氯乙氟灵 | 33245-39-5

• 物质功能分类: 化学农药原药 - 除草剂 - 其他除草剂
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 氯乙氟灵
• 中文别名: 氟消草
• 英文名称: N-(2-chloroethyl)-2,6-dinitro-N-propyl-α,α,α-trifluoro-p-toluidine
• 英文别名: N-(2-chloroethyl)-2,6-dinitro-N-propyl-4-(trifluoromethyl)aniline；fluchloralin；N-propyl-N-(2-chloroethyl)-α,α,α-trifluoro-2,6-dinitro-p-toluidine；basalin；N-(2-chloroethyl)-α,α,α-trifluoro-2,6-dinitro-N-propyl-p-toluidine；4-trifluoromethyl-2,6-dinitro-N-propyl-N-(2-chloroethyl)aniline
• CAS: 33245-39-5
• 化学式: C₁₂H₁₃ClF₃N₃O₄
• mdl: MFCD00078686
• 分子量: 355.701
• InChiKey: MNFMIVVPXOGUMX-UHFFFAOYSA-N

物化性质

• 熔点：
  42-43℃
• 沸点：
  392.3±42.0 °C(Predicted)
• 密度：
  1.4469 (estimate)
• 颜色/状态：
  Orange-yellow solid
• 气味：
  FAINT, MEDICINAL ODOR
• 闪点：
  30 °C
• 溶解度：
  In acetone, benzene, chloroform, diethyl ether, ethyl acetate >1000, cyclohexane 251, ethanol 177, olive oil 260 (all in g/kg, 20 °C)
• 蒸汽压力：
  3X10-5 mm Hg at 20 °C
• 稳定性/保质期：
  Storage stability in the original unopened container is guaranteed for 3 to 4 years at normal room temperatures; sensitive to ultraviolet and visible light.
• 腐蚀性：
  SLIGHTLY CORROSIVE
• 保留指数：
  1795.8;1798.9

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  94.9
• 氢给体数：
  0
• 氢受体数：
  8

ADMET

代谢

三种结构相关的（14）C二硝基苯胺类除草剂，包括氟氯拉林，在正常和苯巴比妥诱导的大鼠肝脏微粒体中广泛代谢。通过对乙酸乙酯提取物中代谢物的鉴定，表明脂肪族羟基化、N-脱烷基化、硝基还原和环化是体外代谢的主要途径。特别值得注意的是，形成了一种苯并咪唑代谢物。

Three structurallyrelated (14)C dinitroaniline herbicides including fluchloralin, were extensively metabolized in vitro by both normal and phenobarbital-induced rat liver microsomes. Identification of the metabolites in the ethyl acetate extracts indicated that aliphatic hydroxylation, N-dealkylation, reduction of a nitro group, and cyclization were the predominant metabolic routes in vitro. Of particular interest was the formation of a benzimidazole metabolite.

来源:Hazardous Substances Data Bank (HSDB)

代谢

大豆的根和芽将氟氯拉林代谢至少产生了10种非极性代谢物、6种极性代谢物和一些甲醇可溶的残留物。通过薄层色谱（TLC）、气相色谱（GLC）和质谱（MS）来鉴定代谢物：从切除的叶和根中获得的1-(2-氯乙基)-2-乙基-7-硝基-5-三氟甲基苯并咪唑；α-α-α-三氟-N-(2-氯乙基)-N-丙基-5-硝基甲苯-3,4-二胺；2-氯甲基-7-硝基-1-丙基-5-三氟甲基苯并咪唑；以及2-氨基-N-(2-氯乙基)-6-硝基-N-丙基-4-三氟甲基苯胺。

Soybean roots and shoots metabolized fluchloralin to at least 10 nonpolar metabolites, 6 polar metabolites, and some methanol soluble residue. TLC, GLC, and MS were used to identify metabolites: 1-(2-chloroethyl)2-ethyl-7-nitro-5-trifluoromethylbenzimidazole; alpha-alpha-alpha-trifluoro-N-(2-chloroethyl)-N-propyl-5-nitrotoluene- 3,4-diamine, obtained from excised leaves and roots; 2-chloromethyl-7-nitro-1-propyl-5-trifluoromethylbenzimidazole; and 2-amino-N-(2-chloroethyl)-6-nitro-N-propyl-4-trifluoromethylaniline.

