1-丁基-1-甲基咪唑氯化物 | 1001671-76-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 1-丁基-1-甲基咪唑氯化物
• 英文名称: 1-butyl-1-methylimidazolium chloride
• 英文别名: butylmethylimidazolium chloride；1-butyl-1-methylimidazol-1-ium;chloride
• CAS: 1001671-76-6
• 化学式: C₈H₁₅N₂*Cl
• 分子量: 174.673
• InChiKey: OCVUKWHYJSLSAX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.25
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-丁基-1-甲基咪唑氯化物 在 iron(III) chloride 作用下， 以93%的产率得到butylmethylimidazolium tetrachloroferrate
  参考文献：
  名称：

  含金属离子液体作为水中羟甲基化的有效催化剂

  摘要：

  含铁离子液体丁基甲基咪唑鎓四氯铁酸盐 (bmim-FeCl4) 被证明是一种有效且可回收的催化剂，用于使用甲醛水溶液进行 β-酮酯羟甲基化，并且催化剂负载量低至 0.1 mol%，无需共溶剂或额外表面活性剂。因此，可以建立一种有用且高产的方法来制备羟甲基化酮酯以及通过串联羟甲基化-内酯化制备 3-二取代丁内酯。（© Wiley-VCH Verlag GmbH & Co. KGaA，69451 Weinheim，德国，2008）

  DOI：

  10.1002/ejoc.200800323
• 作为产物：
  描述：

  N-甲基咪唑 、 氯丁烷 在 氮气 、 乙酸乙酯 、 乙腈 作用下， 以to obtain 1-butyl-1-methylimidazolium chloride (352 g, 2.016 mol)的产率得到1-丁基-1-甲基咪唑氯化物
  参考文献：
  名称：

  LUBRICANT BASE OIL AND LUBRICANT COMPOSITION

  摘要：

  一种润滑基础油包括至少一种含有以下化合物的离子液体：Z+A−，其中Z+表示阳离子，A−表示阴离子，其中Z+是具有两个不同侧链的环状季铵离子，A−是共轭酰胺离子。

  公开号：

  US20130102506A1

文献信息

• Method For Producing Porous Metal-Organic Framework Materials
  申请人：Schubert Markus

  公开号：US20080214806A1

  公开（公告）日：2008-09-04

  The present invention relates to processes for preparing a porous metal-organic framework comprising at least two organic compounds coordinated to at least one metal ion, the porous metal-organic frameworks prepared by the process and their use, in particular for gas storage and gas separation.

  本发明涉及制备多孔金属有机框架的方法，所述多孔金属有机框架包括至少两种有机化合物配位至至少一个金属离子，所述方法制备的多孔金属有机框架及其用途，特别是用于气体储存和气体分离。
• Catalyst and Process for the Production of Hydrogen from Ammonia Boranes
  申请人：NOVAUCD

  公开号：US20160087295A1

  公开（公告）日：2016-03-24

  The present invention relates to a process for the production of hydrogen comprising contacting at least one complex of formula (I), (I) wherein: X − is an anion; M is a metal selected from Ru, Os, Fe, Co and Ni; D is optionally present and is one or more monodentate or multidentate donor ligands; Y 1 is selected from CR 13 , B and N; Z 1 and Z 2 are each independently selected from ═N, ═P, NR 14 , PR 15 , O, S and Se; or Z 2 is a direct bond between carbocyclic ring B and substituent R 4 ; each of A and B is independently a saturated, unsaturated or partially unsaturated carbocyclic hydrocarbon ring; R 3 and R 4 are each independently selected from H, C 1-6 -alkyl, aryl and C 1-6 -haloalkyl, and a linker group optionally attached to a solid support; or R 3 and R 4 together form the following moiety: (AB) Y 2 is a direct single bond or double bond, or is CR 18 ; R 1 , R 2 , R 5-13 and R 16-18 are each independently selected from H, C 1-6 -alkyl, C 2-6 -alkenyl, C 2-6 -alkynyl, aryl, C 1-6 -haloalkyl, NR 19 R 20 and a linker group optionally attached to a solid support; or two or more of said R 1-13 and R 16-18 groups are linked, together with the carbons to which they are attached, to form a saturated or unsaturated hydrocarbon group; R 14 , R 15 , R 19 and R 20 are each independently selected from H, C 1-6 -alkyl, C 2-6 -alkenyl, C 2-6 -alkynyl, aryl, C 1-6 -haloalkyl, and a linker group optionally attached to a solid support; with at least one substrate of formula (II), R 21 R 22 NH—BHR 23 R 24 , wherein R 21 to R 24 are each independently selected from H, C 1-6 -alkyl, fluoro-substituted C 1-6 -alkyl, C 6-14 -aryl and C 6-14 -aralkyl, or any two of R 21 , R 22 , R 23 and R 24 are linked to form a C 3-10 -alkylene group or C 3-10 -alkenylene group, which together with the nitrogen and/or boron atoms to which they are attached, forms a cyclic group; or a substrate comprising two, three or four substrates of formula (II) linked via one or more bridging groups so as to form a dimeric, trimeric or tetrameric species, and wherein the bridging group is selected from straight or branched C 1-6 -alkylene optionally substituted by one or more fluoro groups, boron, C 6-14 -aryl and C 6-14 -aralkyl; or a substrate comprising two, three or four substrates of formula (II) which are joined so as to form a fused cyclic dimeric, trimeric or tetrameric species. Further aspects of the invention relate to a hydrogen generation system comprising a complex of formula (I), a substrate of formula (II) and a solvent, and to the use of complexes of formula (I) in fuel cells. Another aspect of the invention relates to novel complexes of formula (I).

