(2Z)-2-丁烯二酸与N,N-二乙基乙胺化合物 | 1069-58-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: (2Z)-2-丁烯二酸与N,N-二乙基乙胺化合物
• 英文名称: triethylammonium maleate
• 英文别名: (Triethylammonium) maleate；(Z)-but-2-enedioic acid;N,N-diethylethanamine
• CAS: 1069-58-5
• 化学式: C₄H₄O₄*C₆H₁₅N
• 分子量: 217.265
• InChiKey: BGBNXIKULUCCOO-BTJKTKAUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.06
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  77.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  氯乙腈 、 (2Z)-2-丁烯二酸与N,N-二乙基乙胺化合物 生成 Maleinsaeure-monocyanmethylester
  参考文献：
  名称：

  Helferich,B.; Arndt,O., Justus Liebigs Annalen der Chemie, 1965, vol. 687, p. 172 - 175

  摘要：

  DOI：
• 作为产物：
  描述：

  马来酸酐 、 三乙胺 以 氯仿 为溶剂， 反应 2.0h， 生成 (2Z)-2-丁烯二酸与N,N-二乙基乙胺化合物
  参考文献：
  名称：

  蒽酮Diels-Alder反应的协同催化。

  摘要：

  [反应：见正文]胺碱和路易斯酸（Li +）的组合导致蒽酮与巴豆酸甲酯和其他一些反应性较低的亲二烯体的Diels-Alder反应的协同催化作用。这些环加成要么与单独使用的单独的催化剂一起发生，要么被组合的催化剂大大促进。DMSO溶剂允许使用LiCl作为路易斯酸源，并可以更好地控制后续转化为迈克尔加合物的过程。

  DOI：

  10.1021/ol025760o

文献信息

• Pigment dispersions containing copolymer pigment dispersants and methods of grinding pigment dispersions
  申请人：HÜLS AMERICA INC. (a Delaware corporation)

  公开号：EP0033213A2

  公开（公告）日：1981-08-05

  Low-molecular weight addition copolymers of (1) (meth) acrylic acid esters of alcohols such as methanol and butanol with (2) (meth) acrylic acid esters of alcohols such as N-(β-hydroxyethyl)oxazolidine, optionally including (3) α,β-ethylenically-unsaturated monomers such as (meth)acrylic acid, (where in each instance "(meth)acrylic" means acrylic or methacrylic or both) are used as dispersants for inorganic and organic pigments and colourants which are insoluble in organic solvents, for lacquers. These pigment dispersants are compatible with practically all types of lacquer resins, such as vinyls, nitrocellulose and alkyds, and also with many other types of lacquer film-forming materials. Usually, when small amounts of unsaturated carboxylic acids, or other polar monomers and combinations thereof, are incorporated in the polymers, they become improved pigment dispersants. Such pigment dispersions, unexpectedly, can be let down with many types of synthetic resins and used by air-drying or baking the coated articles. Lacquers for metals, paints and printing inks are examples of uses for such blends.

  (1)甲醇和丁醇等醇的(甲基)丙烯酸酯与(2)N-(β-羟乙基)恶唑烷等醇的(甲基)丙烯酸酯的低分子量加成共聚物，可选择包括(3)α、β-乙烯基不饱和单体，如(甲基)丙烯酸（这里的"(甲基)丙烯酸 "是指丙烯酸或甲基丙烯酸或两者），可用作不溶于有机溶剂的无机和有机颜料和着色剂的分散剂，如漆。这些颜料分散剂几乎与所有类型的漆树脂兼容，如乙烯基、硝化纤维和醇酸树脂，也与许多其他类型的漆成膜材料兼容。通常情况下，当聚合物中加入少量不饱和羧酸或其他极性单体及其组合时，它们就会成为经过改良的颜料分散剂。出乎意料的是，这种颜料分散剂可以与多种类型的合成树脂混合，并通过风干或烘烤涂覆物品来使用。金属漆、油漆和印刷油墨就是此类混合物的应用实例。
• Composition for film formation, method of film formation, and silica-based film
  申请人：JSR CORPORATION

  公开号：US20030091838A1

  公开（公告）日：2003-05-15

  A composition for film formation which comprises: (A) a product of hydrolysis and condensation obtained by hydrolyzing and condensing at least one silane compound selected from the group consisting of compounds represented by the formula (1), compounds represented by the formula (2), and compounds represented by the formula (3) in the presence of water and an ammonium compound, and (B) an organic solvent.

  一种用于成膜的组合物，它包括 (A) 至少一种硅烷化合物的水解和缩合产物，该硅烷化合物选自由式（1）、式（2）和式（3）所代表的化合物组成的组，在水和铵化合物存在下水解和缩合得到，以及 (B) 有机溶剂。
• Compositions for producing aminoplast products and method for producing products from these compositions
  申请人：Ratzsch Manfred

