2-(2,4-二-1,1-二甲基丙基苯氧基乙酰氨基)-4,6-二氯-5-甲基苯酚 | 20364-09-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-(2,4-二-1,1-二甲基丙基苯氧基乙酰氨基)-4,6-二氯-5-甲基苯酚
• 中文别名: N-(3,5-二氯-2-羟基-4-甲基苯基)-2-(2,4-二叔戊基苯氧基)乙酰胺
• 英文名称: (2,4-di-tert-pentyl-phenoxy)-acetic acid-(3,5-dichloro-2-hydroxy-4-methyl-anilide)
• 英文别名: (2,4-Di-tert-pentyl-phenoxy)-essigsaeure-(3,5-dichlor-2-hydroxy-4-methyl-anilid)；2-(2,4-bis(1,1-dimethylpropyl)phenoxy)-N-(3,5-dichloro-2-hydroxy-4-methylphenyl)acetamide；Acetamide, 2-[2,4-bis(1,1-dimethylpropyl)phenoxy]-N-(3,5-dichloro-2-hydroxy-4-methylphenyl)-；2-[2,4-bis(2-methylbutan-2-yl)phenoxy]-N-(3,5-dichloro-2-hydroxy-4-methylphenyl)acetamide
• CAS: 20364-09-4
• 化学式: C₂₅H₃₃Cl₂NO₃
• 分子量: 466.448
• InChiKey: RGIVHZWXUHEZIP-UHFFFAOYSA-N

物化性质

• 熔点：
  160-162 °C(lit.)
• 稳定性/保质期：
  按规定使用和贮存的物质不会分解，避免与氧化物接触。

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  31
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  58.6
• 氢给体数：
  2
• 氢受体数：
  3

安全信息

• 危险品标志：
  Xi
• 海关编码：
  2924299090

文献信息

• Process for forming direct positive images, direct positive silver halide elements, compositions and compounds as characteristic feature of such processes and elements
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0168730A2

  公开（公告）日：1986-01-22

  Direct positive photographic elements are disclosed employing internal latent image silver halide emulsions associated with developer autoxidation promoter agents constituted by 5 or 6 membered nucleus-containing heterocyclic compounds comprising an azomethine group, whose methine group is substituted with a 5-amino-1,2,4-triazolyl group, and/or copper complex compounds thereof. Preferably said direct positive photographic elements are multilayer elements comprising internal latent image type type silver halide emulsion layers sensitized to different regions of the visible light and associated with image-dye providing compounds (photographic color couplers).

  本发明公开了直接正像照相元件，该元件采用了与显影剂自氧化促进剂有关的内潜像型卤化银乳剂，该促进剂由包含偶氮甲基的 5 或 6 个含核杂环化合物构成，其甲基被 5-氨基-1,2,4-三唑基取代，和/或其铜络合物。 上述直接正像感光元件最好是多层元件，包括对可见光的不同区域感光的内部潜像型卤化银乳剂层，并与提供图像染料的化合物（感光颜色耦合剂）相关联。
• Silver halide photographic light sensitive material
  申请人：KONICA CORPORATION

  公开号：EP0342939A1

  公开（公告）日：1989-11-23

  Asilver halide photographic light-sensitive material which contains a dye represented by the following formula I. The dye has excellent properties as antiirradiation or antihalation dye. wherein R₁, R₂, R₃, R₄, R₅ and R₆ each represents an alkyl group; Z₁ and Z₂ each represents a group of non-metal atoms necessary to form a condensed benzene ring or a condensed naphthalene ring, provided that at least three of those groups represented by R₁, R₂, R₃, R₄, R₅, R₆, Z₁, and Z₂ are acid groups or groups substituted by an acid group; L represents a methine group; X⊖ represents an anion; m is an integer of 1, 2, or 3; and n is an integer of 1 or 2, provided that the n is 1 when the dye forms an intramolecular salt.

  卤化银感光材料，它含有一种由下式 I 表示的染料。该染料作为抗辐照或抗光晕染料具有优异的性能。 其中 R₁、R₂、R₃、R₄、R₅ 和 R₆ 各代表一个烷基；Z₁ 和 Z₂ 各自代表形成缩合苯环或缩合萘环所需的非金属原子团，但 R₁、R₂、R₃、R₄、R₅、R₆、Z₁ 和 Z₂ 所代表的基团中至少有三个是酸基或被酸基取代的基团；L 代表甲基；X⊖ 代表阴离子；m 是 1、2 或 3 的整数；n 是 1 或 2 的整数，但当染料形成分子内盐时，n 为 1。
• Process for producing aromatic amide compounds useful as cyan coupler for color photographes
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0608896A1

  公开（公告）日：1994-08-03

  There is disclosed a process for producing an aromatic amide compound of the general formula (4), including the steps of subjecting an o-nitrophenol compound of the general formula (1) to catalytic reduction in acetone or an aromatic hydrocarbon solvent under the presence of a nickel catalyst to give an o-aminophenol compound of the general formula (2); and (b) subjecting the o-aminophenol compound of the general formula (2) to condensation with an acid chloride compound having a sulfur content of 0.5% or less, based on the weight of the acid chloride compound, of the general formula (3) in acetone or an aromatic hydrocarbon solvent under an atmosphere of an inert gas having an oxygen concentration of 1% or less. The acid chloride compound having a sulfur content of 0.5% or less, based on the weight of the acid chloride compound, of the general formula (3) may be obtained by allowing a carboxylic acid compound of the general formula (5) to react with thionyl chloride and by concentrating the reaction mixture. Also disclosed is another process for producing an aromatic amide compound of the general formula (4), including the step of subjecting an o-aminophenol hydrochloride salt of the general formula (6) to condensation with an acid chloride compound having a sulfur content of 0.8% or less, based on the weight of the acid chloride compound, of the general formula (3) in an inert solvent.

  本发明公开了一种生产通式(4)的芳香族酰胺化合物的工艺，包括以下步骤：(a) 在镍催化剂存在下，将通式(1)的邻硝基苯酚化合物在丙酮或芳香烃溶剂中进行催化还原，得到通式(2)的邻氨基苯酚化合物；(b) 将通式(2)的邻氨基苯酚化合物与硫含量为 0.5%或更低的通式(3)的酸性氯化物在丙酮或芳香烃溶剂中，在氧浓度为 1%或更低的惰性气体气氛下进行缩合。硫含量为 0.5%或更低的通式（3）的酸性氯化物可以通过让通式（5）的羧酸化合物与亚硫酰氯反应并浓缩反应混合物来获得。还公开了另一种生产通式(4)芳香族酰胺化合物的工艺，包括在惰性溶剂中使通式(6)的邻氨基苯酚盐酸盐与硫含量为 0.8%或以下（以氯化酸化合物重量为基准）的通式(3)氯化酸化合物缩合的步骤。
• Silver halide color photographic light-sensitive material
  申请人：KONICA CORPORATION

  公开号：EP0137273B1

  公开（公告）日：1988-10-19
• Process for producing aromatic amide compounds useful as cyan coupler for color photographs
  申请人：SUMITOMO CHEMICAL COMPANY LIMITED

  公开号：EP0608896B2

  公开（公告）日：2000-11-02