2,4,6-三(2,3,4,5,6-五氟苯基)-1,3,5-三嗪 | 160248-96-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,4,6-三(2,3,4,5,6-五氟苯基)-1,3,5-三嗪
• 中文别名: 2,4,6-三(全氟苯基)-1,3,5-三嗪
• 英文名称: 2,4,6-tris(pentafluorophenyl)-1,3,5-triazine
• 英文别名: 2,4,6-tris(perfluorophenyl)-1,3,5-triazine；perfluoro(triphenyltriazine)；2,4,6-tris(2,3,4,5,6-pentafluorophenyl)-1,3,5-triazine
• CAS: 160248-96-4
• 化学式: C₂₁F₁₅N₃
• 分子量: 579.227
• InChiKey: SIXHTOROHGVBMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  39
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  2,4,6-三(2,3,4,5,6-五氟苯基)-1,3,5-三嗪 、 阻聚剂701 在 sodium amide 作用下， 以 1,3-二甲基-2-咪唑啉酮 为溶剂， 反应 0.5h， 以46%的产率得到
  参考文献：
  名称：

  Synthesis of Polynitroxides Based on Nucleophilic Aromatic Substitution

  摘要：

  The scope and limitations of the synthesis of polynitroxides by nucleophilic substitution of electron-deficient fluorinated aromatic compounds are described. The method provides a facile route to the formation of polynitroxides exhibiting strong electron exchange between nitroxide groups.

  DOI：

  10.1021/ol101529u
• 作为产物：
  描述：

  五氟苯腈 在 氟磺酸 作用下， 反应 168.0h， 以46%的产率得到2,4,6-三(2,3,4,5,6-五氟苯基)-1,3,5-三嗪
  参考文献：
  名称：

  用于全氟渐变折射率聚合物光纤的掺杂剂

  摘要：

  一种全氟化渐变折射率聚合物光纤 (PFGI-POF) 已开发和制造用于数据通信，以提供高带宽、易于端接和布线。在 PFGI-...

  DOI：

  10.1246/bcsj.77.2121

文献信息

• METAL-COMPLEX COMPOUND AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE COMPOUND
  申请人：WATANABE Masami

  公开号：US20070108891A1

  公开（公告）日：2007-05-17

  A metal complex compound having a specific structure having a metal such as iridium, and an organic electroluminescence device which has an organic thin film layer having one layer or a plurality of layers including at least a light emitting layer and disposed between a pair of electrodes and contains the metal complex in at least one layer in the organic thin film layer. The organic electroluminescence device exhibits a great efficiency of light emission and has a long life due to the metal complex compound.

  一种具有特定结构的金属络合物化合物，其中金属例如铱，并且具有包括至少一个发光层的一个层或多个层的有机薄膜层，位于一对电极之间并在有机薄膜层中的至少一层中含有金属络合物的有机电致发光器件。由于金属络合物化合物，这种有机电致发光器件表现出很高的发光效率并且具有长寿命。
• Highly Perfluorinated Covalent Triazine Frameworks Derived from a Low‐Temperature Ionothermal Approach Towards Enhanced CO ₂ Electroreduction
  作者：Xian Suo、Fengtao Zhang、Zhenzhen Yang、Hao Chen、Tao Wang、Zongyu Wang、Takeshi Kobayashi、Chi‐Linh Do‐Thanh、Dmitry Maltsev、Zhimin Liu、Sheng Dai

  DOI：10.1002/anie.202109342

  日期：2021.12

  low-temperature ionothermal approach (275 °C) to prepare F-CTFs, which is achieved via polymerization of tetrafluoroterephthalonitrile (TFPN) over the Lewis superacids, e.g., zinc triflimide [Zn(NTf2 )2 ] without side reactions. With low catalyst loading (equimolar), F-CTFs are afforded with high fluorine content (31 wt %), surface area up to 367 m2  g-1 , and micropores around 1.1 nm. The highly hydrophobic

