2,2',3,3'-四氯-4,4'-二氨基二苯甲烷 | 42240-73-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,2',3,3'-四氯-4,4'-二氨基二苯甲烷
• 中文别名: 硬化剂TCDAM；双(4-氨基-2,3-二氯苯)甲烷；4,4'-亚甲基双(2,3-二氯苯胺)；二(4-氨基-2,3-二氯苯)甲烷；4,4'-二氨基-2,2',3,3'-四氯二苯基甲烷；双(4-氨基-2,3-二氯苯基)甲烷；2(4-氨基-2,3-二氯苯)甲烷
• 英文名称: Bis(4-amino-2,3-dichlorophenyl)methane
• 英文别名: 4-[(4-amino-2,3-dichlorophenyl)methyl]-2,3-dichloroaniline
• CAS: 42240-73-3
• 化学式: C₁₃H₁₀Cl₄N₂
• 分子量: 336.0
• InChiKey: PPUHQXZSLCCTAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 安全说明：
  S24/25
• 海关编码：
  2921590090

文献信息

• [EN] NEW TETRAHYDROPYRANYL COMPOUND AND METHOD FOR PRODUCING THE TETRAHYDROPYRANYL COMPOUND<br/>[FR] NOUVEAU COMPOSÉ TÉTRAHYDROPYRANYLE ET PROCÉDÉ DE PRODUCTION DU COMPOSÉ TÉTRAHYDROPYRANYLE
  申请人：RICOH CO LTD

  公开号：WO2011158950A1

  公开（公告）日：2011-12-22

  To provide a tetrahydropyranyl compound represented by General Formula (1) below: General Formula (1) where X denotes any one of a substituted or unsubstituted alkyl group, an oxygen atom, and a substituted or unsubstituted aromatic hydrocarbon group, R1, R2, R3, R4, R5 and R6 each denote any one of a hydrogen atom, a methyl group and an ethyl group, and n denotes an integer of 1 to 4.

  提供以下通式（1）所代表的四氢吡喃基化合物：通式（1）中，X表示取代或未取代的烷基、氧原子以及取代或未取代的芳香烃基中的任意一个；R1、R2、R3、R4、R5和R6分别表示氢原子、甲基和乙基中的任意一个；n表示1到4之间的整数。
• Process for producing unsaturated dicarboxylic acid imide compound
  申请人：MATSUSHITA ELECTRIC WORKS, LTD.

  公开号：EP0387381A1

  公开（公告）日：1990-09-19

  A process for producing an unsaturated di­carboxylic acid imide compound of formula (I): wherein D represents a divalent organic group having at least one carbon/carbon double bond; R¹ represents an n-­valent organic group having at least one carbon atom; and n is an integer of 1 or above, which comprises reacting an unsaturated amide acid compound of formula (II): wherein D, R¹, and n are as defined above, with an orthoester of formula (III): R²-C⁅OR³]₃      (III) wherein R² and R³, which may be the same or different, each represents a monovalent organic group having at least one carbon atom, to form an unsaturated dicarboxylic acid amide acid ester compound of formula (IV): wherein D, R¹, R³, and n are as defined above, and then imidating the compound of formula (IV).

  一种制备式（I）的不饱和二羧酸酰亚胺化合物的方法：其中D表示至少具有一个碳/碳双键的二价有机基团；R¹表示至少具有一个碳原子的n价有机基团；n为1或以上的整数；包括将式（II）的不饱和酰胺酸化合物与式（III）的正酯发生反应：R²-C⁅OR³]₃      （III），其中R²和R³，可以相同也可以不同，每个都表示至少具有一个碳原子的一价有机基团，形成式（IV）的不饱和二羧酸酰胺酸酯化合物：其中D，R¹，R³和n如上定义，然后对式（IV）的化合物进行亚胺化。
• Epoxy resin composition
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0161576A2

  公开（公告）日：1985-11-21

  57 A thermosettable epoxy resin composition comprising 100 parts by weight of an epoxy resin, 5 to 40 parts by weight of a polysulfone resin having both a resorcinol moiety and 4,4'-dichlorodiphenylsulfone moiety in the molecular chain, and an effective amount of a curing agent, which gives a cured product excellent in toughness as well as in curability, adhesion, mechanical strength at high temperatures and resistance to chemicals.

