2,2'-dimethyl-3,3',5,5'-tetraphenyl-[1,1'-biphenyl]-4,4'-diol | 137119-08-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2'-dimethyl-3,3',5,5'-tetraphenyl-[1,1'-biphenyl]-4,4'-diol
• 英文别名: 4-(4-hydroxy-2-methyl-3,5-diphenylphenyl)-3-methyl-2,6-diphenylphenol
• CAS: 137119-08-5
• 化学式: C₃₈H₃₀O₂
• 分子量: 518.655
• InChiKey: ATYBRXKOXVLKEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.1
• 重原子数：
  40
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  mono-benzyl ester of 2,7-di-tert-butyl-9,9-dimethyl-4,5-xanthene dicarboxylic acid chloride 、 2,2'-dimethyl-3,3',5,5'-tetraphenyl-[1,1'-biphenyl]-4,4'-diol 生成
  参考文献：
  名称：

  Galan Amalia, Sutherland Andrew J., Ballester Pablo, Rebek Julius, Jr., Tetrahedron Lett, 35 (1994) N 30, S 5359-5362

  摘要：

  DOI：
• 作为产物：
  描述：

  4'-methyl-[1,1':3',1''-terphenyl]-2'-ol 在 氧气 、 copper(l) chloride 作用下， 以 various solvent(s) 为溶剂， 生成 2,2'-dimethyl-3,3',5,5'-tetraphenyl-[1,1'-biphenyl]-4,4'-diol
  参考文献：
  名称：

  Synthesis and rotational properties of a series of polyaromatic clefts

  摘要：

  A series of molecular clefts containing convergent functional groups has been developed. The rotational processes occurring within these molecules have been investigated by dynamic NMR experiments and these results are compared with those obtained from molecular modelling.

  DOI：

  10.1016/s0040-4039(00)73499-x

文献信息

• Polymers and copolymers of high glass transition temperature from
  申请人：——

  公开号：US05182358A1

  公开（公告）日：1993-01-26

  Polymers and copolymers having high glass transition temperature and which are soluble in organic solvents are produced from highly hindered biphenols, in particular polyetherketones, polyethersulfones, polyesters and polyetherimides, as well as copolymers based on these polymers may be produced for a variety of applications.

  具有高玻璃转变温度且可溶于有机溶剂的聚合物和共聚物是由高度阻隔的联苯酚制成的，特别是聚醚酮、聚醚砜、聚酯和聚醚酰亚胺，以及基于这些聚合物的共聚物可以用于各种应用。
• Galan Amalia, Sutherland Andrew J., Ballester Pablo, Rebek Julius, Jr., Tetrahedron Lett, 35 (1994) N 30, S 5359-5362
  作者：Galan Amalia, Sutherland Andrew J., Ballester Pablo, Rebek Julius, Jr.

  DOI：——

  日期：——
• US5182358A
  申请人：——

  公开号：US5182358A

  公开（公告）日：1993-01-26
• US5243016A
  申请人：——

  公开号：US5243016A

  公开（公告）日：1993-09-07
• Synthesis and rotational properties of a series of polyaromatic clefts
  作者：Amalia Galán、Andrew J. Sutherland、Pablo Ballester、Julius Rebek

  DOI：10.1016/s0040-4039(00)73499-x

  日期：1994.7

  A series of molecular clefts containing convergent functional groups has been developed. The rotational processes occurring within these molecules have been investigated by dynamic NMR experiments and these results are compared with those obtained from molecular modelling.