1-anilino-1,2-dicyanoethylene | 93692-43-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-anilino-1,2-dicyanoethylene
• 英文别名: (E)-2-anilinobut-2-enedinitrile
• CAS: 93692-43-4
• 化学式: C₁₀H₇N₃
• 分子量: 169.186
• InChiKey: RCRLUNZUUCWHDQ-UXBLZVDNSA-N

物化性质

• 沸点：
  317.6±42.0 °C(Predicted)
• 密度：
  1.220±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  59.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3,3,3-三甲氧基丙腈 在 对甲苯磺酸一水合物 、 苯胺 作用下， 以54.6%的产率得到1-anilino-1,2-dicyanoethylene
  参考文献：
  名称：

  Imine dye and photographic elements containing same

  摘要：

  在摄影材料中有用的亚胺染料具有以下公式：##STR1## 其中 R.sup.1, E.sup.1, E.sup.2, L.sup.1, L.sup.2, L.sup.3, D 和 m 的定义如规范中所述。含有至少一种碱可离子化功能基团（如羧基、磺酰胺基或磺酰胺基）的公式（I）染料的固体颗粒分散体在摄影元素中作为滤光染料是有用的。

  公开号：

  US05466813A1

文献信息

• Mixture of dyes for magenta dye donor for thermal color proofing
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0486995A1

  公开（公告）日：1992-05-27

  A magenta dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of a yellow dye and a magenta dye dispersed in a polymeric binder, the magenta dye having the formula: wherein:    R¹ is hydrogen or a substituted or unsubstituted alkyl or allyl group of from 1 to 6 carbon atoms, with the proviso that R¹ is hydrogen when X is alkoxy;    X is R¹, an alkoxy group of from 1 to 4 carbon atoms or taken together with R² represents the atoms which form a 5- or 6-membered heterocyclic ring;    R² is a substituted or unsubstituted alkyl or allyl group of from 1 to 6 carbon atoms or can be combined with X as described above;    R³ is a substituted or unsubstituted alkyl group of from 1 to 6 carbon atoms or a substituted or unsubstituted aryl group of from 6 to 10 carbon atoms;    J is CO, CO₂, -SO₂- or CONR⁵-;    R⁴ is a substituted or unsubstituted alkyl or allyl group of from 1 to 6 carbon atoms, or a substituted or unsubstituted aryl group of from 6 to 10 carbon atoms; and    R⁵ is hydrogen or R³.

  一种用于热染料转移的洋红色染料捐赠元件包括一个支撑体，支撑体上有一个染料层，染料层由分散在聚合物粘合剂中的黄色染料和洋红色染料的混合物组成，洋红色染料的化学式为 其中 R¹为氢或1至6个碳原子的取代或未取代的烷基或烯丙基，但当X为烷氧基时，R¹为氢； X 是 R¹、1 至 4 个碳原子的烷氧基或与 R² 一起代表构成 5 或 6 元杂环的原子； R² 是 1 至 6 个碳原子的取代或未取代的烷基或烯丙基，或如上所述与 X 结合； R³ 是 1-6 个碳原子的取代或未取代的烷基或 6-10 个碳原子的取代或未取代的芳基； J 是 CO、CO₂、-SO₂- 或 CONR⁵-； R⁴ 是 1 至 6 个碳原子的取代或未取代的烷基或烯丙基，或 6 至 10 个碳原子的取代或未取代的芳基；以及 R⁵ 是氢或 R³。
• Mixture of cyan and yellow dyes to form a green hue for color filter array element
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0518349A1

  公开（公告）日：1992-12-16

  A thermally-transferred color filter array element comprising a support having thereon a polymeric dye image-receiving layer containing a thermally-transferred image comprising a repeating pattern of colorants, one of the colorants being a mixture of a yellow dye and a cyan dye to form a green hue, said cyan dye having the formula: wherein:    R represents hydrogen; a substituted or unsubstituted alkyl group having from 1 to 8 carbon atoms; a cycloalkyl group having from 5 to 8 carbon atoms; a substituted or unsubstituted alkenyl group having from 2 to 8 carbon atoms; or a substituted or unsubstituted aralkyl group having from 7 to 14 carbon atoms;    R¹ represents R; a substituted or unsubstituted acyl group having from 2 to 9 carbon atoms; a substituted or unsubstituted aroyl group having from 7 to 18 carbon atoms; or a substituted or unsubstituted heteroaroyl group having from 2 to 10 carbon atoms;    each J independently represents hydrogen; halogen; or a substituted or unsubstituted alkyl or alkoxy group having from 1 to 6 carbon atoms; and    n is from 1 to 3.

  一种热转印彩色滤光片阵列元件，包括一个支架，支架上有一个聚合物染料图像接收层，该层含有热转印图像，该图像包括着色剂的重复图案，其中一种着色剂是黄色染料和青色染料的混合物，形成绿色色调，所述青色染料的化学式为 其中 R 代表氢；具有 1 至 8 个碳原子的取代或未取代的烷基；具有 5 至 8 个碳原子的环烷基；具有 2 至 8 个碳原子的取代或未取代的烯基；或具有 7 至 14 个碳原子的取代或未取代的芳烷基； R¹ 代表 R；具有 2 至 9 个碳原子的取代或未取代的酰基；具有 7 至 18 个碳原子的取代或未取代的芳基；或具有 2 至 10 个碳原子的取代或未取代的杂芳基； 每个 J 独立地代表氢；卤素；或具有 1 至 6 个碳原子的取代或未取代的烷基或 烷氧基；以及 n 为 1 至 3。
• Black colored dye mixture for use according to thermal dye sublimation transfer
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0579299A1

  公开（公告）日：1994-01-19

  Black colored dye mixture for use in thermal dye sublimation transfer composed of at least four dyes and comprising two dyes having absorption maxima in the spectral range between 470 and 600 nm that are at least 30 nm apart from each other.