来源:Hazardous Substances Data Bank (HSDB)

代谢

氟氯拉林在正常和苯巴比妥诱导的大鼠肝微粒体中广泛代谢。产生的代谢物表明，氟氯拉林代谢涉及N-脱烷基化、脂肪族羟基化、硝基还原和环化。薄层色谱(TLC)和气相色谱-质谱(GC-MS)分析表明，形成了2,6-二硝基-N-(正丙-3-醇基)-α,α,α-三氟-p-甲苯胺及其相应的N-(正丙-2-醇基)类似物。氟氯拉林的N-脱烷基化产生了去-2-氯乙基类似物和双脱烷基化类似物。观察到的其他代谢物包括2-氨基-6-硝基-α,α,α-三氟-p-甲苯胺、5-硝基-7-三氟甲基喹喔啉和2-乙基-7-硝基-5-三氟甲基苯并咪唑。

Fluchloralin was extensively metabolized in vitro by normal and phenobarbital induced rat liver microsomes. Metabolites produced indicated that fluchloralin metabolism involved N-dealkylation, aliphatic hydroxylation, nitro reduction and cyclization. Analyses with TLC and GC-MS indicated the formation of 2,6-dinitro-N-(n-propan-3-ol)-alpha,alpha,alpha- trifluoro-p-toluidine and the corresponding N-(n-propan-2-ol) analog. N-dealkylation of fluchloralin gave the des-2-chloroethyl analog and di- dealkylated analogs. Other metabolites observed included 2-amino-6-nitro-alpha,alpha,alpha-trifluoro-p-toluidine, 5-nitro-7-trifluoromethylquinoxaline, and 2-ethyl-7-nitro-5-trifluoromethyl benzimidazole.

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 解毒与急救

皮肤去污。皮肤污染应立即用肥皂和水清洗处理。眼睛污染应立即用大量清水长时间冲洗。如果皮肤或眼睛刺激持续存在，应立即获得医疗注意。/其他除草剂/

Skin decontamination. Skin contamination should be treated promptly by washing with soap and water. Contamination of the eyes should be treated immediately by prolonged flushing of the eyes with large amounts of clean water. If dermal or ocular irritation persists, medical attention should be obtained without delay. /Other herbicides/

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 解毒与急救

胃肠道去污。摄入这些除草剂后可能会出现呕吐和腹泻，这是由于它们的刺激性特性。管理取决于：（1）摄入量的最佳估计，（2）摄入后经过的时间，（3）受试者的临床状况。活性炭可能有效于限制刺激性效果并减少大部分或所有这些除草剂的吸收。氢氧化铝抗酸剂可能有助于中和更酸性物质的刺激性作用。如果存在肠鸣音且自发腹泻尚未开始，应给予山梨醇以诱导泻药。脱水和电解质紊乱可能严重到需要口服或静脉输液。... 如果摄入了大量除草剂，并且患者在摄入后一小时内就诊，应考虑胃肠道去污。... 如果摄入的除草剂量较小，如果已经发生了有效的呕吐，或者如果治疗延迟，通过口腔给予活性炭和山梨醇。 /其他除草剂/

Gastrointestinal decontamination. Ingestions of these herbicides are likely to be followed by vomiting and diarrhea due to their irritant properties. Management depends on: (1) the best estimate of the quantity ingested, (2) time elapsed since ingestion, and (3) the clinical status of the subject. Activated charcoal is probably effective in limiting irritant effects and reducing absorption of most or all of these herbicides. Aluminum hydroxide antacids may be useful in neutralizing the irritant actions of more acidic agents. Sorbitol should be given to induce catharsis if bowel sounds are present and if spontaneous diarrhea has not already commenced. Dehydration and electrolyte disturbances may be severe enough to require oral or intravenous fluids. ... If large amounts of herbicide have been ingested and the patient is seen within an hour of the ingestion, gastrointestinal decontamination should be considered ... If the amount of ingested herbicides was small, if effective emesis has already occurred, or if treatment is delayed, administer activated charcoal and sorbitol by mouth. /Other herbicides/

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 解毒与急救

静脉输液。如果严重脱水和电解质耗尽是由呕吐和腹泻引起的，监测血液电解质和液体平衡，并给予葡萄糖、生理盐水、林格溶液或林格乳酸盐的静脉输注，以恢复细胞外液容量和电解质。一旦能够保留液体，随即给予口服营养。/其他除草剂/

Intravenous fluids. If serious dehydration and electrolyte depletion have occurred as a result of vomiting and diarrhea, monitor blood electrolytes and fluid balance and administer intravenous infusions of glucose, normal saline, Ringer's solution, or Ringer's lactate to restore extracellular fluid volume and electrolytes. Follow this with oral nutrients as soon as fluids can be retained. /Other herbicides/

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 解毒与急救

支持性措施通常足以成功管理对这些除草剂的过度暴露...如果尽管有良好的支持性护理，患者的状况仍然恶化，应怀疑有其他替代或额外的有毒物质的作用。/其他除草剂/

Supportive measures are ordinarily sufficient for successful management of excessive exposures to these herbicides ... If the patient's condition deteriorates in spite of good supportive care, the operation of an alternative or additional toxicant should be suspected. /Other herbicides/

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 人类毒性摘录

体征和症状：可能略有刺激性。氟硝基甲苯 herbicides 不会解偶联氧化磷酸化或生成变性血红蛋白。

/SIGNS AND SYMPTOMS/ May be mildly irritating. /Flurodinitrotoluidine/ herbicides do not uncouple oxidative phosphorylation or generate methemoglobin.

