[(η5-C5Me5Co)2(μ-toluene)]

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(η5-C5Me5Co)2(μ-toluene)]
• 英文别名: [((η5-pentamethylcyclopentadienyl)Co)2(μ-η6:η6-toluene)]；[((η5-pentamethylcyclopentadienyl)Co)2(η6:η6-toluene)]；(((η(5)-Me5C5)Co)2(μ-(η(6):η(6)-toluene))
• 化学式: C₂₇H₃₈Co₂
• 分子量: 480.585
• InChiKey: WJSRZXPIYULXJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.93
• 重原子数：
  29
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  [(η5-C5Me5Co)2(μ-toluene)] 以 正戊烷 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Schneider, Joerg J., Zeitschrift fur Naturforschung, B: Chemical Sciences, 1995, vol. 50, # 7, p. 1055 - 1060

  摘要：

  DOI：

文献信息

• Fluorenone and Fluorene Complexes with a Slipped Triple Decker Structure DisplayingVariable Hapticity of ((Pentaalkyl)cyclopentadienyl)cobalt(I) Fragments
  作者：Shengli Guo、Ralf Hauptmann、Jörg J. Schneider

  DOI：10.1002/zaac.200700218

  日期：2007.10

  The reaction of the toluene triple decker complexes [(η5-Me5C5)Co}2μ-(η6:η6-toluene)] and [(η5-EtMe4C5)Co}2μ-(η6:η6-toluene)] with fluorenone leads to the first triple decker compounds [(η5-Me5C5)Co}2μ-(η5:η4-fluorenone)] (1) and [(η5-EtMe4C5)Co}2μ-(η5:η4-fluorenone)] (2) of this ligand. In 1 and 2 two [(η5-RMe4C5)Co] fragments are bridged by a fluorenone ligand. One Co atom in 1 and 2 is coordinated

  甲苯三重复合物 [(η5-Me5C5) Co} 2μ- (η6: η6-甲苯)] 和 [(η5-EtMe4C5) Co} 2μ- (η6: η6-甲苯)] 与芴酮的反应到第一个三层化合物 [(η5-Me5C5) Co} 2μ- (η5: η4-芴酮)] (1) 和 [(η5-EtMe4C5) Co} 2μ- (η5: η4-芴酮)] (2 ) 这种配体。在 1 和 2 中，两个 [(η5-RMe4C5) Co] 片段由芴酮配体桥接。1 和 2 中的一个 Co 原子以 η5 方式与芴酮配体的五元环配位，而另一个 Co 原子以 η4 方式与六元环配位。[(η5-Me5C5) Co} 2μ- (η6: η6-甲苯)] 与 9H-芴的反应导致形成第一个滑动三层 [(η5-Me5C5) Co} 2μ- (η5: η3-1H-芴)] (3) 这种配体。一个 (η5-Me5C5) Co} 片段通过六元环之一以
• 1,1′ Ferrocenylenediol as chelating ligand for cobalt in fivefold and sixfold coordination geometry: Synthesis, Electrochemistry and X-ray crystal structure of [{((1,1′ O2(η5-C5H5)2Fe)2}Co(OEt2){(η5-Me5C5)Co}2] and [{((1,1′ O2(η5-C5H5)2Fe)3}Co((η5-EtMe4C5)Co)2]
  作者：Shengli Guo、Ralf Hauptmann、Serena Losi、Piero Zanello、Jörg J. Schneider

  DOI：10.1016/j.jorganchem.2008.11.042

  日期：2009.4

  compounds 3 and 4 were synthesized by reaction of 1,1′ ferrocenylenediol with the Co triple decker compounds [(η5-Me5C5)Co}2(η6:η6-toluene)] and [(η5-EtMe4C5)Co}2(η6:η6-toluene)], respectively. The central Co atom of 3 is coordinated by five O atoms in a square-pyramidal manner. The remaining two Co atoms of 3 are coordinated to a Me5C5 ligand in a η5-fashion and by the two O atoms of two 1,1′ ferrocenylenediolato

