2,4-二(1-金刚烷基)苯酚 | 29690-00-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,4-二(1-金刚烷基)苯酚
• 英文名称: 2,4-di(1-adamantyl)phenol
• 英文别名: 2,4-bis(1-adamantyl)phenol；2,4-Di-(1-adamantyl)phenol
• CAS: 29690-00-4
• 化学式: C₂₆H₃₄O
• 分子量: 362.555
• InChiKey: SGWYPSQWQGYBIP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  苯酚 、 1-金刚烷醇 以2%的产率得到
  参考文献：
  名称：

  KOSHCHIJ, V. A.;KOZLIKOVSKIJ, YA. B.;YURCHENKO, A. G., ZH. ORGAN. XIMII, 24,(1988) N 9, S. 1922-1925

  摘要：

  DOI：

文献信息

• ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, AND RESIN COMPOSITION CONTAINING ADAMANTANE DERIVATIVE
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP2090563A1

  公开（公告）日：2009-08-19

  The present invention is an adamantane derivative which provides optical characteristics such as transparency, (long term) light resistance and the like, long term heat resistance, electric characteristics such as dielectric constant and the like; and good mechanical properties; a production method thereof; and a resin composition containing the above-mentioned adamantane derivative that is an adamantane derivative represented by general formulae (I) to (III); for example, a production method of an adamantane derivative represented by the general formula (III) by reacting an adamantane derivative represented by the general formula (II) with acrylates, a resin composition containing an adamantane derivative represented by the general formula (II) and an epoxy resin curing agent, and a resin composition containing an adamantane derivative represented by the general formula (III) and a thermopolymerization initiator or a photopolymerization initiator. In the formula, R1 represents CnH2n+1 (n is an integer of 1 to 10); R2 represents H, CH3, F or CF3; j is an integer of 1 to 4; k is an integer of 0 to 3; m is an integer of 2 to 5; and j+k+m≤6,

  本发明是一种金刚烷衍生物，具有透明度、（长期）耐光性等光学特性，长期耐热性，介电常数等电学特性；以及良好的机械性能；一种制备方法；以及包含上述金刚烷衍生物的树脂组合物，该金刚烷衍生物是由通式（I）到（III）表示的金刚烷衍生物，例如通过将由通式（II）表示的金刚烷衍生物与丙烯酸酯反应制备通式（III）表示的金刚烷衍生物的制备方法，以及包含由通式（II）表示的金刚烷衍生物和环氧树脂固化剂的树脂组合物，以及包含由通式（III）表示的金刚烷衍生物和热聚合引发剂或光聚合引发剂的树脂组合物。在公式中，R1表示CnH2n+1（n为1至10的整数）；R2表示H、CH3、F或CF3；j为1至4的整数；k为0至3的整数；m为2至5的整数；且j+k+m≤6。
• Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US11254763B2

  公开（公告）日：2022-02-22

  This invention relates to transition metal complexes of a dianionic, tridentate ligand that features a central neutral heterocyclic Lewis base and two phenolate donors, where the tridentate ligand coordinates to the metal center to form two eight-membered rings. Preferably the bis(phenolate) complexes are represented by Formula (I): where M, L, X, m, n, E, E′, Q, R1, R2, R3, R4, R1′, R2′, R3′, R4′, A1, A1′, are as defined herein, where A1QA1′ are part of a heterocyclic Lewis base containing 4 to 40 non-hydrogen atoms that links A2 to A2′ via a 3-atom bridge with Q being the central atom of the 3-atom bridge.

  本发明涉及二阴离子三叉配体的过渡金属配合物，该配体具有一个中心中性杂环路易斯碱和两个苯酚供体，其中三叉配体与金属中心配位形成两个八元环。双（苯酚）配合物最好用式 (I) 表示： 式中 M、L、X、m、n、E、E′、Q、R1、R2、R3、R4、R1′、R2′、R3′、R4′、A1、A1′、 如本文所定义，其中 A1QA1′ 是含有 4 至 40 个非氢原子的杂环路易斯碱的一部分，该路易斯碱通过 3 原子桥将 A2 与 A2′ 连接起来，Q 是 3 原子桥的中心原子。
• Koshchii, V. A.; Kozlikovskii, Ya. B.; Yurchenko, A. G., Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 9, p. 1733 - 1736
  作者：Koshchii, V. A.、Kozlikovskii, Ya. B.、Yurchenko, A. G.

  DOI：——

  日期：——
• KOSHCHIJ, V. A.;KOZLIKOVSKIJ, YA. B.;YURCHENKO, A. G., ZH. ORGAN. XIMII, 24,(1988) N 9, S. 1922-1925
  作者：KOSHCHIJ, V. A.、KOZLIKOVSKIJ, YA. B.、YURCHENKO, A. G.

  DOI：——

  日期：——
• TRANSITION METAL BIS(PHENOLATE) COMPLEXES AND THEIR USE AS CATALYSTS FOR OLEFIN POLYMERIZATION
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：EP3924394A1

  公开（公告）日：2021-12-22