1-(3-溴丙基)-3-苯氧基苯 | 105128-00-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-(3-溴丙基)-3-苯氧基苯
• 英文名称: 1-bromo-3-(3-phenoxyphenyl)propane
• 英文别名: 3-(3-phenoxyphenyl)propyl bromide；3-(3-phenoxyphenyl)-1-bromopropane；3-(3-bromopropyl)diphenyl ether；1-(3-Bromopropyl)-3-phenoxybenzene
• CAS: 105128-00-5
• 化学式: C₁₅H₁₅BrO
• 分子量: 291.187
• InChiKey: ZFCDQZNUBZAHRP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(3-溴丙基)-3-苯氧基苯 、 三苯基膦 生成 Bromo-[3-(3-phenoxyphenyl)propyl]-triphenyl-lambda5-phosphane
  参考文献：
  名称：

  TSUSIMA, KADZUXIRO;TAKAGAKI, TOXEHJ;MATSUO, NORITADA;YANO, TOSIXIKO;XIRAN+

  摘要：

  DOI：
• 作为产物：
  描述：

  3-(3-苯氧基苯基)-1-丙醇 在 吡啶 、 phosphorus tribromide 、 sodium chloride 、 碳酸氢钠 作用下， 以 乙醚 、 水 为溶剂， 生成 1-(3-溴丙基)-3-苯氧基苯
  参考文献：
  名称：

  Insecticidal cyclopropyl-substituted di(aryl) compounds

  摘要：

  该公式化合物为##STR1##，其中Ar为取代或未取代的苯基、萘基或噻吩基；Z为氧、硫或亚甲基；Ar'为2-甲基[1,1'-联苯]-3-基、3-苯氧基苯基、4-氟-3-苯氧基苯基或6-苯氧基-2-吡啶基，具有拟除虫剂和杀螨活性，对水生动物相对无害。

  公开号：

  US04808762A1

文献信息

• 6-pyridyl- and 6-phenyl-3-phenyl-1-hexenes and -1-hexynes, composition
  申请人：Sumitomo Chemical Company, Limited

  公开号：US04772633A1

  公开（公告）日：1988-09-20

  This invention relates to a novel compound represented by the following general formula (I), its production, and an insecticidal and acaricidal composition containing it as an active ingredient: ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, are a hydrogen atom, a halogen atom, a lower alkyl group, a trifluoromethyl group, a lower alkoxyl group, a lower alkenyloxy group or a halogenated lower alkoxyl group or are, taken together, a methylenedioxy group; R.sub.3 is a vinyl group or a ethynyl group; R.sub.4 is a hydrogen atom or a lower alkyl group; R.sub.5 is a hydrogen atom or a fluorine atom; R.sub.6 is a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxyl group or a trifluoromethyl group; Z is a nitrogen atom or a group represented by the formula --CH.dbd.; when Z is a nitrogen atom, Y is an oxygen atom; and when Z is a group of the formula --CH.dbd., Y is an oxygen atom, a sulfur atom, a methylene group or a group represented by the formula --NH--.

  这项发明涉及一种由以下通用式（I）表示的新型化合物，其制备以及含有其作为活性成分的杀虫杀螨组合物： 其中R.sub.1和R.sub.2，可能相同也可能不同，是氢原子、卤素原子、较低的烷基基团、三氟甲基基团、较低的烷氧基团、较低的烯烃氧基团或卤代较低的烷氧基团或者共同为亚甲氧基团；R.sub.3是乙烯基团或乙炔基团；R.sub.4是氢原子或较低的烷基基团；R.sub.5是氢原子或氟原子；R.sub.6是氢原子、卤素原子、较低的烷基基团、较低的烷氧基团或三氟甲基基团；Z是氮原子或由--CH.dbd.表示的基团；当Z是氮原子时，Y是氧原子；当Z是--CH.dbd.的基团时，Y是氧原子、硫原子、亚甲基团或由--NH--表示的基团。
• Diphenyl ether derivatives and their use as insecticides
  申请人：Imperial Chemical Industries PLC

