1,2-二溴-1,1,3,3,3-五氟丙烷 | 431-78-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 中文名称: 1,2-二溴-1,1,3,3,3-五氟丙烷
• 英文名称: 1,2-dibromo-2-hydropentafluoropropane
• 英文别名: 2,3-Dibromo-1,1,1,3,3-pentafluoropropane；1,1,1,3,3-pentafluor-2,3-dibrom-propan；1,2-dibromo-1,1,3,3,3-pentafluoro-propane；1,2-Dibrom-1,1,3,3,3-pentafluor-propan；1,2-dibromo-1,1,3,3,3-pentafluoropropane
• CAS: 431-78-7
• 化学式: C₃HBr₂F₅
• 分子量: 291.841
• InChiKey: PZNIYCULZNYNKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 海关编码：
  2903799090

反应信息

• 作为反应物：
  描述：

  1,2-二溴-1,1,3,3,3-五氟丙烷 在 sodium sulfite 作用下， 生成 2-溴五氟丙烯
  参考文献：
  名称：

  类固醇代谢研究；红外光谱法表征甾族化合物中的羰基和其他官能团

  摘要：

  DOI：

  10.1021/ja01186a014
• 作为产物：
  描述：

  1,1,3,3,3-五氟-1-丙烯 在 溴 作用下， 以 1,1,2-三氯三氟乙烷（CFC-113） 为溶剂， 反应 240.0h， 生成 1,2-二溴-1,1,3,3,3-五氟丙烷
  参考文献：
  名称：

  Condensation of perfluoroisobutylene with compounds containing dihalomethylene groups

  摘要：

  DOI：

  10.1007/bf01418015

文献信息

• PROCESS FOR PRODUCING FLUOROOLEFINS
  申请人：——

  公开号：US20030060670A1

  公开（公告）日：2003-03-27

  A process for producing a fluoroolefin of the formula: CF 3 CY═CX n H p wherein Y is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); X is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); n and p are integers independently equal to 0, 1 or 2, provided that (n+p)=2; comprising contacting, in the presence of a phase transfer catalyst, a compound of the formula: CF 3 C(R 1 a R 2 b ) C(R 3 c R 4 d ), wherein R 1 , R 2 , R 3 , and R 4 are independently a hydrogen atom or a halogen selected from the group consisting of fluorine, chlorine, bromine and iodine, provided that at least one of R 1 , R 2 , R 3 , and R 4 is halogen and there is at least one hydrogen and one halogen on adjacent carbon atoms; a and b are independently=0, 1 or 2 and (a+b)=2; and c and d are independently=0, 1, 2 or 3 and (c+d)=3; and at least one alkali metal hydroxide. The alkali metal hydroxide can be, for example, potassium or sodium hydroxide and the phase transfer catalyst can be, for example, at least one: crown ether such as 18-crown-6 and 15-crown-5; or onium salt such as, quaternary phosphonium salt and quaternary ammonium salt. The olefin is useful, for example, as an intermediate for producing other industrial chemicals and as a monomer for producing oligomers and polymers.

  一种生产化学式为CF3CY═CXnHp的氟代烯烃的方法，其中Y为氢原子或卤素原子（即氟、氯、溴或碘）；X为氢原子或卤素原子（即氟、氯、溴或碘）；n和p是独立等于0、1或2的整数，前提是（n+p）=2；包括在相转移催化剂的存在下，与化合物CF3C（R1aR2b）C（R3cR4d）接触，其中R1、R2、R3和R4独立地为氢原子或卤素，所选卤素来自于氟、氯、溴和碘的群体，前提是R1、R2、R3和R4中至少有一个是卤素，在相邻的碳原子上至少有一个氢原子和一个卤素；a和b独立地等于0、1或2，（a+b）=2；c和d独立地等于0、1、2或3，（c+d）=3；并加入至少一种碱金属氢氧化物。碱金属氢氧化物可以是例如钾氢氧化物或钠氢氧化物，相转移催化剂可以是例如至少一种：冠醚，例如18-冠-6和15-冠-5；或离子盐，例如季铵盐和季膦盐。该烯烃可用于例如作为生产其他工业化学品的中间体，以及作为生产寡聚物和聚合物的单体。
• Process for producing fluoroolefins
  申请人：Honeywell International

  公开号：US06548719B1

  公开（公告）日：2003-04-15

  A process for producing a fluoroolefin of the formula: CF3CY═CXnHp wherein Y is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); X is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); n and p are integers independently equal to 0, 1 or 2, provided that (n+p)=2; comprising contacting, in the presence of a phase transfer catalyst, a compound of the formula: CF3C(R1aR2b)C(R3cR4d), wherein R1, R2, R3, and R4 are independently a hydrogen atom or a halogen selected from the group consisting of fluorine, chlorine, bromine and iodine, provided that at least one of R1, R2, R3, and R4 is halogen and there is at least one hydrogen and one halogen on adjacent carbon atoms; a and b are independently=0, 1 or 2 and (a+b)=2; and c and d are independently=0, 1, 2 or 3 and (c+d)=3; and at least one alkali metal hydroxide. The alkali metal hydroxide can be, for example, potassium or sodium hydroxide and the phase transfer catalyst can be, for example, at least one: crown ether such as 18-crown-6 and 15-crown-5; or onium salt such as, quaternary phosphonium salt and quaternary ammonium salt. The olef in is useful, for example, as an intermediate for producing other industrial chemicals and as a monomer for producing oligomers and polymers.

  一种生产化学式为：CF3CY═CXnHp的氟代烯烃的方法，其中Y是氢原子或卤素原子（即氟、氯、溴或碘）；X是氢原子或卤素原子（即氟、氯、溴或碘）；n和p是整数，独立地等于0、1或2，但要求（n+p）=2；包括在相转移催化剂的存在下，接触化合物CF3C（R1aR2b）C（R3cR4d），其中R1、R2、R3和R4独立地是氢原子或卤素，所述卤素选自氟、氯、溴和碘组成的群体，但要求R1、R2、R3和R4中至少有一个是卤素，在相邻的碳原子上至少有一个氢和一个卤素；a和b独立地等于0、1或2且（a+b）=2；c和d独立地等于0、1、2或3且（c+d）=3；以及至少一种碱金属氢氧化物。碱金属氢氧化物可以是例如钾或钠氢氧化物，相转移催化剂可以是例如至少一种：冠醚，例如18-冠-6和15-冠-5；或离子盐，例如季铵盐和季膦盐。该烯烃可用于例如生产其他工业化学品的中间体以及生产寡聚物和聚合物的单体。
• Addition of free radicals to unsaturated systems. Part XI. The direction of radical addition to 1 : 1 : 3 : 3: 3-pentafluoropropene, and the synthesis of perfluoro-olefins, -ketones, and -acids
  作者：R. N. Haszeldine、B. R. Steele

  DOI：10.1039/jr9550003005

  日期：——
• Condensation of perfluoroisobutylene with compounds containing dihalomethylene groups
  作者：Yu. V. Zeifman、L. T. Lantseva、S. A. Postovoi

  DOI：10.1007/bf01418015

  日期：1981.7
• Studies in Steroid Metabolism. IV. The Characterization of Carbonyl and Other Functional Groups in Steroids by Infrared Spectrometry¹
  作者：R. Norman Jones、V. Z. Williams、M. J. Whalen、Konrad Dobriner

  DOI：10.1021/ja01186a014

  日期：1948.6