1,1'-磺酰基二[2,4,6-三硝基-苯 | 10580-80-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,1'-磺酰基二[2,4,6-三硝基-苯
• 英文名称: bis(2,4,6-trinitrophenyl) sulfone
• 英文别名: dipicryl sulfone；Dipicryl-sulfon；2.4.6.2'.4'.6'-Hexanitro-diphenylsulfon；Pikrylsulfon；Picryl sulfone；1,3,5-trinitro-2-(2,4,6-trinitrophenyl)sulfonylbenzene
• CAS: 10580-80-0
• 化学式: C₁₂H₄N₆O₁₄S
• 分子量: 488.262
• InChiKey: LBSKWFDEDNVDAU-UHFFFAOYSA-N

物化性质

• 熔点：
  335-345 °C (decomp)
• 沸点：
  706.9±60.0 °C(Predicted)
• 密度：
  1.1 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  33
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  317
• 氢给体数：
  0
• 氢受体数：
  14

安全信息

• 海关编码：
  2904909090

反应信息

• 作为反应物：
  描述：

  哌啶 、 1,1'-磺酰基二[2,4,6-三硝基-苯 在 乙醇 作用下， 生成 1-(2,4,6-三硝基苯基)哌啶
  参考文献：
  名称：

  Leandri; Tundo, Annali di Chimica, 1954, vol. 44, p. 479,487

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3,5-三硝基-2-(2,4,6-三硝基苯基)硫基苯 在 chromium(VI) oxide 、 硝酸 作用下， 生成 1,1'-磺酰基二[2,4,6-三硝基-苯
  参考文献：
  名称：

  van Duin; van Lennep, Recueil des Travaux Chimiques des Pays-Bas, 1920, vol. 39, p. 170

  摘要：

  DOI：

文献信息

• Non-electric delay detonator and assembly of a detonating cord and a delay detonator
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0015697A1

  公开（公告）日：1980-09-17

  A non-electric delay detonator adapted for field-assembly with a low energy detonating cord (21) has an expansion shell (10) into which the cord is inserted at the time of use. The pressure pulse resulting from the detonation of the cord causes the shell (10) to expand and an ignition charge (11) which is disposed between the shell (10) and a rigid capsule (6) to be actuated as a result of sudden compression between the expansion shell and the capsule. The burning ignition charge ignites a delay charge (5), which in turn ignites a priming charge (3), causing a base charge (2) to detonate. The presence of ignition charge in the annular spacing between the shell and capsule walls, as well as between the shell and capsule ends, and the proper positioning of cord-gripping means (15) in shell cavity (13), assure actuation of the ignition charge whether or not the cord is shoved to the bottom of the shell (10).

  一种用于现场装配低能量导爆索(21)的非电延时雷管有一个膨胀壳(10)，使用时将导爆索插入其中。导爆索引爆产生的压力脉冲使外壳（10）膨胀，由于膨胀外壳和硬质胶囊（6）之间的突然压缩，放置在外壳（10）和硬质胶囊（6）之间的点火装药（11）被激发。燃烧的点火装药点燃延迟装药 (5)，延迟装药又点燃引燃装药 (3)，导致基本装药 (2) 起爆。点火装药存在于壳体和胶囊壁之间以及壳体和胶囊末端之间的环形间隙中，而且线绳夹持装置（15）在壳体空腔（13）中的位置适当，因此无论线绳是否被推到壳体（10）的底部，都能确保点火装药的启动。
• Delay detonator
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0063942A2

  公开（公告）日：1982-11-03

  improved uniformity of timing, and particularly reduced sensitivity of timing to minor variations in delay charge size, are achieved in delay detonators by placing a loose load of a flame-sensitive ignition composition between a pressed delay charge and an ignition assembly, e.g., a percussion primer, at the actuation end of the detonator. The loose ignition charge has a free surface and is adapted to be ignited in response to direct contact with flame emitted from the ignition of a charge in the ignition assembly. Preferably, the delay charge is pressed into a plastic carrier which, in a non-electric detonator, has an open end terminating between the walls of the detonator shell and a primer shell that closes the actuation end of the detonator, and the ignition charge is loosely loaded into a metal capsule seated against the delay charge.