  公开号：US04791139A1

  公开（公告）日：1988-12-13

  A compound of formula: ##STR1## wherein W represents one or more substituents selected from halo, alkyl, alkoxy, alkoxyalkyl, haloalkyl and haloalkoxy or W represents a bidentate group linking adjacent carbon atoms selected from alkylene and alkylenedioxy; Y is a group of formula ##STR2## wherein X is a group of formula --(CF.sub.2).sub.n R.sup.3, where R.sup.3 is selected from hydrogen, chloro and fluoro, and n is one or two, R.sup.1 is selected from hydrogen, chloro, fluoro and hydroxy and R.sup.2 is selected from methyl, cyano, ethynyl and hydrogen; Q is selected from carbon bearing a hydrogen atom and nitrogen; and Z represents one or more substituents selected from fluoro, benzyl, phenoxy, chlorophenoxy, fluorophenoxy and bromophenoxy, or any isomer thereof. Processes for preparing these compounds and intermediates for use therein, insecticidal compositions containing these compounds and the use thereof are also disclosed.

  一种化合物的化学式：##STR1## 其中W代表从卤素、烷基、烷氧基、烷氧基烷基、卤代烷基和卤代烷氧基中选择的一个或多个取代基，或者W代表选择自烷基和烷二氧基的相邻碳原子之间的双齿基团；Y是式子##STR2## 中的一个基团，其中X是式子--(CF.sub.2).sub.n R.sup.3，其中R.sup.3选择自氢、氯和氟，n为一或二，R.sup.1选择自氢、氯、氟和羟基，R.sup.2选择自甲基、氰基、乙炔基和氢；Q选择自带有氢原子的碳和氮；Z代表从氟、苄基、苯氧基、氯苯氧基、氟苯氧基和溴苯氧基中选择的一个或多个取代基，或其任何异构体。还公开了用于制备这些化合物和中间体的方法，含有这些化合物的杀虫剂组合物以及其用途。
• Substituted alkenes, processes for their preparation and their use as pesticides
  申请人：SCHERING AKTIENGESELLSCHAFT

  公开号：EP0378285A1

  公开（公告）日：1990-07-18

  There are described new substituted alkenes of of general formula I in which in which R1, R2, R3, R4, R5, R6, R7, Y and Z, have the meanings given in the description and processes for their preparation. The compounds can be used as pesticides, especially against insects and mites.

  本文描述了一种新的取代烯烃，其一般式为I，其中R1、R2、R3、R4、R5、R6、R7、Y和Z的含义如说明中所述，并提供了其制备过程。这些化合物可用作农药，特别是用于防治昆虫和螨类。
• Novel compound, its production and insecticidal and acaricidal composition containing it as an active ingredient
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0193189A1

  公开（公告）日：1986-09-03

  This invention relates to a novel compound represented by the following general formula (I), its production, and an insecticidal and acaricidal composition containing it as an active ingredient: wherein R1 and R2, which may be the same or different, are a hydrogen atom, a halogen atom, a lower alkyl group, a trifluoromethyl group, a lower alkoxy group, a lower alkenyloxy group or a halogenated lower alkoxy group or are, taken together, a methylenedioxy group; R3 is a vinyl group or a ethynyl group; R4 is a hydrogen atom or a lower alkyl group; R5 is a hydrogen atom or a fluorine atom; R6 is a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxyl group or a trifluoromethyl group; Z is a nitrogen atom or a group represented by the formula -CH=; when Z is a nitrogen atom, Y is an oxygen atom; and when Z is a group of the formula -CH=, Y is an oxygen atom, a sulfur atom, a methylene group or a group represented by the formula -NH-.

  本发明涉及由以下通式(I)代表的新型化合物、其生产以及含有该化合物作为活性成分的杀虫和杀螨组合物： 其中 R1 和 R2（可以相同或不同）是氢原子、卤素原子、低级烷基、三氟甲基、低级烷氧基、低级烯氧基或卤代低级烷氧基，或合在一起是亚甲基二氧基；R3 是乙烯基或乙炔基；R4 是氢原子或低级烷基；R5 是氢原子或氟原子；R6 是氢原子、卤素原子、低级烷基、低级烷氧基或三氟甲基； Z 是氮原子或式 -CH= 所代表的基团；当 Z 是氮原子时，Y 是氧原子；当 Z 是式 -CH= 所代表的基团时，Y 是氧原子、硫原子、亚甲基或式 -NH- 所代表的基团。
• Oxetane and thietane derivatives having pesticidal properties
  申请人：SCHERING AKTIENGESELLSCHAFT

