2-(1-乙烯亚氨基)-甲基丙烯酸乙酯 | 6498-81-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-(1-乙烯亚氨基)-甲基丙烯酸乙酯
• 英文名称: 2-(1-Aziridinyl)ethyl methacrylate
• 英文别名: 2-(aziridin-1-yl)ethyl 2-methylprop-2-enoate
• CAS: 6498-81-3
• 化学式: C₈H₁₃NO₂
• mdl: MFCD00080406
• 分子量: 155.19
• InChiKey: XEZCCHVCBAZAQD-UHFFFAOYSA-N

物化性质

• 沸点：
  44-50 °C(Press: 0.1 Torr)
• 密度：
  1.014 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.625
• 拓扑面积：
  29.3
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• Process for preparing vinyl substituted beta-diketones
  申请人：Southard E. Glen

  公开号：US20060069288A1

  公开（公告）日：2006-03-30

  A process for preparing vinyl substituted beta-diketones includes reacting a halogen-containing beta-diketone with an olefin in a reaction zone under Heck coupling reaction conditions in the presence of a catalyst, a base, and an organic phosphine to provide a vinyl substituted beta-diketone product.

  制备乙烯基取代的β-二酮的方法包括在反应区域中，在存在催化剂、碱和有机膦的条件下，将含卤素的β-二酮与烯烃进行 Heck 偶联反应，从而得到乙烯基取代的β-二酮产物。
• Functionalized Photoreactive Compounds
  申请人：Cherkaoui Mohammed Zoubair

  公开号：US20080274304A1

  公开（公告）日：2008-11-06

  The present invention concerns functionalized photoreactive compounds of formula (I), that are particularly useful in materials for the alignment of liquid crystals. Due to the adjunction of an electron withdrawing group to specific molecular systems bearing an unsaturation directly attached to two unsaturated ring systems, exceptionally high photosensitivities, excellent alignment properties as well as good mechanical robustness could be achieved in materials comprising said functionalized photoreactive compounds of the invention.

  本发明涉及式(I)的官能化光反应化合物，特别适用于液晶对准材料。由于在特定分子系统中的不饱和键直接连接到两个不饱和环系统上附加了一个电子受体基团，因此在包含本发明的这些官能化光反应化合物的材料中可以实现异常高的光敏性、优异的对准性能以及良好的机械稳健性。
• Emulsion-type pressure sensitive adhesive and process for producing the same
  申请人：Takashima Kiyokuni

  公开号：US20060194912A1

  公开（公告）日：2006-08-31

  A process for producing an emulsion pressure-sensitive adhesive comprises (co)polymerizing a main monomer in the presence of a protective colloid, the protective colloid being an acrylic copolymer comprising (A-1) at least one hydrophilic monomer selected from the group consisting of acrylamide, methacrylamide, hydroxyethyl acrylate and hydroxyethyl methacrylate and (B-1) an alkyl (meth)acrylate that is copolymerizable with the hydrophilic monomer (A-1) and whose alkyl group has 4 to 18 carbon atoms, or (A-2) a hydrophilic monomer being acrylic acid and/or methacrylic acid and (B-2) an alkyl (meth)acrylate that is copolymerizable with the hydrophilic monomer (A-2) and whose alkyl group has 4 to 9 carbon atoms; the hydrophilic monomer and the alkyl (meth)acrylate being copolymerized in a weight ratio in the range of 40-70:60-30; the acrylic copolymer having a weight-average molecular weight in the range of 500 to 50000. The acrylic copolymer for forming the protective colloid may be copolymerized with a third monomer (C) being acrylonitrile and/or styrene according to need. An emulsion pressure-sensitive adhesive obtained as above exhibits particularly high adhesive property to wetting surfaces.

  生产乳液压敏胶粘剂的工艺包括在保护胶体的存在下共聚合主要单体，所述保护胶体是丙烯酸共聚物，包括（A-1）至少一种亲水单体，所述亲水单体选自丙烯酰胺、甲基丙烯酰胺、羟乙基丙烯酸酯和羟乙基甲基丙烯酸酯，以及（B-1）一种与亲水单体（A-1）共聚合且其烷基含有4至18个碳原子的烷基（甲基）丙烯酸酯，或（A-2）一种亲水单体为丙烯酸和/或甲基丙烯酸，以及（B-2）一种与亲水单体（A-2）共聚合且其烷基含有4至9个碳原子的烷基（甲基）丙烯酸酯；亲水单体和烷基（甲基）丙烯酸酯的重量比在40-70:60-30的范围内共聚合；丙烯酸共聚物的重均分子量在500至50000的范围内。用于形成保护胶体的丙烯酸共聚物可以根据需要与丙烯腈和/或苯乙烯等第三单体（C）共聚合。上述方法获得的乳液压敏胶粘剂对潮湿表面具有特别高的粘附性能。
• [EN] CYANOSTILBENES<br/>[FR] CYANOSTILBÈNES
  申请人：ROLIC AG

  公开号：WO2014191292A1

  公开（公告）日：2014-12-04

  The present invention relates to novel compounds that are particularly useful for the alignment, especially photoalignment, of slave material, especially liquid crystals for optical or electro-optical applications, such as security applications, liquid crystal devices or optical or electro-optical films.

  本发明涉及一种新型化合物，特别适用于用于光学或电光应用的从材料，尤其是液晶的定向，特别是光定向，如安全应用、液晶器件或光学或电光薄膜。
• [EN] MOLECULARLY IMPRINTED POLYMERS FOR EXTRACTION OF CANNABINOIDS AND USES THEREOF<br/>[FR] POLYMÈRES À EMPREINTE MOLÉCULAIRE POUR L'EXTRACTION DE CANNABINOÏDES ET UTILISATIONS ASSOCIÉES
  申请人：6TH WAVE INNOVATIONS CORP

  公开号：WO2020186077A1

  公开（公告）日：2020-09-17

  The present disclosure relates to molecularly imprinted polymers that target cannabinoid(s), including THC and CBD, as well as methods of making molecularly imprinted polymers that target cannabinoid(s), including THC and CBD and uses thereof.

  本公开涉及分子印迹聚合物，其针对大麻素（包括THC和CBD）的靶向性，以及制备分子印迹聚合物的方法，针对大麻素（包括THC和CBD）及其用途。