2,5-二硝基苯甲腈 | 2112-24-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,5-二硝基苯甲腈
• 英文名称: 2,5-Dinitrobenzonitrile
• 英文别名: 2,5-Dinitrobenzonitril
• CAS: 2112-24-5
• 化学式: C₇H₃N₃O₄
• 分子量: 193.119
• InChiKey: BUDYMWWQYLMHBU-UHFFFAOYSA-N

物化性质

• 沸点：
  368.2±32.0 °C(Predicted)
• 密度：
  1.55±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  115
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 海关编码：
  2926909090

反应信息

• 作为反应物：
  描述：

  2,5-二硝基苯甲腈 生成 2-氰基-4-硝基苯胺
  参考文献：
  名称：

  KLAUBERT, D. H.;SELLSTEDT, J. H.;GUINOSSO, C. J.;CAPETOLA, R. J.;BELL, S.+, J. MED. CHEM., 1981, 24, N 6, 742-748

  摘要：

  DOI：
• 作为产物：
  描述：

  2,5-二硝基苯甲酸 生成 2,5-二硝基苯甲腈
  参考文献：
  名称：

  Cyano and nitro group effect on the rate of methoxydenitration reaction in the pyrrole and benzene ring

  摘要：

  DOI：

  10.1021/jo00187a014

文献信息

• Compositions and methods for treating heart failure
  申请人：Malik Fady

  公开号：US20050148638A1

  公开（公告）日：2005-07-07

  Certain substituted benzamide derivatives selectively modulate the cardiac sarcomere, for example by potentiating cardiac myosin, and are useful in the treatment of systolic heart failure including congestive heart failure.

  某些取代苯甲酰胺衍生物可以选择性地调节心肌肌节，例如通过增强心肌肌球蛋白，并且在治疗收缩性心力衰竭，包括充血性心力衰竭方面非常有用。
• POLYARYLENE BLOCK COPOLYMER HAVING SULFONIC ACID GROUP AND USE THEREOF
  申请人：YAMAKAWA Yoshitaka

  公开号：US20120052412A1

  公开（公告）日：2012-03-01

  A polyarylene copolymer having a sulfonic acid group which has high proton conductivity and reduced swelling in hot water and reduced shrinkage in drying; a solid polymer electrolyte and a proton conductive membrane comprising the copolymer; and a membrane-electrode assembly using these. The polyarylene block copolymer comprises a polymer segment (A) having a sulfonic acid group, and a polymer segment (B) having substantially no sulfonic acid group, the polymer segment (B) having substantially no sulfonic acid group comprising a structural unit represented by the following formula (1).

  一种具有磺酸基的聚芳烃共聚物，具有高质子传导性能，在热水中具有减少肿胀和干燥中减少收缩的特性；包括该共聚物的固体聚合物电解质和质子导电膜；以及使用这些的膜电极组件。该聚芳烃嵌段共聚物包括具有磺酸基的聚合物段（A）和基本上没有磺酸基的聚合物段（B），基本上没有磺酸基的聚合物段（B）包括由以下公式（1）表示的结构单元。
• Sulfonated polymer having nitrile-containing hydrophobic block and solid polymer electrolyte
  申请人：JSR Corporation

  公开号：EP1524288A2

  公开（公告）日：2005-04-20

  Provided are a sulfonated polymer capable of high hot water resistance even if it has an increased amount of the sulfonic groups introduced therein, and a solid polymer electrolyte containing the sulfonated polymer that has high proton conductivity and excellent generating performance. The sulfonated polymer has repeating units represented by the formula (1'): wherein B' s are each independently an oxygen or a sulfur atom, R1 to R3 may be the same or different and are selected from a hydrogen atom, a fluorine atom, a nitrile group and an alkyl group, n is an integer of 2 or greater, and Q is a structure represented by the formula (q): wherein A is independently a divalent atom or organic group or a direct bond, and R4 to R11 may be the same or different and are selected from a hydrogen atom, a fluorine atom, an alkyl group and an aromatic group.