  公开号：US20050250896A1

  公开（公告）日：2005-11-10

  Compositions for producing aminoplast products by means of melt processing consisting of: A) 95 to 99.9% by mass of solvent-free meltable polycondensates of melamine resins having molar masses ranging from 300 to 300 000; A) from 0.1 to 5% by mass of weak acids serving as thermoinducible curing agents consisting of: acidifiers of the blocked sulfonic acid type; aliphatic C 4 -C 18 carboxylic acids; aromatic C 7 -C 18 carboxylic acids; alkali salts or ammonium salts of phosphoric acid; C 1 -C 12 -alkyl esters or C 2 -C 8 -hydroxyalkyl esters of C 7 -C 14 aromatic carboxylic acids or of inorganic acids; salts of melamine or of guanamines having C 1-18 aliphatic carboxylic acids; anhydrides, half-esters or half-amides of C 4 -C 20 dicarboxylic acids; half-esters or half-amides of copolymers consisting of ethylenically unsaturated C 4 -C 20 dicarboxylic acid anhydrides and ethylenically unsaturated monomers of the C 2 -C 20 olefin type and/or C 8 -C 20 vinyl aromatic compounds; and/or salts of C 1 -C 12 -alkyl amines or alkanolamines having C 1 -C 18 aliphatic, C 7 -C 14 aromatic or alkylaromatic carboxylic acids and inorganic acids of the hydrochloric acid, sulphuric acid or phosphoric acid type, and; B) optionally up to 400% by mass of fillers and or reinforcing fibers, up to 30% by mass of additional reactive polymers of the ethylene copolymer, maleic anhyudride copolymer, modified maleic anhydride copolymer, poly(meth)acrylate, polyamide, polyester and/or polyurethane type, and up to 4% by mass, each time with regard to the polycondensates of melamine resins, of stabilizes, UV absorbers and/or auxiliary agents. These inventive compositions can be processed by means of melt processing into products such as panels, coated supporting materials, profiled pieces, pipes, injection-molded articles, fibrous products and laminates.

  通过熔融加工生产氨基塑料产品的组合物，其成分包括A) 95%至 99.9%（质量百分比）的无溶剂可熔化三聚氰胺树脂缩聚物，其摩尔质量在 300 至 300 000 之间； A) 0.1%至 5%（质量百分比）的弱酸作为热诱导固化剂，包括：封烷磺酸型酸化剂；脂肪族 C 4 -C 18 羧酸；芳香族 C 7 -C 18 羧酸；磷酸的碱盐或铵盐；C 1 -C 12 -烷基酯或 C 2 -C 8 -的羟基烷基酯或 C 7 -C 14 芳香族羧酸或无机酸的酯类；三聚氰胺或具有 C 1-18 脂肪族羧酸的三聚氰胺盐或胍胺盐； C 4 -C 20 二羧酸的酐、半酯或半酰胺；由乙烯基不饱和 C 4 -C 20 二羧酸酐和乙烯基不饱和的 C 2 -C 20 烯烃类型的乙烯不饱和单体和/或 C 8 -C 20 乙烯基芳香族化合物；和/或 C 1 -C 12 -烷基胺或具有 C 1 -C 18 脂肪族、C 7 -C 14 芳香族或烷芳族羧酸和盐酸、硫酸或磷酸类无机酸，以及B) 填充剂和或增强纤维的质量百分比最高可达 400%，乙烯共聚物、马来酸酐共聚物、改性马来酸酐共聚物、聚（甲基）丙烯酸酯、聚酰胺、聚酯和/或聚氨酯类型的附加反应性聚合物的质量百分比最高可达 30%，稳定剂、紫外线吸收剂和/或辅助剂的质量百分比最高可达 4%（就三聚氰胺树脂的缩聚物而言）。这些发明组合物可以通过熔融加工制成板材、涂层支撑材料、异型件、管材、注塑制品、纤维制品和层压板等产品。
• Synthetic material dispersions
  申请人：Jocham Daniel

  公开号：US20060173102A1

  公开（公告）日：2006-08-03

  The invention relates to synthetic material dispersions consisting of (a) an aqueous phase of solutions of hydrophilic melamine resin precondensates and a latent hardening catalyst in water or in mixtures of water and alcohols C 1 -C 6 , (b) an organic nanophase in the form of nanometric droplets and/or nanoparticles derived from 70-99% of the melamine resin precondensates which are insoluble in water and etherifieds and contain hardening acid catalysts and acid impermeability agents, (c) dispersion agents at a concentration of 1-10 mass % in relation to the total mass of the melamine resin precondensates. The synthetic material dispersions are used for producing flat coated products which are externally used in the form of laminates, of coated flat carrying materials or moulded coated bodies for construction or for sports and recreation.

  本发明涉及合成材料分散体，其组成包括 (a) 亲水性三聚氰胺树脂预缩体溶液和潜伏硬化催化剂在水中或水与 C 1 -C 6 (b) 由 70-99% 的三聚氰胺树脂预缩物制得的纳米液滴和/或纳米颗粒形式的有机纳米 相，这种纳米相不溶于水和醚化物，并含有硬化酸催化剂和酸防渗剂； (c) 分散剂，其浓度为三聚氰胺树脂预缩物总重量的 1-10 质量%。合成材料分散体用于生产平涂产品，这些产品以层压板、平涂承载材料或模塑涂覆体的形式对外使用，用于建筑或运动和娱乐。
• ZUSAMMENSETZUNGEN ZUR HERSTELLUNG VON AMINOPLASTERZEUGNISSEN
  申请人：Borealis Agrolinz Melamine GmbH

  公开号：EP1519972B2

  公开（公告）日：2011-08-24