1,3-二溴-2,3-二甲基丁烷 | 49623-54-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 中文名称: 1,3-二溴-2,3-二甲基丁烷
• 英文名称: 2,4-dibromo-2,3-dimethylbutane
• 英文别名: 1,3-dibromo-2,3-dimethyl-butane；1,3-Dibrom-2,3-dimethyl-butan；1,3-Dibromo-2,3-dimethyl-butan；1,3-Dibrom-2,3-dimethylbutan；1.3-Dibrom-2.3-dimethylbutan；1,3-Dibromo-2,3-dimethylbutane
• CAS: 49623-54-3
• 化学式: C₆H₁₂Br₂
• 分子量: 243.969
• InChiKey: PROLBQBUEWXPSN-UHFFFAOYSA-N

物化性质

• 溶解度：
  可溶于氯仿（少许）、甲醇（少许）

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,3-二溴-2,3-二甲基丁烷 在 吡啶 作用下， 75.0 ℃ 、26.66 kPa 条件下， 生成 1-bromo-2,3-dimethyl-2-butene
  参考文献：
  名称：

  Sarytschewa et al., Zhurnal Obshchei Khimii, 1957, vol. 27, p. 2994,2996;engl.Ausg.S.3023,3025

  摘要：

  DOI：
• 作为产物：
  描述：

  3,3-二甲基-1-丁炔 在 氢溴酸 作用下， 生成 1,3-二溴-2,3-二甲基丁烷
  参考文献：
  名称：

  Griesbaum,K. et al., Liebigs Annalen der Chemie, 1979, p. 1137 - 1150

  摘要：

  DOI：

文献信息

• Sarytschewa et al., Zhurnal Obshchei Khimii, 1957, vol. 27, p. 2994,2996;engl.Ausg.S.3023,3025
  作者：Sarytschewa et al.

  DOI：——

  日期：——
• Gelin,R.; Chantegrel,B., Bulletin de la Societe Chimique de France, 1971, p. 2527 - 2544
  作者：Gelin,R.、Chantegrel,B.

  DOI：——

  日期：——
• Preference to have used a medically supervised injecting centre among injecting drug users in Kings Cross, Sydney
  作者：Ingrid van Beek、Stuart Gilmour

  DOI：10.1111/j.1467-842x.2000.tb00507.x

  日期：2000.10

  Objective: To assess factors affecting preference to have last injected in a medically supervised injecting centre (MSIC) among injecting drug users (IDUs) attending a needle syringe program (NSP) in Kings Cross, Sydney. Methods: All NSP attenders over a two-day period in August 1999 were asked where they last injected, whether they injected alone and if they would have preferred to use an MSIC. This was in addition to the routine data collected, which included age, gender and last drug injected. Results: Among the 178 respondents, 52 (29%) last injected in a public place and 77 (44%) last injected alone. Seventy-one per cent of all respondents would have preferred to use an MSIC. Of those who injected in public, 83% would have preferred to use an MSIC compared to 66% of those who injected in private, which was significant (p = 0.03). Age, gender, last drug injected and having injected alone did not affect preference to use an MSIC. Conclusions: Respondents' high preference to use an MSIC suggests that it may well achieve its public order and public health objectives. Implications: An MSIC may significantly shift current patterns of illicit drug use in Kings Cross, the community impact of which should be monitored and managed.
• The Synthesis and Properties of 1,1,2-Trimethylcyclopropane¹
  作者：Robert G. Kelso、Kenneth W. Greenlee、John M. Derfer、Cecil E. Boord

  DOI：10.1021/ja01122a001

  日期：1952.1
• Naphthonitrile-alkene exciplexes. Comparison of bimolecular and bichromophoric cases: effects of linking on fluorescence and photochemistry
  作者：John J. McCullough、W. Keith MacInnis、Colin J. L. Lock、Rommulo Faggiani

  DOI：10.1021/ja00381a023

  日期：1982.8