1-(3,5-二异丙基-4-联苯基)-2-苯基-1H-咪唑 | 1272455-54-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-(3,5-二异丙基-4-联苯基)-2-苯基-1H-咪唑
• 英文名称: 1-(3,5-diisopropylbiphenyl-4-yl)-2-phenyl-1H-imidazole
• 英文别名: 1-(3,5-Diisopropyl-[1,1'-biphenyl]-4-yl)-2-phenyl-1H-imidazole；2-phenyl-1-[4-phenyl-2,6-di(propan-2-yl)phenyl]imidazole
• CAS: 1272455-54-5
• 化学式: C₂₇H₂₈N₂
• 分子量: 380.533
• InChiKey: JWLIGGYTWRVCJX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  29
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  iridium(III) chloride 、 1-(3,5-二异丙基-4-联苯基)-2-苯基-1H-咪唑 以 乙二醇乙醚 、 水 为溶剂， 反应 4.0h， 以4.5 g的产率得到
  参考文献：
  名称：

  IRIDIUM COMPLEX COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT MATERIAL, ORGANIC ELECTROLUMINESCENT ELEMENT, ILLUMINATION DEVICE AND DISPLAY DEVICE

  摘要：

  一种有机电致发光元件，其中至少包括一个有机层，包括一个发光层，夹在阳极和阴极之间，其中至少一个有机层包括以下一般式（1）所代表的铱配合物化合物。

  公开号：

  US20130200340A1
• 作为产物：
  描述：

  1-[2,6-Di(propan-2-yl)phenyl]-2-phenylimidazole;iridium(3+);2-phenyl-1-[4-phenyl-2,6-di(propan-2-yl)phenyl]imidazole 在 溶剂黄146 作用下， 以 乙酸乙酯 为溶剂， 反应 1.0h， 生成 1-(2,6-二异丙基苯基)-2-苯基-1H-咪唑 、 1-(3,5-二异丙基-4-联苯基)-2-苯基-1H-咪唑
  参考文献：
  名称：

  イリジウム錯体のフェイシャル体の製造方法

  摘要：

  【问题】提供一种生产高收率和高纯度的顺向体铱配合物的方法。 【解决方案】通过光照射亲合体铱配合物，然后使用弱酸处理，制备式（1）所示的顺向体铱配合物。 [B1-B5和B11-B15分别是C，N，O或S，B1-B5中至少一个和B11-B15中至少一个是氮原子；Z和Z1是形成6元环所需的非金属原子团；m1是1-3的整数；m2是0-2的整数；m1 + m2 = 3] 【选择图】无

  公开号：

  JP2017200929A

文献信息

• PHOSPHORESCENT EMITTERS AND HOST MATERIALS WITH IMPROVED STABILITY
  申请人：Xia Chuanjun

  公开号：US20110057559A1

  公开（公告）日：2011-03-10

  Devices containing a particular combination of organic compounds are provided. In particular, the devices contain twisted aryl compounds having extended conjugation (i.e., the twisted aryl is substituted with an additional aryl group) in combination with dibenzothiophene or dibenzofuran containing host materials. The organic light emitting devices may provide improved stability color, lifetime and manufacturing. Compounds containing a twisted aryl having extended conjugation are also provided.

  提供了含有特定有机化合物组合的设备。具体来说，这些设备包含具有扭曲芳基化合物的延伸共轭（即，扭曲芳基被另一个芳基取代）与含有二苯并噻吩或二苯并呋喃的宿主材料相结合。这些有机发光器件可能提供改善的稳定性、颜色、寿命和制造工艺。还提供了含有具有延伸共轭的扭曲芳基的化合物。
• TRANSITION METAL COMPLEXES COMPRISING SYMMETRIC TETRADENTATE LIGANDS
  申请人：SOLVAY SA

  公开号：US20150221877A1

  公开（公告）日：2015-08-06

  Light emitting transition metal complexes comprising sub-units based on symmetric tetradentate ligands.

  基于对称四齿配体的亮度发射过渡金属配合物。
• Homoleptic tris-cyclometalated iridium(<scp>iii</scp>) complexes with phenylimidazole ligands for highly efficient sky-blue OLEDs
  作者：Jinyong Zhuang、Wanfei Li、Weichen Wu、Minshun Song、Wenming Su、Ming Zhou、Zheng Cui

  DOI：10.1039/c4nj01316f

  日期：——

  Sky-blue homoleptic iridium(iii) complexes with phenylimidazole ligands show consistent behavior that is linked to their ligand conjugation.

  含有苯基咪唑配体的天蓝色同配型的三价铱配合物表现出一致的行为，这与它们的配体共轭有关。
• TRANSITION METAL COMPLEXES COMPRISING ASYMMETRIC TETRADENTATE LIGANDS
  申请人：SOLVAY SA

  公开号：US20150243910A1

  公开（公告）日：2015-08-27

  Light emitting transition metal complexes comprising sub-units based on asymmetric tetradentate ligands comprising two different bidentate ligand units.

  含有基于不对称四齿配体的亚单位的发光过渡金属配合物，该配体包含两个不同的双齿配体单位。
• PREPARATION OF HETEROLEPTIC METAL COMPLEXES
  申请人：SOLVAY SA

  公开号：US20140378685A1

  公开（公告）日：2014-12-25

  A process for the manufacture of heteroleptic complexes of a transition metal M having the general formula [M(L) n L′] wherein M is Ir, Rh, Pt or Pd and n is 2 for M=Ir or Rh and n is 1 for M=Pt or Pd and L is a bidentate cyclometallated ligand coordinated to the metal M through covalent metal-C and dative donor-atom-metal bonds, by reacting a halo-bridged dimer of general formula [L n M(μ-X) 2 )ML n ] with a bidentate ligand compound of formula L′-H or a halo-bridged dimer of general formula [L′ n M(μ-X) 2 ) -ML′ n ] with a ligand compound of formula L-H where (μ-X) represents a bridging halide in a solvent mixture of an organic solvent and water comprising more than 25 vol % of water at a temperature of from 50 to 260° C. in the presence of from 0 to 5 molar equivalents relative to the number of moles of halide X-ion introduced into the reaction mixture through the halo-bridged dimer of a scavenger for halide X-ion and in the presence of from 0 to 0.8 moles, based on the molar amount of transition metal in the halo-bridged dimer of an added salt and of from 0 to 10 vol %, based on the total volume of the solvent mixture, of a solubilisation agent increasing the solubility of the halo-bridged dimer in the reaction mixture.