The invention describes a process for stabilizing an organic material against oxidative, thermal or light-induced degradation, which comprises incorporating therein or applying thereto at least a compound of the formula (I) wherein the general symbols are as defined in claim
1
. The compounds of the formula I are especially useful as processing stabilizers for synthetic polymers.
A lubricant composition includes a base oil present in an amount of greater than 70 parts by weight per 100 parts by weight of the lubricant composition and an antioxidant. The antioxidant has the structure: wherein each X is independently CH or N, so long as at least one X is N. A is an electron donating group that (1) has an atom having at least one lone pair of electrons that is bonded directly to the aromatic ring or (2) is an aryl or alkyl group. Z is chosen from a hydrogen atom and an electron donating group that has an atom having at least one lone pair of electrons that is bonded directly to the aromatic ring or is an aryl or alkyl group.
3-Arylbenzofuranones with electron-withdrawing substituents as stabilizers
申请人:——
公开号:US20030212170A1
公开(公告)日:2003-11-13
The invention describes novel compounds of the formula (I) wherein the general symbols are as defined in claim (1) and R
1
is an aromatic radical with electron withdrawing substituents, as stabilizers for protecting organic materials, in particular polymers and lubricants, against oxidative, thermal or light-induced degradation and as scavengers for oxidized developer in color photographic material.
Disclosed are borate and boronate compounds of the formulae
1
where
R
1
, R
2
and R
3
are independently hydrogen, straight or branched chain alkyl of 1 to 24 carbon atoms, straight or branched chain alkenyl of 2 to 24 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 10 carbon atoms, aralkyl of 7 to 15 carbon atoms, alkaryl of 7 to 15 carbon atoms; Ar is substituted or unsubstituted aryl of 6 to 10 carbon atoms; and R
4
and R
5
are independently defined as for R
1
and may also be hydroxyphenyl or alkylated hydroxyphenyl, or R
4
and R
5
together with the —OBO— group form a substituted or unsubstituted 5 or 6 membered ring. The borate and boronate compounds are effective as antiwear, extreme pressure, and friction modifying additives for lubricating oils and fuels.
Lubricating oil compositions with improved performance
申请人:Al-Akhdar Walid
公开号:US20060040833A1
公开(公告)日:2006-02-23
Disclosed are stabilized lubricating oil compositions with improved oxidative performance. These lubricating oil compositions contain certain phenolic antioxidants, in combination with other antioxidants, which contribute to the improved performance. These certain phenolic antioxidants are defined in formula (I),
wherein, R1 is alkyl of 1 to 4 carbon atoms, n is 1 to 4, R2 is H or R3,
R3 is —(CH2)
x
-COOR4 where x is 1 to 10, R4 is straight or branched chain alkyl of 1 to 24 carbon atoms or E, when n is 1, E is straight or branched chain alkyl of 1 to 24 carbon atoms; when n is 2, E is straight or branched chain alkylene of 2 to 12 carbon atoms or said alkylene interrupted by one to five O or S atoms; when n is 3, E is a straight or branched chain alkanetriyl of 3 to 6 carbon atoms; and when n is 4, E is pentaerthyrityl.