1-氯-4-[1-(4-氯苯基)丙-2-烯基]苯 | 819082-57-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-氯-4-[1-(4-氯苯基)丙-2-烯基]苯
• 英文名称: 3,3-bis(4-chlorophenyl)-propene
• 英文别名: 3,3-Bis(4-chlorophenyl)-1-propene；1-chloro-4-[1-(4-chlorophenyl)prop-2-enyl]benzene
• CAS: 819082-57-0
• 化学式: C₁₅H₁₂Cl₂
• 分子量: 263.166
• InChiKey: HGNDCUSEFANRBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  乙烯基溴化镁 、 4,4'-二氯二苯甲酮 在 lithium aluminium tetrahydride 、 三氯化铝 作用下， 以60%的产率得到1-氯-4-[1-(4-氯苯基)丙-2-烯基]苯
  参考文献：
  名称：

  Analysis of Non-Extractable DDT-Related Compounds in Riverine Sediments of the Teltow Canal, Berlin, by Pyrolysis and Thermochemolysis

  摘要：

  Eighteen pre-extracted samples derived from a subaquatic riverine sediment core taken from the Teltow Canal, Berlin (Germany), were treated by off-line TMAH-thermochemolysis and subsequently analyzed by GC-MS to investigate release and thermodegradation of non-extractable anthropogenic organic compounds (bound residues). Furthermore, six selected samples from the lower core section were additionally treated by off-line pyrolysis. Due to former investigations of the extractable fraction of Teltow Canal sediments, high amounts of compounds structurally related to the pesticide DDT (1,1,1-trichloro-2,2-bis(4-chlorophenyl) ethane) were anticipated within the nonextractable fraction. It has been shown that DDT-related bound residues can be gathered by pyrolysis and TMAH-thermochemolysis. Among other compounds, the experiments revealed two DDT-related degradation products (DDPU (3,3-bis(4-chlorphenyl)-1-propene) and DDPS (1,1-bis(4-chlorophenyl) propane)) which were detected for the first time in the environment. The latter compounds may represent formerly unknown metabolites or hints for the existence of carbon-carbon incorporated DDT-metabolites. Both methods tend to produce artifacts which complicate the interpretation of the results. With more knowledge on mechanisms occurring during application of pyrolysis and thermochemolysis, both methods can serve as valuable tools for analyzing bound residues in sediments.

  DOI：

  10.1021/es0605568

文献信息

• Photosensitive resin compositon, transfer material, image forming method, color filter and producing method thereof and photomask and producing method thereof
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20030129504A1

  公开（公告）日：2003-07-10

  The invention provides a colored photosensitive resin composition for forming a colored image on a transparent substrate, the colored photosensitive resin composition comprising: an alkali-soluble binder, one of a monomer and an oligomer having at least two ethylenic unsaturated double bonds, one of a photopolymerization initiator and a photopolymerization initiating system, and a pigment, said alkali-soluble binder comprising a copolymer including a structural unit having a carboxyl group, a structural unit represented by the following general formula (1), and a structural unit comprising a (meth)acrylate having at least one of an aromatic ring and an alicyclic ring: General formula (1) 1 wherein R 1 represents one of a hydrogen atom and a methyl group; and each of R 2 to R 6 independently represents one of a hydrogen atom, a substituted and unsubstituted alkyl group, a substituted and unsubstituted aryl group, a halogen atom and a cyano group.

  本发明提供了一种用于在透明基板上形成彩色图像的彩色光敏树脂组合物，该彩色光敏树脂组合物包括：碱溶性粘合剂、具有至少两个乙烯基不饱和双键的单体或低聚物之一、光聚合引发剂或光聚合引发体系之一，以及颜料，其中所述碱溶性粘合剂包括共聚物，包括具有羧基的结构单元，以下一般式（1）所表示的结构单元，以及包含至少一个芳香环和脂环的（甲基）丙烯酸酯的结构单元：一般式（1）其中，R1表示氢原子和甲基基团中的一种；R2到R6中的每一个独立地表示氢原子、取代和未取代的烷基、取代和未取代的芳基、卤素原子和氰基中的一种。
• OXIME COMPOUND, PHOTOSENSITIVE COMPOSITION, COLOR FILTER, METHOD FOR PRODUCTION OF THE COLOR FILTER, AND LIQUID CRYSTAL DISPLAY ELEMENT
  申请人：FUJIFILM Corporation

  公开号：EP2116527A1

  公开（公告）日：2009-11-11

  Provided are an oxime compound represented by General Formula (1), a photosensitive composition containing the oxime compound as a photopolymerization initiator, a production method for a color filter using the photosensitive composition, and a color filter obtained by the production method: in General Formula (1), R1 represents a hydrogen atom, an acyl group, an alkoxycarbonyl group or an aryloxylcarbonyl group, each of which may have a substituent; R2 represents or R2s each represent a halogen atom, an alkyl group, an aryl group, an alkyloxy group, an aryloxy group, an alkylthio group, an arylthio group or an amino group; m is an integer of 0 to 4; when m is an integer of 2 or more, R2s may be linked together to form a ring; and A represents a 4-, 5-, 6- or 7-membered ring.

  本文提供了通式（1）表示的肟化合物、含有该肟化合物作为光聚合引发剂的感光组合物、使用该感光组合物的彩色滤光片的生产方法，以及通过该生产方法获得的彩色滤光片： 通式（1）中，R1 代表氢原子、酰基、烷氧羰基或芳氧羰基，其中每个基团都可以有一个取代基；R2 代表或 R2s 各自代表卤原子、烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基或氨基；m 为 0 至 4 的整数；当 m 为 2 或 2 以上的整数时，R2s 可连接在一起形成环；以及 A 代表 4、5、6 或 7 元环。