1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十六氟-9-(乙烯基氧基)壬烷 | 71726-31-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 中文名称: 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十六氟-9-(乙烯基氧基)壬烷
• 中文别名: 3-(4-氨基苯基)-3-环己基并哌啶-2,6-二酮
• 英文名称: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorononyl vinyl ether
• 英文别名: 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Hexadecafluoro-9-(vinyloxy)nonane；9-ethenoxy-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluorononane
• CAS: 71726-31-3
• 化学式: C₁₁H₆F₁₆O
• 分子量: 458.142
• InChiKey: PLZIKMVNRWVJKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  28
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十六氟-9-(乙烯基氧基)壬烷 、 溶剂黄146 在 三氟乙酸 作用下， 反应 10.5h， 以82%的产率得到Acetic acid 1-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluoro-nonyloxy)-ethyl ester
  参考文献：
  名称：

  摘要：

  Polyfluoroalkyl vinyl ethers take up aliphatic and aromatic carboxylic acids in the presence of 0.2-5 wt% of trifluoroacetic acid at 55-105degreesC to give fluorine-containing hemiacetals in 60-100% yields.

  DOI：

  10.1023/a:1019516520501

文献信息

• Fluorine-containing copolymer and composition containing the same
  申请人：Daikin Kogyo Co., Ltd.

  公开号：EP0121934A1

  公开（公告）日：1984-10-17

  A fluorine-containing copolymer comprising chlorotrifluoroethylene, 2,2,3,3-tetrafluoropropyl vinyl ether and 0 to 25% by mole of a vinyl ether having a functional group selected from the group consisting of hydroxyl group, glycidyl group and amino group. The fluorine-containing copolymer has a good compatibility with methyl methacrylate polymers and gives, in combination use with methyl methacrylate polymers, products such as coating film, self-supporting film and molded article, which have good stain resistance and transparency.

  一种含氟共聚物，由三氟氯乙烯、2,2,3,3-四氟丙基乙烯基醚和 0-25% （以摩尔计）的乙烯基醚组成，乙烯基醚的官能团选自羟基、缩水甘油基和氨基。含氟共聚物与甲基丙烯酸甲酯聚合物具有良好的相容性，与甲基丙烯酸甲酯聚合物结合使用，可制成具有良好抗污性和透明度的产品，如涂膜、自支撑膜和模塑制品。
• Vinylidene fluoride copolymer and composition containing the same
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0458290A2

  公开（公告）日：1991-11-27

  A vinylidene fluoride copolymer comprising 50 to 90 % by mole of units having the formula (I):         -CH₂-CF₂-   (I) 1 to 30 % by mole of units having the formula (II): 1 to 30 % by mole of units having the formula (III): 1 to 30 % by mole of units having the formula (IV): and a composition comprising the copolymer as the main component. Since the copolymer is excellent in solvent solubility, it can be dissolved in a widely used solvent for coatings and it is not required to treat the film at a high temperature after coating. Moreover, the obtained film is excellent in adhesion to a substrate, glossiness, weatherability, stain resistance and corrosion resistance.

  一种亚乙烯基氟化物共聚物，由 50%至 90%（以摩尔计）具有式 (I) 的单元组成： -CH₂-CF₂- (I) 1-30%（摩尔）具有式 (II) 的单元： 1-30%（以摩尔计）具有式（III）的单元： 1-30%（以摩尔计）具有式（IV）的单元： 以及一种以该共聚物为主要成分的组合物。由于共聚物具有优异的溶剂溶解性，因此可以溶解在广泛使用的涂料溶剂中，涂膜后也无需高温处理。此外，获得的薄膜在与基材的附着力、光泽度、耐候性、抗污性和耐腐蚀性方面都非常出色。
• Fluorine-containing copolymer and curable composition containing the same
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0483750A1

  公开（公告）日：1992-05-06

  A fluorine-containing copolymer comprising: 30 to 85 % by mole of structural units (a): 1 to 30 % by mole of structural units (b): and 3 to 60 % by mole of structural units (c): and a curable composition containing the same. The copolymer is excellent in compatibility with curing agents and the obtained film therefrom is excellent in appearance, gloss, durability, and the like.

  含氟共聚物，包括30% 至 85% （以摩尔计）的结构单元 (a)： 1 至 30%（摩尔）的结构单元（b）： 和 3%至 60%（以摩尔计）的结构单元（c）： 的共聚物，以及含有这种共聚物的可固化组合物。该共聚物与固化剂的相容性极佳，由此获得的薄膜在外观、光泽度、耐久性等方面也非常出色。
• Transparent fluorine-containing copolymer
  申请人：Central Glass Company, Limited

  公开号：US20030236369A1

  公开（公告）日：2003-12-25

  The present invention relates to a fluorine-containing copolymer. This fluorine-containing copolymer includes (a) a first unit derived from &agr;-trifluoromethyl acrylic ester represented by the following general formula (1); and (b) a second unit derived from a vinyl monomer, 1 where R 1 is an organic group containing at least one fluorine atom.

  本发明涉及一种含氟共聚物。这种含氟共聚物包括：(a) 由&agr;-三氟甲基丙烯酸酯衍生的第一单元，其代表通式如下(1)；(b) 由乙烯基单体衍生的第二单元、 1 其中 R 1 是含有至少一个氟原子的有机基团。
• Fluorine-containing copolymer and the curable composition containing the same
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0464704B1

  公开（公告）日：1995-01-11