  用于热染料升华转移的黑色染料混合物，由至少四种染料组成，其中两种染料在 470 纳米到 600 纳米的光谱范围内具有吸收最大值，且彼此相距至少 30 纳米。
• Thiazolylazoaniline dyes for use in thermal dye sublimation transfer
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0578870A1

  公开（公告）日：1994-01-19

  Dye-donor element for use according to thermal dye sublimation transfer comprising a support having thereon a dye layer containing a thiazolylazoaniline dye, said thiazolylazoaniline dye containing on the 4-position of the thiazolyl ring a substituent selected from the group consisting of hydroxy, alkoxy, cycloalkoxy, aryloxy, mercapto, thioalkyl, thiocycloalkyl and thioaryl.

  用于热染料升华转移的染料给体元件，包括一个支撑体，支撑体上有一个染料层，染料层中含有噻唑基氮苯胺染料，所述噻唑基氮苯胺染料在噻唑环的 4 位上含有一个取代基，该取代基选自由羟基、烷氧基、环烷氧基、芳氧基、巯基、硫代烷基、硫代环烷基和硫代芳基组成的组。
• Imine dyes and photographic elements containing same
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0598420A1

  公开（公告）日：1994-05-25

  Imine dyes useful in photographic materials have the formula wherein D is selected from and wherein E¹, E², E³, and E⁴ each individually represents strongly electron-withdrawing groups; R¹ and R⁶ each individually represents an alkyl group of 1 to about 8 carbon atoms, or an aralkyl or cycloalkyl group of 5 to about 10 carbon atoms, or an aryl group of 6 to about 14 carbon atoms; R², R³, and R¹¹ each individually represents an alkyl group of 1 to about 8 carbon atoms, or an alkenyl group of 2 to about 8 carbon atoms, or an aryl, aralkyl, or cycloalkyl group of 5 to about 14 carbon atoms; or R² and R³ individually represent the non-metallic atoms necessary to form a 5- or 6-membered fused ring with the phenyl ring to which the nitrogen is attached, or together represent the non-metallic atoms required to form a 5- or 6-membered ring with each other; R⁴, R⁷, R⁸, R⁹, and R¹⁰ each individually represents hydrogen, or an alkyl, aralkyl, cycloalkyl, alkoxy, alkylamino, or alkylthio group of 1 to about 10 carbon atoms; R⁵ represents an alkyl group of 1 to about 8 carbon atoms, or an aralkyl or cycloalkyl group of 5 to about 10 carbon atoms; R¹² represents cyano, or an aryl, aminocarbonyl, or alkoxycarbonyl group of 2 to about 8 carbon atoms, or an alkylsulfonyl, arylsulfonyl, or sulfamoyl group of 1 to about 8 carbon atoms; or R¹¹ and R¹² together represent the non-metallic atoms necessary to complete a substituted or unsubstituted ring system containing at least one 5- or 6-membered heterocyclic or unsaturated alicyclic nucleus; G represents O or C(CN)₂; Y and Z each individually represents the non-metallic atoms necessary to complete a substituted or unsubstituted ring system containing at least one 5- or 6-membered heterocyclic nucleus; M⁺ is a cation; L¹ through L⁶ each individually represents unsubstituted or substituted methine groups; m is 0, 1, 2, or 3; n is 0 or 1; p is 0, 1, 2, 3, or 4; q is 0, 1, 2, or 3; and r is 0, 1, 2, 3, 4, or 5. Solid particle dispersions of dyes of formula (I) that contain at least one base-ionizable functional group such as carboxy, sulfonamido, or sulfamoyl are useful as filter dyes in photographic elements.

  用于照相材料的亚胺染料的化学式为 其中 D 选自 其中 E¹、E²、E³ 和 E⁴ 各自代表强吸电子基团；R¹ 和 R⁶ 各自代表 1 至约 8 个碳原子的烷基，或 5 至约 10 个碳原子的芳基或环烷基，或 6 至约 14 个碳原子的芳基；R²、R³和 R¹¹各自单独代表 1 至约 8 个碳原子的烷基，或 2 至约 8 个碳原子的烯基，或 5 至约 14 个碳原子的芳基、芳烷基或环烷基；或 R² 和 R³ 分别代表与氮相连的苯基环形成 5 或 6 元融合环所需的非金属原子，或共同代表彼此形成 5 或 6 元环所需的非金属原子；R⁴、R⁷、R⁸、R⁹ 和 R¹⁰ 各自代表氢或 1 至约 10 个碳原子的烷基、芳基、环烷基、烷氧基、烷基氨基或烷基硫基；R⁵ 代表 1 至约 8 个碳原子的烷基，或 5 至约 10 个碳原子的芳基或环烷基；R¹² 代表氰基，或 2 至约 8 个碳原子的芳基、氨基羰基或烷氧基羰基，或 1 至约 8 个碳原子的烷基磺酰基、芳基磺酰基或氨基磺酰基；或 R¹¹ 和 R¹² 共同代表完成包含至少一个 5 或 6 元杂环或不饱和脂环核的取代或未取代环系统所需的非金属原子；G 代表 O 或 C(CN)₂； Y 和 Z 分别代表完成含有至少一个 5 或 6 元杂环核的取代或未取代环系统所需的非金属原子；M⁺是阳离子；L¹至L⁶各自单独代表未取代或取代的甲基；m是0、1、2或3；n是0或1；p是0、1、2、3或4；q是0、1、2或3；以及r是0、1、2、3、4或5。 式（I）染料的固体颗粒分散体含有至少一个可碱电离的官能团，如羧基、磺酰胺基或磺酰基，可用作摄影元件中的滤光染料。