1,3,4-trimethyl-Δ³-phospholene oxide | 15450-80-3

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: 1,3,4-trimethyl-Δ³-phospholene oxide
• 英文别名: 1,3,4-trimethyl-Δ³-phospholen oxide；1,3,4-trimethyl-2,5-dihydro-1H-phosphole 1-oxide；1,3,4-trimethyl-3-phospholene 1-oxide；1,3,4-trimethyl-2,5-dihydro-1H-phosphole 1-oxide；1,3,4-Trimethyl-3-phospholenoxid；1,3,4-Trimethyl-2,5-dihydro-1H-1lambda~5~-phosphol-1-one；1,3,4-trimethyl-2,5-dihydro-1λ5-phosphole 1-oxide
• CAS: 15450-80-3
• 化学式: C₇H₁₃OP
• 分子量: 144.153
• InChiKey: PLIBMPRCDNXLHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.6
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,3,4-trimethyl-Δ³-phospholene oxide 在 苯硅烷 作用下， 反应 1.0h， 以79%的产率得到1,3,4-trimethyl-Δ³-phospholene
  参考文献：
  名称：

  The reaction of 1-substituted 3,4-dimethyl-Δ³-phospholens with diethyl peroxide: a correlation between rate and³¹P nuclear magnetic resonance shift

  摘要：

  DOI：

  10.1039/p29820000205
• 作为产物：
  描述：

  1,3,4-trimethyl-Δ³-phospholene 在 苯次磺酸,乙酯 作用下， 以 甲苯 为溶剂， 生成 1,3,4-trimethyl-Δ³-phospholene oxide
  参考文献：
  名称：

  Hammond, Philip J.; Lloyd, John R.; Hall, C. Dennis, Phosphorus and Sulfur and the Related Elements, 1981, vol. 10, p. 67 - 80

  摘要：

  DOI：

文献信息

• 1,4,2-DIAZAPHOSPHOLIDINE DERIVATIVES
  申请人：Richter Frank

  公开号：US20110207927A1

  公开（公告）日：2011-08-25

  The present invention relates to novel 1,4,2-diazaphospholidine derivatives, to a process for preparation thereof and to use as catalysts.

  本发明涉及新颖的1,4,2-二氮磷杂环丙烷衍生物，以及其制备方法和用作催化剂的用途。
• POLYCYCLIC DIIMINOOXADIAZINONES
  申请人：Covestro Deutschland AG

  公开号：US20180346482A1

  公开（公告）日：2018-12-06

  The invention relates to polycyclic diiminooxadiazinones of the formula I and/or of the formula II, in which in each case R 1 to R 12 are each independently hydrogen, a saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic organic radical having 1 to 20 carbon atoms, which is unsubstituted or is substituted by radicals inert to isocyanate groups, and/or comprises heteroatoms inert to isocyanate groups in the chain, or are an aromatic organic radical having 6 to 20 carbon atoms, which is unsubstituted or is substituted by radicals inert to isocyanate groups, wherein two or more of the aforementioned radicals R 1 to R 6 may form further rings, in each case with one another and incorporating one, two or three carbon atoms of the fused ring segment X, and/or two or more of the aforementioned radicals R 7 to R 12 may form further rings, in each case with one another and incorporating one, two or three carbon atoms of the fused ring segment Y.

  该发明涉及公式I和/或公式II的多环二亚胺氧二氮杂环酮，其中在每种情况下，R1至R12各自独立地表示氢，具有1至20个碳原子的饱和或不饱和的线性或支链脂肪族或环脂族有机基团，其未被取代或被取代为对异氰酸酯基惰性的基团，和/或在链中包含对异氰酸酯基惰性的杂原子，或者是具有6至20个碳原子的芳香族有机基团，其未被取代或被取代为对异氰酸酯基惰性的基团，其中上述R1至R6中的两个或更多基团可以进一步与X融合的环节中的一个、两个或三个碳原子相互形成进一步的环，上述R7至R12中的两个或更多基团可以进一步与Y融合的环节中的一个、两个或三个碳原子相互形成进一步的环。
• 1 4,2-DIAZAPHOSPHOLIDINE DERIVATIVES
  申请人：Bayer MaterialScience AG

  公开号：US20140221650A1

  公开（公告）日：2014-08-07

  The present invention relates to novel 1,4,2-diazaphospholidine derivatives, to a process for preparation thereof and to use as catalysts.

  本发明涉及一种新型的1,4,2-二氮杂磷杂环丙烷衍生物，其制备方法及用作催化剂的用途。
• Polycyclic diiminooxadiazinones
  申请人：Covestro Deutschland AG

  公开号：US10464948B2

  公开（公告）日：2019-11-05

  The invention relates to polycyclic diiminooxadiazinones of the formula I and/or of the formula II, in which in each case R1 to R12 are each independently hydrogen, a saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic organic radical having 1 to 20 carbon atoms, which is unsubstituted or is substituted by radicals inert to isocyanate groups, and/or comprises heteroatoms inert to isocyanate groups in the chain, or are an aromatic organic radical having 6 to 20 carbon atoms, which is unsubstituted or is substituted by radicals inert to isocyanate groups, wherein two or more of the aforementioned radicals R1 to R6 may form further rings, in each case with one another and incorporating one, two or three carbon atoms of the fused ring segment X, and/or two or more of the aforementioned radicals R7 to R12 may form further rings, in each case with one another and incorporating one, two or three carbon atoms of the fused ring segment Y.

  本发明涉及式 I 和/或式 II 的多环二亚氨基恶二嗪酮、 在每种情况下 R1 至 R12 各自独立地为氢、具有 1 至 20 个碳原子的饱和或不饱和、直链或支链、 脂肪族或环脂族有机基，该有机基未被异氰酸酯基取代或被异氰酸酯基惰性基取代， 和/或在链中包含对异氰酸酯基惰性的杂原子，或者为具有 6 至 20 个碳原子的芳香族有 机基，该芳香族有机基未被异氰酸酯基取代或被异氰酸酯基惰性基取代、 其中两个或两个以上的上述基 R1 至 R6 可形成更多的环，在每种情况下相互结合并包含一个、两个或三个碳原子的融合环段 X，和/或两个或两个以上的上述基 R7 至 R12 可形成更多的环，在每种情况下相互结合并包含一个、两个或三个碳原子的融合环段 Y。
• Structure of diene-phosphonous dihalide addition products and of derived phospholenes and phospholene oxides
  作者：Louis D. Quin、Joan P. Gratz、Thomas P. Barket

  DOI：10.1021/jo01267a020

  日期：1968.3