  在延迟雷管中，通过在雷管起爆端压制的延迟装药和点火组件（如撞击底火）之间放置对火焰敏感的点火成分的松散装药，可提高定时的均匀性，特别是降低定时对延迟装药尺寸微小变化的敏感性。松散的点火装药具有自由表面，可在与点火组件中的装药点火时发出的火焰直接接触时被点燃。最好是将延迟装药压入塑料载体中，在非电雷管中，塑料载体的开口端位于雷管壳壁和封闭雷管起爆端的底火壳之间，点火装药松散地装入金属壳体中，与延迟装药固定在一起。
• Non-electric detonators without a percussion element
  申请人：ETI EXPLOSIVES TECHNOLOGIES INTERNATIONAL INC.

  公开号：EP0271233A1

  公开（公告）日：1988-06-15

  A non-electric detonator device having a tubular shell (6) that is closed at its bottom end and containing a base charge (10) of a detonating explosive at the bottom of the shell (6), a priming charge (9) of a heat sensitive detonating explosive composition adjacent to the base charge (10), a rupturable membrane (7) that seals the top end of the shell (6) and forms an open volume (8) between the priming charge (9) and the top end of the shell (6) and a holder (1) for holding a low energy detonating cord (LEDC) (3) in abutting relationship to the membrane (7): whereby on detonation of the LEDC (3) the membrane (7) is ruptured and the priming charge (9) is initiated which in turn initiates the detonating explosive (10).

  一种非电雷管装置，有一个管状壳体（6），其底端封闭，壳体（6）底部装有起爆炸药的基本装药（10）、 与基本装药（10）相邻的热敏起爆炸药（9）、 一个可破裂的薄膜 (7)，用于密封弹壳 (6) 的上端，并在引药 (9) 和弹壳 (6) 的上端之间形成一个开放的容积 (8)，以及 用于固定低能引爆线 (LEDC) (3) 的固定器 (1)，与薄膜 (7) 连接： 其中，LEDC（3）起爆时，膜（7）破裂，引爆装药（9），进而引爆炸药（10）。
• MODIFIER FOR EXPLOSIVES
  申请人：Obshestvo S Ogranichennoy Otvetstvennjctyu "Ifokhim"

  公开号：EP2128117A2

  公开（公告）日：2009-12-02

  Universal modifiers from the class of organic and inorganic acids and their salts of new power systems of driving force on the basis of complex complete or/and incomplete nitrates (nitroesters) monoatomic (alcohols, alkanes), diatomic (diols, glycols, alkanediols), triatomic (triols, glycerin), multinuclear (of absolute valence) alcohols, cellulose, as well as nitroamines (nitramines), azides (azoimides), nitro compounds and compositions (substances) with mixed groups and their mixes purposefully modifying their thermodynamic (thermochemical) parameters (characteristics), mechanical, physical, chemical, biochemical properties.

  来自有机酸和无机酸及其盐类的通用改性剂，以复杂的完全或/和不完全硝酸盐（硝基酯）单原子（醇、烷烃）、二原子（二醇、乙二醇、烷二醇）、三原子（三醇、甘油）为基础的新动力系统、 多核（绝对价）醇、纤维素，以及硝基胺（硝胺）、叠氮化物（叠氮）、硝基化合物和具有混合基团的成分（物质），以及有目的地改变其热力学（热化学）参数（特性）、机械、物理、化学和生物化学性质的混合体。
• Method of preparing propellants using multimodal grains of beta-octogen
  申请人：——

  公开号：US20010023727A1

  公开（公告）日：2001-09-27

  A method of preparing propellants involves using &bgr;-octogen with a multimodal grain size distribution and an average grain size of less than 50 &mgr;m in a propellant composition containing other explosives, inert binders and active binders.

  一种制备推进剂的方法是在含有其他炸药、惰性粘合剂和活性粘合剂的推进剂组合物中使用具有多模态粒度分布且平均粒度小于 50 微米的辛原。