1,2-二丁基-1,2-二甲基肼 | 116149-14-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 1,2-二丁基-1,2-二甲基肼
• 英文名称: 1,2-di-n-butyldimethylhydrazine
• 英文别名: Hydrazine, N,N'-dibutyl-N,N'-dimethyl-；1,2-dibutyl-1,2-dimethylhydrazine
• CAS: 116149-14-5
• 化学式: C₁₀H₂₄N₂
• 分子量: 172.314
• InChiKey: HUUBGMAZZGQSLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N,N'-Dimethylhydrazine dihydrochloride 、 正丁醛 在 sodium tetrahydroborate 、 二甲基十二/十四烷基叔胺 、 溶剂黄146 作用下， 生成 1,2-二丁基-1,2-二甲基肼
  参考文献：
  名称：

  Gas-phase electron-transfer equilibrium studies on tetraalkylhydrazines: geometry effects on ionization thermochemistry, relaxation energies, and ion solvation energies

  摘要：

  DOI：

  10.1021/ja00232a001

文献信息

• PROCESS FOR PREPARING POLYCARBONATES BY POLYMERIZATION OF FIVE-MEMBERED-RING CYCLIC CARBONATES
  申请人：Total Research & Technology Feluy

  公开号：EP2992032A1

  公开（公告）日：2016-03-09
• [EN] PROCESS FOR PREPARING POLYCARBONATES BY POLYMERIZATION OF FIVE-MEMBERED-RING CYCLIC CARBONATES<br/>[FR] PROCÉDÉ DE PRÉPARATION DE POLYCARBONATES PAR POLYMÉRISATION DE CARBONATES CYCLIQUES À CINQ CHAÎNONS
  申请人：TOTAL RES & TECHNOLOGY FELUY

  公开号：WO2014177558A1

  公开（公告）日：2014-11-06

  The invention relates to a process for the preparation of polycarbonates. In particular the invention relates to a process for the preparation of polycarbonates or copolymers thereof, by ring-opening polymerization of five-mem bered cyclic carbonates, said process comprises the step of homo- or copolymerizing in the presence of at least one catalyst, one or more compounds of formula (I), stereoisomers, racemics, or mixtures thereof; optionally with one or more cyclic esters, stereoisomers, racemics, or mixtures thereof; wherein each dotted bond "a" and "b" are a solid bond, a wedged bond, or a hashed wedged bond; and R21 and R22 taken together with the carbon atoms 4 and 5 of the cyclic carbonate form a ring selected from C5-9cycloalkylene, C5-9cycloalkenylene, and C6-12arylene, said ring being optionally substituted with one or more substituents each independently selected from halo, hydroxyl, C1-6alkyl, haloC1-6alkyl, C1-6alkoxy, haloC1-6alkoxy, C6-12aryl, C1-6alkylthio, carboxyl, C1-6 alkoxycarbonyl, C1-6alkylcarbonyloxy, amino; or mono- or di-C1-6alkylamino.
• Gas-phase electron-transfer equilibrium studies on tetraalkylhydrazines: geometry effects on ionization thermochemistry, relaxation energies, and ion solvation energies
  作者：Stephen F. Nelsen、Daniel T. Rumack、Michael. Meot-Ner

  DOI：10.1021/ja00232a001

  日期：1988.11