  57 一种热固性环氧树脂组合物，其成分包括 100 重量份的环氧树脂、5 至 40 重量份的聚砜树脂（分子链中同时含有间苯二酚分子和 4,4'- 二氯二苯砜分子）以及有效量的固化剂，固化后的产品具有优异的韧性、固化性、粘附性、高温下的机械强度和耐化学性。
• Thermosettable heat-resistant epoxy resin composition
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0188337A2

  公开（公告）日：1986-07-23

  An epoxy resin composition curable to a heat resistant product comprises (i) amino group-terminated imide compound (A) produced by imidating at least one aromatic diamine selected from those of formulae (I), (II) and (III), wherein R,, R2, R3, R4 and R5 are selected independently from hydrogen and halogen atoms and C1-C5 alkyl, C1-C3 alkoxy and hydroxyl groups and the or each X represents a divalent group selected from with at least one aromatic tetracarboxylic anhydride at a diamine:anhydride molar ratio of from 1.2:1 to 4:1, and epoxy resin (B) having at least two epoxy groups in the molecule, the molar ratio of the amino group content of imide compound (A) to the epoxy group content of epoxy resin (B) being 1:1.6 to 1:2.6; or (ii) epoxy resin (D) having two or more β-unsubstituted glycidyl groups in the molecule and aromatic amide-imide compound (E) having both an imide and amide groups in the molecule and a terminal amino group.

  一种可固化成耐热产品的环氧树脂组合物包括 (i) 由至少一种选自式(I)、(II)和(III)的芳香族二胺酰亚胺化而成的氨基封端酰亚胺化合物 (A)、 其中 R、R2、R3、R4 和 R5 分别独立地选自氢、卤素原子、C1-C5 烷基、C1-C3 烷氧基和羟基，或每个 X 代表选自以下各项的二价基团 与至少一个芳香族四羧酸酐的二胺：酸酐摩尔比为 1.2:1 至 4:1，以及分子中至少有两个环氧基团的环氧树脂（B），亚胺化合物（A）的氨基含量与环氧树脂（B）的环氧基团含量的摩尔比为 1:1.6 至 1:2.6；或(ii) 分子中含有两个或两个以上 β-未取代缩水甘油基的环氧树脂(D)和分子中含有酰亚胺和酰胺基以及末端氨基的芳香族酰胺-酰亚胺化合物(E)。
• Use of imides hardeners for epoxy resins and epoxy resin compositions containing these imides.
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0214750A1

  公开（公告）日：1987-03-18

  Imide compounds of formula (wherein the X's are selected from hydroxyl and amino groups; the Ar1's, and the or each Ar2 if present, are selected independently from aromatic residues; the or each R1 is selected independently from a hydrogen atom and C1-C10 alkyl groups: the or each R2 is selected independently from a hydrogen atom, a hydroxyl group; and C1-C20 alkyl and alkoxy groups; and n is zero or an integer of up to 30) are hardeners for epoxy resin compositions yielding hardened epoxy products of improved thermal resistance.

  式中的酰亚胺化合物 (其中 X 选自羟基和氨基；Ar1 和每个 Ar2（如有）独立选自芳香族残基；R1 或每个 R1 独立选自氢原子和 C1-C10 烷基；R2 或每个 R2 独立选自氢原子、羟基、C1-C20 烷基和烷氧基；n 为零或不超过 30 的整数）是环氧树脂组合物的固化剂，可产生耐热性更好的硬化环氧产品。