methyl-butyl-amine hydroiodide | 1122406-63-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: methyl-butyl-amine hydroiodide
• 英文别名: N-methylbutylamine hydriodide；N-butylmethylammonium iodide；Methylbutylammonium iodide；butyl(methyl)azanium;iodide
• CAS: 1122406-63-6
• 化学式: C₅H₁₃N*HI
• 分子量: 215.077
• InChiKey: DQZRNCYNPUUEMR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.02
• 重原子数：
  7
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  16.6
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  methyl-butyl-amine hydroiodide 、 氯化异氰盐酸盐 在 吡啶 作用下， 反应 3.0h， 以17.6 mg的产率得到N-butyl-N-methylisonicotinamide
  参考文献：
  名称：

  Yebeutchou, Roger M.; Dalcanale, Enrico, Journal of the American Chemical Society, 2009, vol. 131, p. 2452 - 2453

  摘要：

  DOI：
• 作为产物：
  描述：

  甲基丁胺 在 氢碘酸 作用下， 以 乙醚 、 水 为溶剂， 反应 0.33h， 以95%的产率得到methyl-butyl-amine hydroiodide
  参考文献：
  名称：

  Molecular Recognition on a Cavitand-Functionalized Silicon Surface

  摘要：

  A Si(100) surface featuring molecular recognition properties was obtained by covalent functionalization with a tetraphosphonate cavitand (Tiiii), able to complex positively charged species. Tiiii cavitand was grafted onto the Si by photochemical hydrosilylation together with 1-octene as a spatial spectator. The recognition properties of the Si-Tiii surface were demonstrated through two independent analytical techniques, namely XPS and fluorescence spectroscopy, during the course of reversible complexationguest exchange-clecomplexation cycles with specifically designed ammonium and pyridinium salts. Control experiments employing a Si(100) surface functionalized with a structurally similar, but complexation inactive, tetrathiophosphonate cavitand (TSiiii) demonstrated no recognition events. This provides evidence for the complexation properties of the Si-Tiiii surface, ruling out the possibility of nonspecific interactions between the substrate and the guests. The residual Si-O- terminations on the surface replace the guests' original counterions, thus stabilizing the complex ion pairs. These results represent a further step toward the control of self-assembly of complex supramolecular architectures on surfaces.

  DOI：

  10.1021/ja901678b

文献信息

• Molecular Recognition on a Cavitand-Functionalized Silicon Surface
  作者：Elisa Biavardi、Maria Favazza、Alessandro Motta、Ignazio L. Fragalà、Chiara Massera、Luca Prodi、Marco Montalti、Monica Melegari、Guglielmo G. Condorelli、Enrico Dalcanale

  DOI：10.1021/ja901678b

  日期：2009.6.3

  A Si(100) surface featuring molecular recognition properties was obtained by covalent functionalization with a tetraphosphonate cavitand (Tiiii), able to complex positively charged species. Tiiii cavitand was grafted onto the Si by photochemical hydrosilylation together with 1-octene as a spatial spectator. The recognition properties of the Si-Tiii surface were demonstrated through two independent analytical techniques, namely XPS and fluorescence spectroscopy, during the course of reversible complexationguest exchange-clecomplexation cycles with specifically designed ammonium and pyridinium salts. Control experiments employing a Si(100) surface functionalized with a structurally similar, but complexation inactive, tetrathiophosphonate cavitand (TSiiii) demonstrated no recognition events. This provides evidence for the complexation properties of the Si-Tiiii surface, ruling out the possibility of nonspecific interactions between the substrate and the guests. The residual Si-O- terminations on the surface replace the guests' original counterions, thus stabilizing the complex ion pairs. These results represent a further step toward the control of self-assembly of complex supramolecular architectures on surfaces.
• Yebeutchou, Roger M.; Dalcanale, Enrico, Journal of the American Chemical Society, 2009, vol. 131, p. 2452 - 2453
  作者：Yebeutchou, Roger M.、Dalcanale, Enrico

  DOI：——

  日期：——