Photolysis of argon samples containing Cl2, Br2, O3 with 800-360 nm irradiation produced new absorptions at 940.9-932.7 and 818.9-817.5 cm−1, which were assigned to the new BrClO and ClBrO species. Formation of these species proceeds through photodissociation of BrCl: O3 and ClBr: O3 complexes. Photolysis of ClBrO molecules above 400 nm produced BrCl species.
含Cl 2,Br 2,O 3的氩气样品在800-360 nm照射下发生光解,在940.9-932.7和818.9-817.5 cm -1处产生新的吸收,这些吸收被指定为新的BrClO和ClBrO种类。这些物质的形成通过BrCl:O 3和ClBr:O 3络合物的光解而进行。ClBrO分子在400 nm以上的光解产生BrCl物质。