2-(2-甲基-2-丙烯-1-基)联苯 | 860770-58-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-(2-甲基-2-丙烯-1-基)联苯
• 英文名称: 2-(2-methylallyl)biphenyl
• 英文别名: 2-Methallyl-biphenyl；3-(2-Biphenyl)-2-methyl-1-propene；1-(2-methylprop-2-enyl)-2-phenylbenzene
• CAS: 860770-58-7
• 化学式: C₁₆H₁₆
• 分子量: 208.303
• InChiKey: RJYAJPAFNXFGNM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-联苯基碘化镁 、 3-氯-2-甲基丙烯 在 乙醚 作用下， 生成 2-(2-甲基-2-丙烯-1-基)联苯
  参考文献：
  名称：

  Goodman; Wise, Tech. Note Nr. 2260 <1951> 12

  摘要：

  DOI：

文献信息

• Highly Efficient Route to <i>o</i>-Allylbiaryls via Palladium-Catalyzed Three-Component Coupling of Benzynes, Allylic Halides, and Aryl Organometallic Reagents
  作者：Thiruvellore Thatai Jayanth、Masilamani Jeganmohan、Chien-Hong Cheng

  DOI：10.1021/ol050859r

  日期：2005.7.1

  [reaction: see text] o-Allylbiaryl derivatives have been prepared in good to excellent yields by the palladium-catalyzed three-component reaction of allyl halides, benzynes, and aryl organometallic reagents.

  [反应：见正文]通过钯催化的烯丙基卤化物，苯并炔和芳基有机金属试剂的三组分反应，可以很好地制备o-烯丙基联芳基衍生物。
• A N-heterocyclic tetracarbene Pd(<scp>ii</scp>) moiety containing a Pd(<scp>ii</scp>)–Pb(<scp>ii</scp>) bimetallic MOF for three-component cyclotrimerization via benzyne
  作者：Ying Dong、Yue Li、Yong-Liang Wei、Jian-Cheng Wang、Jian-Ping Ma、Jun Ji、Bing-Jian Yao、Yu-Bin Dong

  DOI：10.1039/c6cc04570g

  日期：——

  A N-heterocyclic tetracarbene Pd(ii) moiety containing a bimetallic metal–organic framework Pd(ii)–Pb(ii)–MOF, which can be a highly active heterogeneous catalyst for three-component cyclotrimerization, is reported.

  一种含有双金属金属-有机框架Pd（II）-Pb（II）-MOF的N-杂环四酮咯Pd（II）基团，可作为高活性的三组分环三聚反应的杂化催化剂。
• Microwave-assisted palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation
  作者：Masayuki Iwasaki、Sayuri Hayashi、Koji Hirano、Hideki Yorimitsu、Koichiro Oshima

  DOI：10.1016/j.tet.2007.03.165

  日期：2007.6

  The palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation proceeds at 200-250 degrees C in a toluene-DMF mixed solvent using microwave heating. Even at such high temperatures, the regio- and stereospecificity of the allyl transfer reaction is still satisfactory. The amount of the palladium catalyst can be reduced to 0.5 or 0.05 mol %. (c) 2007 Elsevier Ltd. All rights reserved.