1,2-双[[4-(溴甲基)苯氧基]甲基]苯 | 683248-48-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,2-双[[4-(溴甲基)苯氧基]甲基]苯
• 英文名称: Benzene, 1,2-bis[[4-(bromomethyl)phenoxy]methyl]-
• 英文别名: 1,2-bis[[4-(bromomethyl)phenoxy]methyl]benzene
• CAS: 683248-48-8
• 化学式: C₂₂H₂₀Br₂O₂
• 分子量: 476.208
• InChiKey: DHOLYCORLNLVHL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-双[[4-(溴甲基)苯氧基]甲基]苯 在 硫脲 、 氢氧化钾 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 24.0h， 以65%的产率得到[4-[[2-[[4-(Sulfanylmethyl)phenoxy]methyl]phenyl]methoxy]phenyl]methanethiol
  参考文献：
  名称：

  环内连接双环环烷的合成与络合研究

  摘要：

  用二硫代硫酸钠还原衍生自2,6-双（氯甲基）苯醌和合适的二硫醇的环烷，然后进一步与各种二溴化物偶合，得到环内连接的双环环烷，与TCNQ和TCNE形成电荷转移配合物。

  DOI：

  10.1016/j.tet.2006.07.064
• 作为产物：
  描述：

  1,2-benzyloxy-bis-(4-benzaldehyde) 在 sodium tetrahydroborate 、 三溴化磷 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 18.0h， 生成 1,2-双[[4-(溴甲基)苯氧基]甲基]苯
  参考文献：
  名称：

  Dioxastilbenophanes—synthesis and charge transfer complexation studies

  摘要：

  Intramolecular McMurry coupling of dialdehydes derived from xylenyl dibromide and 4-hydroxy benzaldehyde afforded cis-stilbenophanes along with cyclophane diols. Stilbenophanes with a large cavity were also synthesized. Charge transfer complexations of the stilbenophanes with TCNE, TCNQ and PQT were studied. Some stilbenophanes form a relatively stronger complex with PQT rather than with TCNE and TCNQ. (C) 2004 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tet.2004.01.008

文献信息

• Dioxastilbenophanes—synthesis and charge transfer complexation studies
  作者：Perumal Rajakumar、Venghatraghavan Murali

  DOI：10.1016/j.tet.2004.01.008

  日期：2004.3

  Intramolecular McMurry coupling of dialdehydes derived from xylenyl dibromide and 4-hydroxy benzaldehyde afforded cis-stilbenophanes along with cyclophane diols. Stilbenophanes with a large cavity were also synthesized. Charge transfer complexations of the stilbenophanes with TCNE, TCNQ and PQT were studied. Some stilbenophanes form a relatively stronger complex with PQT rather than with TCNE and TCNQ. (C) 2004 Published by Elsevier Ltd.
• Synthesis and complexation studies of intra annularly linked bicyclic cyclophanes
  作者：Perumal Rajakumar、Rajagopal Kanagalatha

  DOI：10.1016/j.tet.2006.07.064

  日期：2006.10

  The cyclophanes derived from 2,6-bis(chloromethyl)benzoquinone and suitable dithiols were reduced with sodium dithionate and then further coupled with various dibromides to give intra annularly linked bicyclic cyclophanes, which forms charge transfer complexes with TCNQ and TCNE.

  用二硫代硫酸钠还原衍生自2,6-双（氯甲基）苯醌和合适的二硫醇的环烷，然后进一步与各种二溴化物偶合，得到环内连接的双环环烷，与TCNQ和TCNE形成电荷转移配合物。