1,1'-(1,6-己烷二基)二(3-苄基脲) | 39072-70-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,1'-(1,6-己烷二基)二(3-苄基脲)
• 中文别名: 3,4-二氨基二苯甲酮；N,N'-己烷-1,6-二基双(N'-苯脲)；N,N-己烷-1,6-二基双(N-苯脲)
• 英文名称: N,N'-bis(benzylcarbamoyl)-1,6-hexamethylenediamine
• 英文别名: N,N''-hexane-1,6-diylbis(N'-benzylurea)；1,6-bis(benzylureido)-hexane；3,3'-Dibenzyl-1,1'-(1,6-hexamethylen)-diharnstoff；Urea, N,N''-1,6-hexanediylbis[N'-(phenylmethyl)-；1-benzyl-3-[6-(benzylcarbamoylamino)hexyl]urea
• CAS: 39072-70-3
• 化学式: C₂₂H₃₀N₄O₂
• mdl: MFCD00088657
• 分子量: 382.506
• InChiKey: KTVATEBHFLZLCI-UHFFFAOYSA-N

物化性质

• 熔点：
  224-226 °C(Solv: ethanol (64-17-5))
• 沸点：
  675.5±55.0 °C(Predicted)
• 密度：
  1?+-.0.06 g/cm3(Predicted)
• LogP：
  2.4 at 22.8℃
• 物理描述：
  Liquid; WetSolid

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  28
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.363
• 拓扑面积：
  82.3
• 氢给体数：
  4
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,6-己二异氰酸酯 在 二氧化硫 作用下， 以 水 为溶剂， 生成 1,1'-(1,6-己烷二基)二(3-苄基脲)
  参考文献：
  名称：

  Dalton,J.R. et al., Australian Journal of Chemistry, 1976, vol. 29, p. 2201 - 2205

  摘要：

  DOI：

文献信息

• Detection of nerve agent via perturbation of supramolecular gel formation
  作者：Jennifer R. Hiscock、Francesca Piana、Mark R. Sambrook、Neil J. Wells、Alistair J. Clark、Jack C. Vincent、Nathalie Busschaert、Richard C. D. Brown、Philip A. Gale

  DOI：10.1039/c3cc44841j

  日期：——

  The formation of tren-based tris-urea supramolecular gels in organic solvents is perturbed by the presence of the nerve agent soman providing a new method of sensing the presence of organophosphorus warfare agents.

  有机溶剂中基于tren的三脲超分子凝胶的形成受到神经毒剂沙克影响，从而为探测有机磷战争剂的存在提供了一种新方法。
• Synthesis of Bis-ureas from Bis(o-nitrophenyl) Carbonate
  作者：Maria-Cristina Turoczi、Monika Simon、Valentin Badea、Carol Csunderlik

  DOI：10.3390/molecules13123192

  日期：——

  A general method for the preparation of bis-ureas from bis(o-nitrophenyl) carbonate has been developed. Directional urea synthesis is achieved by sequential amine addition to bis(o-nitrophenyl) carbonate in two steps: in the first step bis(o-nitrophenyl) carbonate is reacted with benzylamine to form benzyl-o-nitrophenyl carbamate; in the second step the carbamate is reacted with a variety of diamines

  已经开发了一种从双（邻硝基苯基）碳酸酯制备双脲的通用方法。定向尿素合成是通过连续胺加成到双（邻硝基苯基）碳酸酯分两步实现的：第一步，双（邻硝基苯基）碳酸酯与苄胺反应生成苄基-邻硝基苯基氨基甲酸酯；在第二步中，氨基甲酸酯在甲苯中与多种二胺反应生​​成双脲。
• Solution casting method and polymer film
  申请人：Sugiura Masaru

  公开号：US20050077648A1

  公开（公告）日：2005-04-14

  A solvent in which dichloromethane is mixed with alcohol as a poor solvent is used for preparing a dope. Alcohol is supplied to the dope in a inline pipe to mix with a static mixer, such as a casting dope in which a composition of alcohol is increased. The temperature of the rotary drum is adjusted to −7° C. The casting dope is fed from a casting die to the rotary drum so as to form a casting film whose thickness is 40 μm. Since the content of alcohol is high and a storage modulus of the cooled casting film is at least 150 thousands Pa, the peeling defect does not occur, and the stretch is reduced as far as possible. A gel-like film is dried by a tenter type drying device, and stretched such that the stretch ratio is at most 110%. The produced film is thin and excellent in a surface condition and optical isotropy.

  二氯甲烷与作为劣质溶剂的酒精混合的溶剂用于制备涂料。酒精通过内联管道供应到涂料中，与静态混合器混合，如增加酒精成分的铸造涂料。将浇注料从浇注模具送入旋转滚筒，以形成厚度为 40 μm 的浇注膜。由于酒精含量高，冷却后的浇注膜的储存模量至少为 15 万帕，因此不会出现剥离缺陷，拉伸也尽可能减小。凝胶状薄膜由拉幅机干燥，拉伸率不超过 110%。生产出的薄膜很薄，表面状态和光学各向同性都很好。
• Guise,G.B. et al., Australian Journal of Chemistry, 1972, vol. 25, p. 2583 - 2595
  作者：Guise,G.B. et al.

  DOI：——

  日期：——
• Di-urea compounds as gelators for organic solvents
  作者：Jan van Esch、Richard M. Kellogg、Ben L. Feringa

  DOI：10.1016/s0040-4039(96)02292-7

  日期：1997.1

  Simple diurea compounds form thermoreversible gets with several organic solvents. These gels are stable up to temperatures of 100 degrees C, and can be stored for months. Electron microscopy reveals that in these solvents the gelation agents assemble into very thin rectangular sheets which are several tens of micrometers long. Copyright (C) 1996 Elsevier Science Ltd