申请人：SarTec Corporation

  公开号：US20140046104A1

  公开（公告）日：2014-02-13

  Embodiments of the invention include apparatus and systems for hydrocarbon synthesis and methods regarding the same. In an embodiment, the invention includes a process for creating a hydrocarbon product stream comprising reacting a reaction mixture in the presence of a catalyst inside of a reaction vessel to form a product mixture, the reaction mixture comprising a carbon source and water. The temperature inside the reaction vessel can be between 450 degrees Celsius and 600 degrees Celsius and the pressure inside the reaction vessel can be above supercritical pressure for water. In an embodiment, the invention includes an extrusion reactor system for creating a hydrocarbon product stream. The temperature inside the extrusion reactor housing between 450 degrees Celsius and 600 degrees Celsius. Pressure inside the reaction vessel can be above supercritical pressure for water. Other embodiments are also included herein.
• US9388345B2
  申请人：——

  公开号：US9388345B2

  公开（公告）日：2016-07-12
• Cu-catalyzed intramolecular aryl-etherification reactions of alkoxyl alkynes with diaryliodonium salts via cleavage of a stable C–O bond
  作者：Jing Chen、Chao Chen、Junjie Chen、Guohua Wang、Hongmei Qu

  DOI：10.1039/c4cc08363f

  日期：——

  A novel Cu-catalyzed intramolecular aryl-etherification reaction of alkoxyl alkynes with diaryliodonium salts is realized. The reactions proceed smoothly to produce valuable oxo-heterocycles with readily available linear starting materials via cleavage of a stable C-O bond.

  实现了一种新型的铜催化的烷氧基炔烃与二芳基碘鎓盐的分子内芳基醚化反应。反应平稳进行，通过裂解稳定的CO键，生成具有容易获得的线性起始原料的有价值的氧杂环。