(2-苯基苯基)丙酸酯 | 54074-17-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: (2-苯基苯基)丙酸酯
• 英文名称: 2-biphenylyl propionate
• 英文别名: propionic acid biphenyl-2-yl ester；Propionsaeure-biphenyl-2-ylester；Biphenylyl-(2)-propionat；2-Propionyloxy-biphenyl；2-Propionyloxy-diphenyl；o-Diphenylylpropionat；(2-Phenylphenyl) propanoate
• CAS: 54074-17-8
• 化学式: C₁₅H₁₄O₂
• 分子量: 226.275
• InChiKey: HPTNBOLRFMQMMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2-苯基苯基)丙酸酯 在 α-chymotrypsin 作用下， 生成 邻苯基苯酚
  参考文献：
  名称：

  侧链中含有 2-联苯酯键的聚合物的酶促酯解

  摘要：

  描述了锚定杀菌剂联苯-2-醇的聚合物底物的制备和 α-胰凝乳蛋白酶催化的酯解作用。为了获得有关一种类型影响的信息...

  DOI：

  10.1246/bcsj.59.3621
• 作为产物：
  描述：

  丙酰氯 、 邻苯基苯酚 以64%的产率得到(2-苯基苯基)丙酸酯
  参考文献：
  名称：

  侧链中含有 2-联苯酯键的聚合物的酶促酯解

  摘要：

  描述了锚定杀菌剂联苯-2-醇的聚合物底物的制备和 α-胰凝乳蛋白酶催化的酯解作用。为了获得有关一种类型影响的信息...

  DOI：

  10.1246/bcsj.59.3621

文献信息

• An extremely efficient and green method for the acylation of secondary alcohols, phenols and naphthols with a deep eutectic solvent as the catalyst
  作者：Hai Truong Nguyen、Phuong Hoang Tran

  DOI：10.1039/c6ra22757k

  日期：——

  The typical deep eutectic solvent [CholineCl][ZnCl2]3 easily prepared from choline chloride and zinc chloride is green and useful for the acylation of secondary alcohols, phenols, and naphthols with acid anhydrides....

  由氯化胆碱和氯化锌容易制备的典型深共熔溶剂[CholineCl] [ZnCl2] 3是绿色的，可用于用酸酐对仲醇，酚和萘进行酰化反应。
• Preparation and Properties of Polymers Anchoring Biphenyl-2-ol
  作者：Tomomichi Ishikawa、Satoshi Asai

  DOI：10.1246/bcsj.56.2177

  日期：1983.7

  The monomer, 2-biphenylyl acrylate (BPA), was prepared and was polymerized and copolymerized with vinyl acetate (VAc), styrene and N-vinylpyrrolidone. The reactivity ratios of BPA (M1) with VAc were evaluated as r1=4.6+0.4 and r2=0.37+0.08. The polymers were hydrolyzed in methanol–phosphate buffer solution(pH 6 and 8), and the release rate of biphenyl-2-ol from the polymer was investigated.

  制备了单体 2-丙烯酸联苯酯（BPA），并将其与醋酸乙烯酯（VAc）、苯乙烯和 N-乙烯基吡咯烷酮进行聚合和共聚。双酚 A（M1）与醋酸乙烯酯（VAc）的反应比分别为 r1=4.6+0.4 和 r2=0.37+0.08。聚合物在甲醇-磷酸盐缓冲溶液（pH 值为 6 和 8）中水解，并研究了聚合物中联苯-2-醇的释放率。
• NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY AND MATERIAL FOR USE IN SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3567663A1

  公开（公告）日：2019-11-13

  In a lithium ion secondary battery according to one embodiment of the present invention, an electrode includes an electrode active material, a conductive auxiliary agent, and a binding material configured by a binding component that binds the conductive auxiliary agent and forms a conduction path between the electrode active material, and by a melting point depressant that lowers a melting point of the binding component. The melting point depressant is a PTC functionality-imparting component that lowers the melting start temperature of the binding material and imparts the PTC functionality to the lithium ion secondary battery. The lithium ion secondary battery according to the invention is configured such that, when short circuit heat generation has occurred within the battery due to a conductive foreign substance, the binding material at a periphery of the foreign substance melts to sever the conduction path.

  在根据本发明一个实施例的锂离子二次电池中，电极包括电极活性材料、导电辅助剂和结合材料，结合材料由结合导电辅助剂并在电极活性材料之间形成传导路径的结合成分和降低结合成分熔点的熔点抑制剂配置而成。熔点抑制剂是一种 PTC 功能赋予成分，可降低结合材料的熔点起始温度，并将 PTC 功能赋予锂离子二次电池。根据本发明，锂离子二次电池的构造是，当导电异物在电池内产生短路热量时，异物外围的结合材料熔化，切断传导路径。
• Harris; Christiansen, Journal of the American Pharmaceutical Association (1912), 1934, vol. 23, p. 530,534
  作者：Harris、Christiansen

  DOI：——

  日期：——
• Synthetic Estrogens. Phenyl and Benzyl Hexestrols and Dienestrols^1,2
  作者：J. B. Niederl、R. M. Silverstein

  DOI：10.1021/ja01182a054

  日期：1948.2