Mono-perphthalsaeure-tert.-butylester | 15042-77-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Mono-perphthalsaeure-tert.-butylester
• 英文别名: tert-Butyl monoperphthalate；2-tert-butylperoxycarbonylbenzoic acid
• CAS: 15042-77-0
• 化学式: C₁₂H₁₄O₅
• 分子量: 238.24
• InChiKey: UQSXEMVUGMPGLS-UHFFFAOYSA-N

物化性质

• 熔点：
  57-57.5 °C
• 沸点：
  398.9±25.0 °C(Predicted)
• 密度：
  1.216±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  72.8
• 氢给体数：
  1
• 氢受体数：
  5

安全信息

• 危险等级：
  5.2

反应信息

• 作为反应物：
  描述：

  Mono-perphthalsaeure-tert.-butylester 、 三丁基氧化锡 以 乙醚 为溶剂， 以88%的产率得到(C4H9)3SnOOCC6H4COOOC4H9-t-2
  参考文献：
  名称：

  碳XIII以外的元素的过氧化物。一些三烷基锡（IV）和二烷基锡（IV）过氧化物的制备

  摘要：

  通过将三烷基锡氧化物或氢氧化物和氢过氧化物烷基的混合物进行共沸脱水，可获得高收率的烷基三烷基锡过氧化物R 3 Sn = O = OR'。与二烷基氧化相应的反应产生的diperoxydistannoxanes，R'OOSnR 2 OSnR 2 OOR'。讨论了这些化合物和相关化合物的结构。

  DOI：

  10.1016/s0022-328x(00)82763-1
• 作为产物：
  描述：

  叔丁基过氧化氢 、 苯酐 在 吡啶 作用下， 生成 Mono-perphthalsaeure-tert.-butylester
  参考文献：
  名称：

  Davies et al., Journal of the Chemical Society, 1953, p. 1541,1545

  摘要：

  DOI：

文献信息

• PHENOLIC HYDROXYL GROUP-CONTANING COMPOUND, PHENOLIC HYDROXYL GROUP-CONTANING COMPOSITION, (METH)ACRYLOYL GROUP-CONTAINING RESIN, CURABLE COMPOSITION, CURED PRODUCT THEREOF, AND RESIST MATERIAL
  申请人：DIC CORPORATION

  公开号：US20150274636A1

  公开（公告）日：2015-10-01

  The present invention provides a (meth)acryloyl group-containing resin having excellent heat resistance and a phenolic hydroxyl group-containing compound used as a raw material of the resin. A phenolic hydroxyl group-containing compound has a molecular structure represented by general formula (1) below [in the formula, R 1 , R 2 , and R 3 are each independently an alkyl group having 1 to 8 carbon atoms, m and n are each independently an integer of 1 to 4, p is an integer of 0 to 4, V is a hydrogen atom, a (meth)acryloyloxy group, or a hydroxyl group, and W, X, and Y are each independently a (meth)acryloyloxy group or a hydroxyl group], wherein at least one of V, W, X, and Y is a hydroxyl group, and at least one of V, W, X, and Y is a (meth)acryloyloxy group.

  本发明提供了一种具有优异耐热性的含有(meth)丙烯酰基的树脂，以及一种作为该树脂原料的含酚羟基化合物。含酚羟基的化合物具有以下通式(1)所表示的分子结构[在该式中，R1、R2和R3分别独立地为具有1至8个碳原子的烷基基团，m和n分别独立地为1至4的整数，p为0至4的整数，V为氢原子、(meth)丙烯酰氧基或羟基，W、X和Y分别独立地为(meth)丙烯酰氧基或羟基]，其中V、W、X和Y中至少有一个为羟基，至少有一个为(meth)丙烯酰氧基。
• COMPOUNDS CARRYING NITROGEN-CONTAINING BINDING GROUPS
  申请人：Arkema France

  公开号：US20190315695A1

  公开（公告）日：2019-10-17

  The invention relates to a compound of formula (I), wherein: A1 and A 2 represent, independently of one another, a binding group comprising at least one nitrogen atom; Q 1 and Q 2 represent, independently of one another, a linkage group; and x is an integer between 2 and 6, preferably between 3 and 6. The invention also relates to a rubber composition comprising said compound.