  本发明提供了一种即使引入更多磺酸基团也能具有高耐热水性的磺化聚合物，以及一种含有该磺化聚合物的固体聚合物电解质，该电解质具有高质子传导性和优异的发电性能。 磺化聚合物具有由式（1'）表示的重复单元： 其中 B' s 各自独立地为氧原子或硫原子，R1 至 R3 可以相同或不同，且选自氢原子、氟原子、腈基和烷基，n 为 2 或更大的整数，Q 为式（q）表示的结构： 其中 A 独立地为二价原子或有机基团或直接键，R4 至 R11 可以相同或不同，且选自氢原子、氟原子、烷基和芳基。
• AROMATIC COMPOUND AND SULFONATED POLYARYLENE POLYMER
  申请人：JSR Corporation

  公开号：EP2011814A1

  公开（公告）日：2009-01-07

  Sulfonated polymers have excellent processability and methanol resistance. An aromatic compound is represented by Formula (1) below: wherein A, D and E are each at least one structure selected from the group consisting of a direct bond, -O-, -S-, -CO-, -SO2-, -SO-, -CONH-, -COO-, -(CF2)f- (wherein f is an integer of 1 to 10), -(CH2)h- (wherein h is an integer of 1 to 10), -CR'2- (wherein R' is an aliphatic hydrocarbon group, an aromatic hydrocarbon group or a halogenated hydrocarbon group), a cyclohexylidene group and a fluorenylidene group; each B is independently an oxygen atom or a sulfur atom; X is an atom or a group selected from halogen atoms other than fluorine, -OSO2CH3 and -OSO2CF3; R1 to R28 are the same or different from one another and are each at least one atom or group selected from the group consisting of a hydrogen atom, a fluorine atom, alkyl groups, partially or completely halogenated alkyl groups, allyl groups, aryl groups, nitro group and nitrile group; l and o are each an integer of 0 to 4; m is an integer of 1 to 4; q is an integer of 2 or greater; n and p indicate a composition ratio of the respective units and are each a number ranging from 0 to 1; n + p = 1; and n is not 0.

  磺化聚合物具有优异的加工性和耐甲醇性。 芳香族化合物如下式（1）所示： -(CH2)h-（其中 h 为 1-10 的整数）、-CR'2-（其中 R'为脂肪族烃基、芳香族烃基或卤代烃基）、亚环己基和亚芴基；每个 B 独立地是一个氧原子或一个硫原子； X 是一个原子或一个基团，选自除氟以外的卤素原子、-OSO2CH3 和 -OSO2CF3；R1 至 R28 彼此相同或不同，且各自至少是一个原子或基团，选自由氢原子、氟原子、烷基、部分或完全卤化的烷基、烯丙基、芳基、硝基和腈基组成的组；l 和 o 分别为 0 至 4 的整数；m 为 1 至 4 的整数；q 为 2 或更大的整数；n 和 p 表示各单元的组成比例，分别为 0 至 1 的数字；n + p = 1；n 不为 0。
• Polyarylene block copolymer having sulfonic acid group and use thereof
  申请人：JSR Corporation

  公开号：EP2424018A1

  公开（公告）日：2012-02-29

  A polyarylene copolymer having a sulfonic acid group which has high proton conductivity and reduced swelling in hot water and reduced shrinkage in drying; a solid polymer electrolyte and a proton conductive membrane comprising the copolymer; and a membrane-electrode assembly using these. The polyarylene block copolymer comprises a polymer segment (A) having a sulfonic acid group, and a polymer segment (B) having substantially no sulfonic acid group, the polymer segment (B) having substantially no sulfonic acid group comprising a structural unit represented by the following formula (1).

  一种具有磺酸基团的聚芳基醚共聚物，它具有高质子传导性，在热水中溶胀减小，在干燥中收缩减小；一种固体聚合物电解质和一种质子传导膜，由该共聚物组成；以及一种使用这些共聚物的膜电极组件。 聚芳基嵌段共聚物包括具有磺酸基的聚合物段（A）和基本上没有磺酸基的聚合物段（B），基本上没有磺酸基的聚合物段（B）由下式（1）表示的结构单元组成。