  全氟化共价三嗪骨架（F-CTFs）在分离和催化方面表现出独特的特性和吸引人的性能。然而，由于氯化物（路易斯碱）引起的 CF 键断裂和部署的苛刻条件（400-700°C），通过 ZnCl2 促进的程序合成的最先进的 F-CTF 具有相当低的氟含量。制造具有高氟含量（> 30 wt%）的 F-CTF 仍然具有挑战性。在此，我们提出了一种低温电离热方法 (275 °C) 来制备 F-CTF，这是通过四氟对苯二甲腈 (TFPN) 在路易斯超强酸（例如三氟甲磺酸锌 [Zn(NTf2 )2 ] 上无副反应的情况下进行聚合来实现的） . 在低催化剂负载（等摩尔）的情况下，F-CTF 具有高氟含量（31 重量%）、高达 367 m2 g-1 的表面积和约 1.1 nm 的微孔。
• Fluorine-containing diene, its production method and its polymer
  申请人：Asahi Glass Company, Limited

  公开号：US20010047115A1

  公开（公告）日：2001-11-29

  A fluorine-containing diene represented by the formula 1: CF 2 ═CF(CF 2 ) n CXYOCF═CF 2 Formula 1 wherein each of X and Y which are independent of each other, is an atom selected from a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom and an iodine atom, provided that X and Y are not simultaneously hydrogen atoms or fluorine atoms, and n is an integer of from 1 to 3.

  一种含氟二烯，其化学式为1:CF2═CF(CF2)nCXYOCF═CF2，其中X和Y分别为氢原子、氟原子、氯原子、溴原子或碘原子中的一种，且X和Y不能同时为氢原子或氟原子，n为1至3的整数。
• Fluorine-containing resin composition
  申请人：Asahi Glass Company Ltd.

  公开号：EP0905179A1

  公开（公告）日：1999-03-31

  A fluorine-containing resin composition comprising at least one fluorine-containing polycyclic compound (A) selected from the group consisting of the following compounds (A1), (A2) and (A3), and a polymer (B) having a fluorine-containing alicyclic structure: (A1) a fluorine-containing non-condensed polycyclic compound having at least two fluorine-containing rings bonded by a bond containing at least one member selected from the group consisting of a triazine ring, an oxygen atom, a sulfur atom, a phosphorus atom and a metal atom, each of said fluorine-containing rings being a carbon ring or a heterocyclic ring, of which some or all of hydrogen atoms are substituted by a fluorine atom or a fluorine-containing group; (A2) a fluorine-containing non-condensed polycyclic compound having at least three fluorine-containing rings bonded directly or by a bond containing a carbon atom, each of said fluorine-containing rings being a carbon ring or a heterocyclic ring, of which some or all of hydrogen atoms are substituted by a fluorine atom or a fluorine-containing group; (A3) a fluorine-containing condensed polycyclic compound which is a condensed polycyclic compound composed of at least three carbon rings or heterocyclic rings, of which some or all of hydrogen atoms are substituted by a fluorine atom or a fluorine-containing group.

  一种含氟树脂组合物，包含至少一种从以下化合物（A1）、（A2）和（A3）组成的组中选出的含氟多环化合物（A），以及一种具有含氟脂环结构的聚合物（B）： (A1) 具有至少两个含氟环的含氟非缩合多环化合物，这两个含氟环通过含有至少一个选 自三嗪环、氧原子、硫原子、磷原子和金属原子组成的组的键结合，每个所述含氟环是 碳环或杂环，其中部分或全部氢原子被氟原子或含氟基团取代； (A2) 含氟非缩合多环化合物，至少有三个含氟环直接或通过含有碳原子的键结合在一起，每个含氟环是碳环或杂环，其中部分或全部氢原子被氟原子或含氟基团取代； (A3) 含氟缩合多环化合物，它是由至少三个碳环或杂环组成的缩合多环 化合物，其中部分或全部氢原子被氟原子或含氟基团取代。
• NOVEL FLUORINE COMPOUND, PROCESS FOR PRODUCING THE SAME, AND POLYMER THEREOF
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP1285905A1

  公开（公告）日：2003-02-26

  A novel polymer useful as an optical resin material excellent in heat resistance, a novel monomer for obtaining the polymer, etc., are provided. A fluorinated diene represented by CF2=CF(CF2)nC(CF3)ROCF=CF2 (wherein R is a fluorine atom or a trifluoromethyl group, and n is an integer of from 1 to 3), and a polymer thereof.

  本发明提供了一种作为光学树脂材料使用的耐热性能优异的新型聚合物、一种用于获得该聚合物的新型单体等。由 CF2=CF(CF2)nC(CF3)ROCF=CF2 表示的氟化二烯（其中 R 为氟原子或三氟甲基，n 为 1 至 3 的整数）及其聚合物。