  该发明涉及一种式子为（I）的化合物，其中：A1和A2分别代表至少含有一个氮原子的结合基团；Q1和Q2分别代表连接基团；x为2到6之间的整数，最好为3到6之间的整数。该发明还涉及一种包含该化合物的橡胶组合物。
• Diacyl peroxy compounds
  申请人：Pennwalt Corporation

  公开号：US03991109A1

  公开（公告）日：1976-11-09

  I. A novel class of compounds X.sub.n --R.sub.p --Y.sub.m where R is a 2-4 valence aliphatic, cycloaliphatic or aromatic radical, X is an acylating function; Y is a peroxy containing group and n and m are each equal to 1-2 and p is at least 1. Ii. a novel class of polymers [A.sub.n -(R-D.sub.n).sub.n ].sub.v -P.sub.w -Z where A is a peroxy containing group; R is a 2-4 valence aliphatic, cycloaliphatic or aromatic radical, P is a polyvalent polymeric residue; D is a carbonyl containing connecting group; Z is H, OH, NH.sub.2, NHR.sub.2, SH or R.sub.2 O group; v and w are each equal to 1-100; and n is equal to 1-2. Iii. polymers II are useful with vinyl monomers in the formation of block and graft polymers. Iv. peroxides having an acylating function are prepared by reacting at 0.degree.-80.degree. C an organic peroxide having an hydroxyl or carboxyl group with a defined acylating reactant. V. peroxides having at least one acylating function are prepared by peroxidizing a compound having at least two acylating functions as the only peroxidizable substituents.

  I. 一种新型化合物X.sub.n --R.sub.p --Y.sub.m，其中R为2-4价的脂肪族、环状脂肪族或芳香族基团，X为酰化功能；Y为过氧化物含有基团，n和m分别等于1-2，p至少为1。 II. 一种新型聚合物[A.sub.n -(R-D.sub.n).sub.n ].sub.v -P.sub.w -Z，其中A为过氧化物含有基团；R为2-4价的脂肪族、环状脂肪族或芳香族基团，P为多价聚合物残基；D为含有羰基的连接基团；Z为H、OH、NH.sub.2、NHR.sub.2、SH或R.sub.2 O基团；v和w分别等于1-100；n等于1-2。 III. 聚合物II与乙烯单体一起使用可形成块状和嫁接聚合物。 IV. 具有酰化功能的过氧化物通过将具有羟基或羧基的有机过氧化物与定义的酰化反应物在0℃-80℃反应制备。 V. 具有至少一个酰化功能的过氧化物是通过过氧化至少具有两个酰化功能作为唯一可过氧化取代基团的化合物制备的。
• Resin-reinforced elastomer, process for producing same and pneumatic tire using same
  申请人：Bridgestone Corporation

  公开号：EP0867471A1

  公开（公告）日：1998-09-30

  There are disclosed a resin-reinforced elastomer which comprises as principal components, a rubber and a polyolefin having an average particle diameter of at most 1 µm, and in which the rubber and the polyolefin are linked together; a process for producing the resin-reinforced elastomer by melt kneading a polyolefin, a No.1 rubber and a binding agent to prepare a thermoplastic composition, adding a No.2 rubber to the resultant thermoplastic composition and melt kneading the mixture thus formed to disperse the polyolefin in the rubber components; and a pneumatic tire using the resin-reinforced elastomer in its tread. The above resin -reinforced elastomer has a uniform modulus and a low density, is minimized in directionality, and is excellent in tensile strength, fatigue resistance and abrasion resistance.

  公开了一种树脂增强弹性体，其主要成分包括橡胶和平均颗粒直径不超过 1 微米的聚烯烃，其中橡胶和聚烯烃连接在一起；一种生产树脂增强弹性体的工艺，通过熔融捏合聚烯烃、1 号将聚烯烃、1 号橡胶和粘合剂熔融捏合以制备热塑性组合物，将 2 号橡胶添加到生成的热塑性组合物中，然后熔融捏合由此形成的混合物，使聚烯烃分散在橡胶成分中；以及在轮胎胎面中使用树脂增强弹性体的充气轮胎。上述树脂增强弹性体具有均匀的模量和较低的密度，方向性最小，拉伸强度、抗疲劳性和耐磨性极佳。
• Poly(arylene ether) adhesive compositions
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP1167484A2

  公开（公告）日：2002-01-02

  An adhesive for thermoplastic film is formed from a composition comprising a blend of a poly(arylene ether), a thermosetting resin, a toughening agent, an optional plasticizer, and a cure agent. The adhesive finds particular utility in circuit board applications.

  一种用于热塑性薄膜的粘合剂是由聚芳基醚、热固性树脂、增韧剂、可选增塑剂和固化剂的混合物组成。这种粘合剂在电路板应用中特别有用。