2-(3-甲基噻吩-2-基)-5-噻吩-2-基噻吩 | 113386-75-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 中文名称: 2-(3-甲基噻吩-2-基)-5-噻吩-2-基噻吩
• 英文名称: 3-methyl-2,2':5',2''-terthienyl
• 英文别名: 2-(3-Methylthiophen-2-yl)-5-thiophen-2-ylthiophene
• CAS: 113386-75-7
• 化学式: C₁₃H₁₀S₃
• 分子量: 262.42
• InChiKey: DDHABWAJQPWWIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  84.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2,2'-联二噻吩 在 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) 正丁基锂 、 溴 、 碳酸氢钠 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 、 氯仿 为溶剂， 反应 17.5h， 生成 2-(3-甲基噻吩-2-基)-5-噻吩-2-基噻吩
  参考文献：
  名称：

  Pham, Chiem Van; Burkhardt, A.; Shabana, R., Phosphorus, Sulfur and Silicon and the Related Elements, 1989, vol. 46, p. 153 - 168

  摘要：

  DOI：

文献信息

• Synthesis of oligomeric 2,5-thienylenes; their u.v. spectra and oxidation potentials
  作者：D. D. Cunningham、L. Laguren-Davidson、Harry B. Mark、Chiem Van Pham、Hans Zimmer

  DOI：10.1039/c39870001021

  日期：——

  Oligomeric 2,5-thienylenes and 3-methyl-2,5-thienylenes have been synthesized by NiCl2(dppp)(dppp = Ph2PCH2CH2CH2PPh2) coupling of Grignard compounds with the appropriate bromothiophene; u.v. spectra and oxidation potentials of the oligomers are dicussed in terms of coplanarity of the oligomeric species.

  通过格氏试剂与合适的溴噻吩的NiCl 2（dppp）（dppp = Ph 2 PCH 2 CH 2 CH 2 CH 2 PPh 2）偶联，合成了低聚的2,5-噻吩基和3-甲基-2,5-噻吩基；根据低聚物种类的共面性，讨论了低聚物的紫外光谱和氧化电位。
• Process of manufacturing an electrically conductive material and a secondary battery using the electrically conductive material
  申请人：SANYO ELECTRIC CO., LTD.

  公开号：EP0219063A2

  公开（公告）日：1987-04-22

  An electrically conductive material containing no substantial amount of water and prepared by polymerizing, in the presence of an oxidizing agent, a compound having conjugated double bonds on a base material in a gas phase. The base material has spaces capable of retaining the oxidizing agent. The elecrically conductive material is used for at least one electrode of a secondary battery.

  一种不含大量水分的导电材料，其制备方法是在有氧化剂存在的情况下，在气相中聚合基材上具有共轭双键的化合物。基体材料具有能够保留氧化剂的空间。这种导电材料可用于二次电池的至少一个电极。
• Electrically conductive material and a process for the preparation of same and secondary battery using the electrically conductive material
  申请人：SANYO ELECTRIC CO., LTD.

  公开号：EP0261837A2

  公开（公告）日：1988-03-30

  New electrically conductive material suitable particularly for a secondary battery and a process for preparing the electrically conductive material are provided. The process for the preparation of the electrically conductive material comprises the steps of reacting a compound having conjugated double bonds with an oxidizing agent wherein the oxidizing agent comprises a cupric compound and a nitrile compound. The electrically conductive material comprises grainy polypyrrole obtained by reacting a pyrrole compound with an oxidizing agent which is constituted by primary particles having an average particle size of 0.01 to 0.4 µm and has a press molding density of 1 to 1.6 g/cm³.

  本发明提供了特别适用于二次电池的新型导电材料以及制备该导电材料的工艺。 制备该导电材料的工艺包括以下步骤：使具有共轭双键的化合物与氧化剂反应，其中氧化剂包括铜化合物和腈化合物。 该导电材料包括通过使吡咯化合物与氧化剂反应而获得的粒状聚吡咯，该聚吡咯由平均粒径为 0.01 至 0.4 微米的初级颗粒构成，其压制成型密度为 1 至 1.6 克/立方厘米。
• Dispersion of electrically conductive particles in a dispersing medium
  申请人：DSM N.V.

  公开号：EP0589529A1

  公开（公告）日：1994-03-30

  The invention relates to a dispersion of electrically conductive particles, comprising a binder and an electrically conductive polymer, and a stabiliser in a dispersing medium. The dispersion according to the invention is characterised in that the particles contain a non-ionic stabiliser. It has been found that the stability of the dispersion according to the invention is very good. In addition the dispersion according to the invention is extremely suitable for providing objects with a coating in a simple manner. The applied coating has good electrically conductive properties as well as good coating properties. The applied coating is homogeneously distributed over the coated object. Moreover the applied coating appears to adhere well to the object.

  本发明涉及一种导电微粒的分散体，包括分散介质中的粘合剂、导电聚合物和稳定剂。根据本发明的分散体的特点是颗粒中含有非离子稳定剂。研究发现，本发明的分散液稳定性非常好。此外，本发明的分散体非常适合以简单的方式为物体提供涂层。涂覆的涂层具有良好的导电性能和涂覆性能。涂层均匀地分布在被涂物体上。此外，涂覆的涂层看起来与物体附着良好。
• Aqueous coating dispersion, process for the preparation thereof and use thereof in anticorrosive paint
  申请人：DSM N.V.

  公开号：EP0821040A1

  公开（公告）日：1998-01-28

  The invention relates to an aqueous coating dispersion comprising at least electrically conductive particles, which particles comprise at least a first binder, a conductive polymer and a non-ionic stabiliser, characterised in that the coating dispersion contains 50 to 99 wt. %, relative to the total amount of solids present, of a second binder, which second binder consists of electrically non-conductive particles. The invention also relates to a process for the preparation of the aqueous coating dispersion and to the use thereof in an anticorrosive paint, to the anticorrosive paint based on the aqueous coating dispersion according to the invention and to the metals protected herewith.

  本发明涉及一种水性涂料分散体，该分散体至少包含导电颗粒，该导电颗粒至少包含第一粘合剂、导电聚合物和非离子稳定剂，其特征在于该涂料分散体包含相对于固体总量为50-99重量％的第二粘合剂，该第二粘合剂由不导电颗粒组成。本发明还涉及水性涂料分散体的制备工艺及其在防腐涂料中的应用，以及基于本发明水性涂料分散体的防腐涂料和受其保护的金属。