来源:Hazardous Substances Data Bank (HSDB)

吸收、分配和排泄

几乎没有叶片吸收。氟氯拉林用于土壤施用。具有转运特性；整个植物的根部吸收和向顶端的运动。

Little or no foliar absorption. Fluchloralin is used for soil incorporated applications. Translocation characteristics; root uptake and acropetal movement throughout the entire plant occurs.

来源:Hazardous Substances Data Bank (HSDB)

安全信息

• 危险品标志：
  N
• 安全说明：
  S60,S61
• 危险类别码：
  R50/53
• WGK Germany：
  2
• 海关编码：
  2921430033
• 危险品运输编号：
  UN3077 9/PG 3

SDS

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SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifiers
Product name : Fluchloralin
REACH No. : A registration number is not available for this substance as the substance
or its uses are exempted from registration, the annual tonnage does not
require a registration or the registration is envisaged for a later
registration deadline.
CAS-No. : 33245-39-5
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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SECTION 2: Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute aquatic toxicity (Category 1), H400
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
N Dangerous for the R50/53
environment
For the full text of the R-phrases mentioned in this Section, see Section 16.
Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word Warning
Hazard statement(s)
H400 Very toxic to aquatic life.
Precautionary statement(s)
P273 Avoid release to the environment.
Supplemental Hazard none
Statements
Other hazards - none

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SECTION 3: Composition/information on ingredients
Substances
Formula : C12H13ClF3N3O4
Molecular Weight : 355,70 g/mol
CAS-No. : 33245-39-5
EC-No. : 251-426-0
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Fluchloralin
CAS-No. 33245-39-5 Aquatic Acute 1; H400 <= 100 %
EC-No. 251-426-0
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
Fluchloralin
CAS-No. 33245-39-5 N, R50/53 <= 100 %
EC-No. 251-426-0
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

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SECTION 4: First aid measures
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
Indication of any immediate medical attention and special treatment needed
no data available

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SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
no data available
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

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SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

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SECTION 7: Handling and storage
Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

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SECTION 8: Exposure controls/personal protection
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards
such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Choose body protection in relation to its type, to the concentration and amount of dangerous
substances, and to the specific work-place., The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired,
use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.

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SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing no data available
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evapouration rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility insoluble
o) Partition coefficient: n- log Pow: 4,63
octanol/water
p) Auto-ignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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SECTION 10: Stability and reactivity
Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5

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SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
LD50 Oral - rat - 2.940 mg/kg
LC50 Inhalation - rat - 4 h - 8.400 mg/m3
LD50 Dermal - rabbit - > 10.000 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
Human
lymphocyte
Cytogenetic analysis
Human
lymphocyte
Micronucleus test
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: XU5160000
Central nervous system depression, To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.

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SECTION 12: Ecological information
Toxicity
Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 0,02 mg/l - 96,0 h
Toxicity to daphnia and EC50 - Daphnia magna (Water flea) - 0,56 mg/l - 48 h
other aquatic
invertebrates
Persistence and degradability
Bioaccumulative potential
Bioaccumulation Gambusia affinis (Mosquito fish) - 72 h
- 14,8 µg/l
Bioconcentration factor (BCF): 32
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
Very toxic to aquatic life.

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SECTION 13: Disposal considerations
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

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SECTION 14: Transport information
UN number
ADR/RID: 3077 IMDG: 3077 IATA: 3077
UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Fluchloralin)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Fluchloralin)
IATA: Environmentally hazardous substance, solid, n.o.s. (Fluchloralin)
Transport hazard class(es)
ADR/RID: 9 IMDG: 9 IATA: 9
Packaging group
ADR/RID: III IMDG: III IATA: III
Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes
Special precautions for user
Further information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination
packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

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SECTION 15 - REGULATORY INFORMATION
N/A

