1,1,1-三氟-4-三氟甲基戊烷 | 75121-33-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 中文名称: 1,1,1-三氟-4-三氟甲基戊烷
• 英文名称: 1,1,1-trifluoro-4-trifluoromethylpentane
• 英文别名: 1,1,1,-5,5,5-hexafluoro-4-methylpentane；1,1,1,5,5,5-Hexafluoro-2-methylpentane
• CAS: 75121-33-4
• 化学式: C₆H₈F₆
• 分子量: 194.12
• InChiKey: ZVEAVWJAOLJGIP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,1,1-三氟-3-碘-4-三氟甲基戊烷 在 氢碘酸 作用下， 生成 1,1,1-三氟-4-三氟甲基戊烷
  参考文献：
  名称：

  Davies, Terry; Haszeldine, Robert N.; Tipping, Anthony E., Journal of the Chemical Society. Perkin transactions I, 1983, # 7, p. 1353 - 1356

  摘要：

  DOI：

文献信息

• [EN] PESTICIDAL AND PARASITICIDAL PYRAZOLE-ISOXAZOLINE COMPOUNDS<br/>[FR] COMPOSÉS DE PYRAZOLE-ISOXAZOLINE À ACTIVITÉ PESTICIDE ET PARASITICIDE
  申请人：MERIAL INC

  公开号：WO2019036407A1

  公开（公告）日：2019-02-21

  The present invention relates to pesticidal and parasiticidal isoxazoline of formula (I) and salts thereof: wherein variables R1, P, Y and Q are described herein are as defined in the description. The invention also relates to parasiticidal and pesticidal compositions comprising the isoxazoline compounds of formula (I), processes for their preparation and their uses to prevent or treat parasitic infections or infestations in animals and as pesticides.

  本发明涉及式(I)的杀虫剂和杀寄生虫的异恶唑啉及其盐：其中变量R1、P、Y和Q如本文所述，在描述中定义。本发明还涉及包含式(I)异恶唑啉化合物的杀寄生虫和杀虫组合物，其制备过程及其用于预防或治疗动物寄生虫感染或侵袭以及作为杀虫剂的应用。
• Compositions, Halogenated Compositions, Chemical Production, and Telomerization Processes
  申请人：Brandstadter Stephan

  公开号：US20070276167A1

  公开（公告）日：2007-11-29

  Compositions are provided that can include R F (R T ) n Q, formula I (I), formula II (II), and/or R Cl (R T ) n H. The R F group can have four fluorine atoms, the R T group can include a C-2 group having a pendant —CF 3 group, n can be at least 1, the R 1 group can include a carbon atom, the R Cl group can be —CCI 3 , and the Q group can include one or more atoms of the periodic table of elements. Telomerization processes are also provided.

  提供了可以包括RF(RT)nQ、化学式I (I)、化学式II (II)和/或RCl(RT)nH的组合物。RF基团可以有四个氟原子，RT基团可以包括一个带有—CF3基团的C-2基团，n至少可以为1，R1基团可以包括一个碳原子，RCl基团可以是—CCI3，Q基团可以包括周期表元素中的一个或多个原子。还提供了缩聚反应过程。
• Halogenated Compositions
  申请人：Brandstadter Stephan

  公开号：US20070027349A1

  公开（公告）日：2007-02-01

  Compositions are provided that can include R F (R T ) n Q, and/or R Cl (R T ) n H. The R F group can have four fluorine atoms, the R T group can include a C-2 group having a pendant —CF 3 group, n can be at least 1, the R 1 group can include a carbon atom, the R Cl , group can be —CCl 3 , and the Q group can include one or more atoms of the periodic table of elements. Telomerization processes are also provided.

  提供的组合物可以包括RF（RT）nQ，和/或RCl（RT）nH。 RF基团可以有四个氟原子，RT基团可以包括一个具有一个悬挂的-CF3基团的C-2基团，n至少可以为1，R1基团可以包括一个碳原子，RCl基团可以是—CCl3，Q基团可以包括元素周期表中的一个或多个原子。还提供了缩聚反应过程。
• Trifluoroethylation of olefins with trichlorotrifluoroethane
  作者：Michael Van Der Puy

  DOI：10.1016/s0022-1139(00)80423-6

  日期：1993.3

  1-Trichlorotrifluoroethane was added to seven different olefins using a redox system, giving adducts having the CF3CCl2-C-CCl- subunit. Selective addition to the exocyclic double bond in limonene was observed. The adducts were dechlorinated by catalytic reduction or with tri-n-butyltin hydride. The two-step sequence thus provided a method for appending the trifluoroethyl group (CF3CH2-) to olefins.

  使用氧化还原系统将1,1,1-三氯三氟乙烷添加到七个不同的烯烃中，得到具有CF 3 CCl 2 -C-CCl-亚单元的加合物。观察到柠檬烯中向环外双键的选择性加成。加合物通过催化还原或用三正丁基氢化锡脱氯。因此，两步顺序提供了将三氟乙基（CF 3 CH 2-）连接至烯烃的方法。
• Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams, and foams stabilizers
  申请人：Boggs Janet

  公开号：US20070149437A1

  公开（公告）日：2007-06-28

  Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohols, reacting olefins and a saturated compounds, reacting reactants having at least two —CF 3 groups with reactants having cyclic groups. RF compositions such as R F -intermediates, R F -surfactants, R F -monomers, R F- monomer units, R F -metal complexes, R F -phosphate esters, R F -glycols, R F urethanes, and/or R F -foam stabilizers. The R F portion can include at least two —CF 3 groups, at least three —CF 3 groups, and/or at least two —CF 3 groups and at least two —CH 2 — groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R F -surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R F -monomer unit Compositions are provided that include a substrate having a R F -composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include R F -surfactants and/or R F -foam stabilizers are provided.

  提供生产过程和系统，包括反应卤代化合物，脱卤化合物，反应醇，反应烯烃和饱和化合物，将至少含有两个—CF3基团的反应物与具有环状基团的反应物反应。提供RF组分，例如RF中间体，RF表面活性剂，RF单体，RF单体单元，RF金属络合物，RF磷酸酯，RF乙二醇，RF聚氨酯和/或RF泡沫稳定剂。RF部分可以包括至少两个—CF3基团，至少三个—CF3基团，和/或至少两个—CF3基团和至少两个—CH2—基团。提供包括RF表面活性剂组分的清洁剂，乳化剂，油漆，粘合剂，油墨，润湿剂，发泡剂和消泡剂。提供包括RF单体单元的丙烯酸，树脂和聚合物。提供包括具有RF组分的基底的组合物。提供包括RF表面活性剂和/或RF泡沫稳定剂的水性成膜泡沫（“AFFF”）配方。