  公开号：EP0216228A1

  公开（公告）日：1987-04-01

  There are described newcompounds of general formula I in which R, is aryl or aryl substituted by C1-4-alkyl, halo-C1-4-alkyl, phenyl-C1-4-alkyl, C2-4-alkenyl, halo-C2-4-alkenyl, phenyl-C2-4-alkenyl, C2-4-alkynyl, halo-C2-4-alkynyl, phenyl-C2-4-alkynyl, C1-4-alkoxy, halo-C1-4-alkoxy, phenyl-C1-4-alkoxy, C2-4-alkenyloxy, alkylsulphonyloxy, haloalkylsulphonyloxy, arylsulphonyloxy, halo-C2-4-alkenyloxy, phenyl-C2-4-alkenyloxy, halo, cyano, nitro, aryloxy, haloaryloxy, C1-4-alkylaryloxy, or nitro-C1-4-alkylaryloxy, R2 and R3 are the same or different and are hydrogen, fluorine, cyano or ethynyl, R4 is phenyl or pyridyl or these groups substituted by one or more of C1-6-alkyl, halo-C1-6-alkyl, phenyl-C1-6-alkyl, C1-6-alkyl interrupted by an 0-, N- or S- atom, C2-4-alkenyl, halo-C2-4-alkenyl, phenyl-C2-4-alkenyl, C1-4-alkoxy, halo-C1-4-slkoxy, phenyl-C1-4-alkoxy, C2-4-alkenyl oxy, halo-C2-4-alkenyloxy, phenyl-C2-4-alkenyloxy, aryloxy, haloaryloxy, C1-4-alkylaryloxy, arylamino, haloarylamino, C1- 4-alkylarylamino, aryl-N-C1-4-alkylamino, aryl-N-C1. 4acylamino, aroyl, haloaroyl, C1-4-alkylaroyl, aryl, haloaryl, C,. 4-alkylaryl or halo, A is O or S and B is CH2 or 0, processes for their preparation and their use as insecticides and acaricides.

  描述了通式 I 的新化合物 其中 R，是芳基或被 C1-4-烷基、卤代-C1-4-烷基、苯基-C1-4-烷基、C2-4-烯基、卤代-C2-4-烯基、苯基-C2-4-烯基、C2-4-炔基、卤代-C2-4-炔基、苯基-C2-4-炔基、C1-4-烷氧基、卤代-C1-4-烷氧基、苯基-C1-4-烷氧基、C2-4-烯氧基、烷基磺酰氧基、卤代烷基磺酰氧基取代的芳基、苯基-C1-4-烷氧基、C2-4-烯氧基、烷基磺酰氧基、卤代烷基磺酰氧基、芳基磺酰氧基、卤代-C2-4-烯氧基、苯基-C2-4-烯氧基、卤代、氰基、硝基、芳氧基、卤代芳氧基、C1-4-烷基芳氧基或硝基-C1-4-烷基芳氧基、 R2 和 R3 相同或不同，并且是氢、氟、氰基或乙炔基、 R4 是苯基或吡啶基，或这些基团被一个或多个 C1-6-烷基、卤代-C1-6-烷基、苯基-C1-6-烷基、被 0-、N- 或 S-原子间断的 C1-6-烷基、C2-4-烯基、卤代-C2-4-烯基、苯基-C2-4-烯基、C1-4-烷氧基取代、C1-4-烷氧基、卤代-C1-4-烷氧基、苯基-C1-4-烷氧基、C2-4-烯基氧基、卤代-C2-4-烯基氧基、苯基-C2-4-烯基氧基、芳基氧基、卤代芳基氧基、C1-4-烷基芳基氧基、芳基氨基、卤代芳基氨基、C1- 4-烷基芳基氨基、芳基-N-C1-4-烷基氨基、芳基-N-C1.4-烷基氨基、芳基、卤代芳酰基、C1-4-烷基芳酰基、芳基、卤代芳基、C1.4-烷基芳基或卤代、 A 是 O 或 S，以及 B 是 CH2 或 0、 它们的制备方法以及作为杀虫剂和杀螨剂的用途。