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

类别：农药
毒性分级：中毒
急性毒性：

• 大鼠 LD50: 2940 毫克/公斤
• 小鼠 LD50: 730 毫克/公斤

可燃性危险特性： 燃烧会产生有毒的氮氧化物、氯化物和氟化物气体。

储运特性： 需存放在通风低温干燥的库房内，并与食品原料分开储存和运输。

灭火剂： 使用干粉、泡沫或砂土进行灭火。

反应信息

• 作为产物：
  描述：

  4-氯-3,5-二硝基三氟甲苯 、 1-propylaziridine 生成 氯乙氟灵
  参考文献：
  名称：

  Nestler,H.J.; Bestian,H., Justus Liebigs Annalen der Chemie, 1974, p. 460 - 467

  摘要：

  DOI：

文献信息

• [EN] 3-[(HYDRAZONO)METHYL]-N-(TETRAZOL-5-YL)-BENZAMIDE AND 3-[(HYDRAZONO)METHYL]-N-(1,3,4-OXADIAZOL-2-YL)-BENZAMIDE DERIVATIVES AS HERBICIDES<br/>[FR] DÉRIVÉS DE 3-[(HYDRAZONO))MÉTHYL]-N-(TÉTRAZOL-5-YL)-BENZAMIDE ET DE 3-[(HYDRAZONO)MÉTHYL]-N-(1,3,4-OXADIAZOL-2-YL)-BENZAMIDE UTILISÉS EN TANT QU'HERBICIDES
  申请人：SYNGENTA CROP PROTECTION AG

  公开号：WO2021013969A1

  公开（公告）日：2021-01-28

  The present invention related to compounds of Formula (I): or an agronomically acceptable salt thereof, wherein Q, R2, R3, R4, R5 and R6 are as described herein. The invention further relates to compositions comprising said compounds, to methods of controlling weeds using said compositions, and to the use of compounds of Formula (I) as a herbicide.

  本发明涉及以下式（I）的化合物或其农业上可接受的盐，其中Q、R2、R3、R4、R5和R6如本文所述。该发明还涉及包含所述化合物的组合物，使用这些组合物控制杂草的方法，以及将式（I）的化合物用作除草剂的用途。
• [EN] INSECTICIDAL TRIAZINONE DERIVATIVES<br/>[FR] DÉRIVÉS DE TRIAZINONE INSECTICIDES
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2013079350A1

  公开（公告）日：2013-06-06

  Compounds of the formula (I) or (I'), wherein the substituents are as defined in claim 1, are useful as pesticides.

  式(I)或(I')的化合物，其中取代基如权利要求1所定义的那样，可用作杀虫剂。
• [EN] HERBICIDALLY ACTIVE HETEROARYL-S?BSTIT?TED CYCLIC DIONES OR DERIVATIVES THEREOF<br/>[FR] DIONES CYCLIQUES SUBSTITUÉES PAR HÉTÉROARYLE À ACTIVITÉ HERBICIDE OU DÉRIVÉS DE CELLES-CI
  申请人：SYNGENTA LTD

  公开号：WO2011012862A1

  公开（公告）日：2011-02-03

  The invention relates to a compound of formula (I), which is suitable for use as a herbicide wherein G is hydrogen or an agriculturally acceptable metal, sulfonium, ammonium or latentiating group; Q is a unsubstituted or substituted C3-C8 saturated or mono-unsaturated heterocyclyl containing at least one heteroatom selected from O, N and S, or Q is heteroaryl or substituted heteroaryl; m is 1, 2 or 3; and Het is an optionally substituted monocyclic or bicyclic heteroaromatic ring; and wherein the compound is optionally an agronomically acceptable salt thereof.

  该发明涉及一种化合物，其化学式为(I)，适用作为除草剂，其中G为氢或农业可接受的金属、磺酸盐、铵盐或潜伏基团；Q为未取代或取代的含有至少一个来自O、N和S的杂原子的饱和或单不饱和的C3-C8杂环烷基，或Q为杂芳基或取代的杂芳基；m为1、2或3；Het为可选择地取代的单环或双环杂芳环；且该化合物可选择地为其农学上可接受的盐。
• Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto
  申请人：Dow AgroSciences LLC

  公开号：US20180279612A1

  公开（公告）日：2018-10-04

  This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

  这份披露涉及具有对节肢动物门、软体动物门和线虫门害虫具有杀虫效用的分子领域，用于生产此类分子的过程，用于此类过程的中间体，含有此类分子的杀虫组合物，以及使用此类杀虫组合物对抗此类害虫的过程。这些杀虫组合物可以用作螨虫剂、杀虫剂、螨虫剂、软体动物杀虫剂和线虫杀虫剂。本文件披露了具有以下式（“式一”）的分子。
• [EN] NOVEL HERBICIDES<br/>[FR] NOUVEAUX HERBICIDES
  申请人：SYNGENTA LTD

  公开号：WO2009015877A1

  公开（公告）日：2009-02-05

  Bicyclic dione compounds, and derivatives thereof, which are suitable for use as herbicides. formula (I)

  双环二酮化合物及其衍生物，适用于用作除草剂。公式（I）

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