1,3,4,6-Tetrahydro-7,8,9,10-tetraphenyl-2,5-benzodithiocin

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3,4,6-Tetrahydro-7,8,9,10-tetraphenyl-2,5-benzodithiocin
• 化学式: C₃₄H₂₈S₂
• 分子量: 500.728
• InChiKey: KHCACLGMWQSSDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.83
• 重原子数：
  36.0
• 可旋转键数：
  4.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  1,4-dithia-6-cyclooctyne 、 四苯基环戊二烯酮 以62%的产率得到1,3,4,6-Tetrahydro-7,8,9,10-tetraphenyl-2,5-benzodithiocin
  参考文献：
  名称：

  Preparation of dithiacycloalkynes by cyclization reactions applying the cesium effect

  摘要：

  The strained dithiacycloalkynes 3a,b and the larger heterocyclic alkynes 3c and 4 are obtained by cesium assisted cyclization reactions of the dithiols 1a-c and 1,4-dibromo-2-butyne (2). The reactivity of 3a-c was studied in cycloaddition and complexation reactions generating the adducts 5a,b and 6 and the silver and cobalt complexes 7 and 8.

  DOI：

  10.1016/s0040-4039(00)73972-4

文献信息

• Preparation of dithiacycloalkynes by cyclization reactions applying the cesium effect
  作者：Herbert Meier、Yujia Dai

  DOI：10.1016/s0040-4039(00)73972-4

  日期：1993.8

  The strained dithiacycloalkynes 3a,b and the larger heterocyclic alkynes 3c and 4 are obtained by cesium assisted cyclization reactions of the dithiols 1a-c and 1,4-dibromo-2-butyne (2). The reactivity of 3a-c was studied in cycloaddition and complexation reactions generating the adducts 5a,b and 6 and the silver and cobalt complexes 7 and 8.
• Meier, Herbert; Dai, Yujia; Schuhmacher, Hans, Chemische Berichte, 1994, vol. 127, # 10, p. 2035 - 2042
  作者：Meier, Herbert、Dai, Yujia、Schuhmacher, Hans、Kolshorn, Heinz

  DOI：——

  日期：——