1,2-di(9-anthryl)tetramethyldisilane

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,2-di(9-anthryl)tetramethyldisilane
• 英文别名: 1,2-Di(9-anthryl)tetramethyldisilane；anthracen-9-yl-[anthracen-9-yl(dimethyl)silyl]-dimethylsilane
• 化学式: C₃₂H₃₀Si₂
• 分子量: 470.761
• InChiKey: HMUMUQIGEVMQKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.91
• 重原子数：
  34
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,2-二氯四甲基二硅烷 、 9-溴蒽 在 正丁基锂 作用下， 以 正己烷 为溶剂， 生成 1,2-di(9-anthryl)tetramethyldisilane
  参考文献：
  名称：

  π−π and σ−π Interactions in α,ω-Di-(9-anthryl) and Di-(1-naphthyl) Oligosilanes Studied by Time-Resolved Fluorescence in Solution

  摘要：

  The photophysical properties of two series of oligosilanes, (1-naphthyl)-(SiMe2)(n)-(1-naphthyl) (1-5) and (9-anthryl)-(SiMe2)(n)-(9-anthryl) (6-10) with n = 1-4 and 6, were investigated. In these compounds, two types of interactions, a pi-pi interaction between two aromatic groups and a sigma-pi interaction between aromatics and: a silicon chain unit, were observed. Intramolecular excimer emission was observed in cyclohexane when n greater than or equal to 2. The strongest excimer emission of 2 and 7 is different from the Hirayama rule (n = 3) proposed for carbon analogues and also shows that intramolecular cycloaddition is minor. The time-resolved fluorescence speptra of an anthryl series revealed that the time constant of excimer formation varied depending on the chain length (82-152 ps). In the cases of 4, 5, and 10, charge-transfer (CT) emission was observed in acetonitrile or THF. The time constant of the CT-state formation for 10 was relatively slow (45 ps), which may indicate a conformational change. Monomer emission from the locally excited state was observed for I and 6 in both cyclohexane and acetonitrile.

  DOI：

  10.1021/jp0355760

文献信息

• Karatsu, Takashi; Shibata, Toshifumi; Nishigaki, Atsuko, Chemistry Letters, 2001, # 10, p. 994 - 995
  作者：Karatsu, Takashi、Shibata, Toshifumi、Nishigaki, Atsuko、Fukui, Keijiro、Kitamura, Akihide

  DOI：——

  日期：——
• π−π and σ−π Interactions in α,ω-Di-(9-anthryl) and Di-(1-naphthyl) Oligosilanes Studied by Time-Resolved Fluorescence in Solution
  作者：Takashi Karatsu、Toshifumi Shibata、Atsuko Nishigaki、Akihide Kitamura、Yusuke Hatanaka、Yoshinobu Nishimura、Shin-ichiro Sato、Iwao Yamazaki

  DOI：10.1021/jp0355760

  日期：2003.11.1

  The photophysical properties of two series of oligosilanes, (1-naphthyl)-(SiMe2)(n)-(1-naphthyl) (1-5) and (9-anthryl)-(SiMe2)(n)-(9-anthryl) (6-10) with n = 1-4 and 6, were investigated. In these compounds, two types of interactions, a pi-pi interaction between two aromatic groups and a sigma-pi interaction between aromatics and: a silicon chain unit, were observed. Intramolecular excimer emission was observed in cyclohexane when n greater than or equal to 2. The strongest excimer emission of 2 and 7 is different from the Hirayama rule (n = 3) proposed for carbon analogues and also shows that intramolecular cycloaddition is minor. The time-resolved fluorescence speptra of an anthryl series revealed that the time constant of excimer formation varied depending on the chain length (82-152 ps). In the cases of 4, 5, and 10, charge-transfer (CT) emission was observed in acetonitrile or THF. The time constant of the CT-state formation for 10 was relatively slow (45 ps), which may indicate a conformational change. Monomer emission from the locally excited state was observed for I and 6 in both cyclohexane and acetonitrile.