  标题化合物3和4是由1,1'ferrocenylenediol的反应与联合三重双层化合物合成[（η 5 -Me 5 Ç 5）有限} 2（η 6：η 6 -甲苯）]和[（ η 5 -EtMe 4 ç 5）有限} 2（η 6：η 6 -甲苯）]中。的中心钴原子3是通过在四方锥方式5个O原子配位。中的其余两个Co原子3被配位到我5 Ç 5配位体在一个η 5-形成并通过两个1,1'二茂铁基亚乙基二醇基配体的两个O原子作为螯合配体。在4，中央钴原子配位到ferrocenylenediolato在三角棱柱形的方式配体3的所有六个O原子，而两个其它的Co原子由一个EtMe协调4 Ç 5配位体在一个η 5 -时尚和由三个氧三个二茂铁基乙二醇配体的原子导致4的整体三体结构。
• Synthesis and structure of mono- and dinuclear cyclopentadienyl–indenyl complexes of iron(II) and further reactions to mixed tri- and tetranuclear iron–cobalt complexes
  作者：Shengli Guo、Ildiko Balog、Ralf Hauptmann、Mathias Nowotny、Jörg J. Schneider

  DOI：10.1016/j.jorganchem.2008.11.024

  日期：2009.4

  The reaction of a mixture of sodium cyclopentadienide and the monolithium salt or dilithium salt of 2,2-bis(indenyl)propane with FeCl2 leads to the mononuclear complex [(eta(5)-C5H5)Fe(eta(5)-ind-C(CH3)(2)-ind)] (ind = 1-indenyl) (1) and the dinuclear complex [(eta(5)-C5H5)Fe(eta(5)-ind)}(2)C(CH3)(2)] (2), respectively. [(eta(5)-Me5C5)Fe(tmeda)Cl] reacts with dilithium 1,1'-biindenyl under formation of [(eta(5)-Me5C5)Fe}(2)(mu-eta(5):eta(5)-1,1'-biind)] (4). Due to the annelated arene rings of the eta(5)-indenyl ligands, 2 and 4 may act as 4-electron donor ligands, as exemplified by the reaction with the triple-decker complex [(eta(5)-Me5C5)Co}(2)(mu-eta(6):eta(6)-toluene)], which afforded the tetranuclear dimer of triple-decker complexes [(eta(5)-C5H5)Fe(eta(5)-Me5C5)-Co(mu-eta(5):eta(4)-1-ind)}(2)C(CH3)(2)] (3) and the trinuclear complex [(eta(5)-Me5C5)Fe-2(eta(5)-Me5C5)Co(mu(3)-eta(5):eta(4):eta(5)-1,1'-biind)] center dot Et2O (5 center dot Et2O) by replacement of the central toluene deck, respectively. The [(eta(5)-Me5C5)Co] fragments of 3 and 5 are bonded via the six-membered rings of the indenyl ligands in a eta(4)-fashion. Caused by the coordination to the Co atoms the six-membered rings lose their planarity and adopt a butterfly structure. The coordination geometry of the Fe atoms is similar in all five complexes. Each Fe atom is coordinated by the C atoms of one of the five-membered rings of the indenyl ligands in a slightly distorted eta(5) manner (eta(3) + eta(2)-coordination) and by a cyclopentadienyl ligand in a regular eta(5)-fashion. The structures of 3 and 5 represent the first examples of slipped triple-decker complexes which comprise indenyl ligands in a mu-eta(5):eta(4) coordination mode. (C) 2008 Elsevier B.V. All rights reserved.
• Schneider, Joerg J.; Wolf, Dirk, Zeitschrift fur Naturforschung, B: Chemical Sciences, <hi>1998</hi>, vol. 53, # 11, p. 1267 - 1272
  作者：Schneider, Joerg J.、Wolf, Dirk

  DOI：——

  日期：——