  本发明涉及一种制备氢气的方法，包括将式（I）的至少一个配合物与式（II）的至少一个底物接触，其中：式（I）中：X-是阴离子；M是从Ru、Os、Fe、Co和Ni中选择的金属；D可以存在，是一种或多种单齿或多齿供体配体；Y1选择自CR13、B和N；Z1和Z2各自独立地选择自═N、═P、NR14、PR15、O、S和Se；或者Z2是环状碳基环B和取代基R4之间的直接键；A和B各自独立地为饱和、不饱和或部分不饱和的碳环烃环；R3和R4各自独立地选择自H、C1-6-烷基、芳基和C1-6-卤代烷基，并且可以附加到固体支持上的连接基；或者R3和R4一起形成以下基团：（AB）；Y2是直接的单键或双键，或者是CR18；R1、R2、R5-13和R16-18各自独立地选择自H、C1-6-烷基、C2-6-烯基、C2-6-炔基、芳基、C1-6-卤代烷基、NR19R20和可以附加到固体支持上的连接基；或者所述的R1-13和R16-18中的两个或更多个基团被连接起来，与它们连接的碳一起形成饱和或不饱和的碳氢基团；R14、R15、R19和R20各自独立地选择自H、C1-6-烷基、C2-6-烯基、C2-6-炔基、芳基、C1-6-卤代烷基和可以附加到固体支持上的连接基；式（II）中：R21至R24各自独立地选择自H、C1-6-烷基、氟取代的C1-6-烷基、C6-14-芳基和C6-14-芳基烷基；或者R21、R22、R23和R24中的任意两个被连接起来形成C3-10-烷基或C3-10-烯基，它们与它们连接的氮和/或硼原子一起形成环状基团；或者包括通过一个或多个桥接基团连接的两个、三个或四个式（II）底物，以形成二聚体、三聚体或四聚体物种，其中桥接基团选择自直链或支链的C1-6-烷基，可选地被一个或多个氟基、硼、C6-14-芳基和C6-14-芳基烷基取代；或者包括两个、三个或四个式（II）底物，它们被连接起来形成融合的环状二聚体、三聚体或四聚体物种。本发明的另一方面涉及一种包括式（I）的配合物、式（II）的底物和溶剂的制氢系统，以及在燃料电池中使用式（I）的配合物的用途。本发明的另一方面涉及式（I）的新型配合物。
• LUBRICANT BASE OIL AND LUBRICANT COMPOSITION
  申请人：Yoshida Yukio

  公开号：US20130102506A1

  公开（公告）日：2013-04-25

  A lubricating base oil includes at least one of ionic liquids containing a compound represented by a formula (1): Z + A − , in which Z + represents a cation and A − represents an anion, in which Z + is a cyclic quaternary ammonium ion having two different side chains and A − is a conjugated amide ion.

  一种润滑基础油包括至少一种含有以下化合物的离子液体：Z+A−，其中Z+表示阳离子，A−表示阴离子，其中Z+是具有两个不同侧链的环状季铵离子，A−是共轭酰胺离子。
• IMIDAZOLIUM SALTS AND THE USE OF THESE IONIC LIQUIDS AS A SOLVENT
  申请人：CENTRE NATIONAL DELA RECHERCHE SCIENTIFIQUE (CNRS)

  公开号：EP1328518A1

  公开（公告）日：2003-07-23
• POLYMERIZATION OF MACROCYCLIC POLYESTER OLIGOMERS USING N-HETEROCYCLIC CARBENE CATALYSTS
  申请人：E.I. DUPONT DE NEMOURS AND COMPANY

  公开号：EP1833875A1

  公开（公告）日：2007-09-19